Issue 50, 2018

Proton and ammonia intercalation into layered iron chalcogenides

Abstract

Structurally related to the iron-based superconductors, two new intercalated iron chalcogenides (H0.5NH3)Fe2Ch2 where Ch = S, Se have been prepared. By topochemical conversion, the protons were exchanged by lithium to form (Li0.5NH3)Fe2Ch2. Hydrogen bonding plays a significant role in the guest–host interactions of these intercalated phases.

Graphical abstract: Proton and ammonia intercalation into layered iron chalcogenides

Supplementary files

Article information

Article type
Communication
Submitted
27 mar 2018
Accepted
30 apr 2018
First published
02 maj 2018

Chem. Commun., 2018,54, 6895-6898

Author version available

Proton and ammonia intercalation into layered iron chalcogenides

X. Zhou, B. Wilfong, S. Liou, H. Hodovanets, C. M. Brown and E. E. Rodriguez, Chem. Commun., 2018, 54, 6895 DOI: 10.1039/C8CC02436G

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