Issue 22, 2016
From the journal:

CrystEngComm

Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis†

Sumit Sachdeva,ab   Alexey Pustovarenko,b   Ernst J. R. Sudhölter,a   Freek Kapteijn,b   Louis C. P. M. de Smeta  and  Jorge Gascon*b  

* Corresponding authors

a Organic Materials and Interfaces, Department of Chemical Engineering, Delft University of Technology, Delft, The Netherlands

b Catalysis Engineering, Department of Chemical Engineering, Delft University of Technology, Delft, The Netherlands
E-mail: j.gascon@tudelft.nl

Abstract

A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.

Graphical abstract: Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

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Article information

DOI
https://doi.org/10.1039/C5CE02462E
Article type
Communication
Submitted
15 dec 2015
Accepted
11 jan 2016
First published
11 jan 2016
This article is Open Access
Creative Commons BY license

CrystEngComm, 2016,18, 4018-4022

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Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

S. Sachdeva, A. Pustovarenko, E. J. R. Sudhölter, F. Kapteijn, L. C. P. M. de Smet and J. Gascon, CrystEngComm, 2016, 18, 4018 DOI: 10.1039/C5CE02462E

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