Issue 2, 2021

Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions

Abstract

Here, we present the first example of sp3 hybridized carbon centered (Csp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp3⋯N and Csp3⋯F pair interactions. The carbon tetrel bond interaction energies of Csp3⋯N and Csp3⋯F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.

Graphical abstract: Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions

Supplementary files

Article information

Article type
Communication
Submitted
12 nov 2020
Accepted
07 dec 2020
First published
08 dec 2020

CrystEngComm, 2021,23, 268-272

Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions

M. M. Ayhan, E. Özcan, B. Dedeoglu, Y. Chumakov, Y. Zorlu and B. Coşut, CrystEngComm, 2021, 23, 268 DOI: 10.1039/D0CE01640C

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