Issue 28, 2024

Recent advances in lead-free halide perovskites: from synthesis to applications

Abstract

Lead-based halide perovskites have taken semiconductor optoelectronics research by storm owing to their impressive optical and optoelectronic properties, emerging as promising candidates for high-performance solar cells, transistors, light-emitting diodes (LEDs), photodetectors, and other devices. However, the toxicity of these perovskites significantly limits their large-scale application. Therefore, the development of lead-free halide perovskites without sacrificing device performance is highly desirable. Lead-free halide perovskites based on elements such as Sn, Ge, Bi, and Cu are considered suitable alternatives for different applications. Herein, we review the methods for the synthesis of lead-free halide perovskites and comprehensively summarize the latest progress on lead-free halide perovskites in solar cells, transistors, photodetectors, sensors, LEDs and other fields based on different alternative elements from the perspective of materials science and device physics. Moreover, the performance advantages and application potential of lead-free perovskite materials based on different elements are highlighted, and strategies to improve the performance and stability of lead-free halide optoelectronic devices are investigated. Simultaneously, future development directions such as perovskite-organic hybrid optoelectronic devices in this research field are proposed and discussed. This review provides a comprehensive perspective on the in-depth study of lead-free halide perovskites and provides valuable insights into the current research status of lead-free halide perovskite optoelectronic devices, which will promote the development and design of new structures and devices, thereby further improving the performance and stability of devices to meet different needs in practical applications.

Graphical abstract: Recent advances in lead-free halide perovskites: from synthesis to applications

Article information

Article type
Review Article
Submitted
16 apr 2024
Accepted
11 jun 2024
First published
11 jun 2024

J. Mater. Chem. C, 2024,12, 10267-10329

Recent advances in lead-free halide perovskites: from synthesis to applications

Y. Wang, J. Liu, Y. Liu, S. Li, X. Xu and Z. Lou, J. Mater. Chem. C, 2024, 12, 10267 DOI: 10.1039/D4TC01556H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements