Issue 21, 2011

Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride–triazolophane complexes

Abstract

Structural rigidity is verified as a pre-organizational factor that acts together with the macrocyclic effect such that synthesis helps in paying the cost of bringing together electropositive CH donors ready for H-bonding with chloride.

Graphical abstract: Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride–triazolophane complexes

Supplementary files

Article information

Article type
Communication
Submitted
21 jan 2011
Accepted
03 apr 2011
First published
26 apr 2011

Chem. Commun., 2011,47, 5979-5981

Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride–triazolophane complexes

Y. Hua, R. O. Ramabhadran, J. A. Karty, K. Raghavachari and A. H. Flood, Chem. Commun., 2011, 47, 5979 DOI: 10.1039/C1CC10428D

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