Issue 37, 2016
From the journal:

RSC Advances

Luminescent sensing from a new Zn(ii) metal–organic framework†

Jian-Qiang Liu,*ab   Jian Wu,c   Fu-Mei Li,ab   Wei-Cong Liu,ab   Bao-Hong Li,*ab   Jun Wang,d   Qin-Ling Li,ab   Reena Yadave  and  Abhinav Kumar*e  

* Corresponding authors

a School of Pharmacy, Guangdong Medical University, Dongguan, P. R. China
E-mail: jianqiangliu2010@126.com, gdmcli@126.com
Fax: +86-769-22896560
Tel: +86-769-22896560

b Guangdong Key Laboratory for Research and Development of Natural Drugs, Guangdong Medical University, P. R. China

c Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi University for Nationalities, College of Chemistry and Chemical Engineering, Nanning, Guangxi 530006, China

d School of Chemistry and Pharmaceutical Engineering, Sichuan University of Science & Engineering, Zigong 643000, P. R. China

e Department of Chemistry, Faculty of Science, University of Lucknow, Lucknow 226 007, India
E-mail: kumar_abhinav@lkouniv.ac.in

Abstract

A new metal–organic framework having the formula (NH2(CH3)2)[Zn2(OAc)(L)]·0.5DMF (H4L = 2,5-di(3′,5′-dicarboxylphenyl)pyridine) (GDMU-3) has been synthesized and characterized. The net of GDMU-3 is uninodal and is closely related to the lvt net, which has the same Schläfli symbol of 42·84. GDMU-3 displays selective properties for the detection of nitrobenzene and Fe3+ ions. Remarkably, GDMU-3 exhibits an excellent capability to adsorb methylene blue with high selectivity. The present work indicates that GDMU-3 could be a potential candidate for developing novel luminescence sensors for the selective sensing of nitrobenzene which can be deployed for explosives, Fe3+ and organic dyes.

Graphical abstract: Luminescent sensing from a new Zn(ii) metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C6RA01709F
Article type
Paper
Submitted
20 jan 2016
Accepted
10 mar 2016
First published
14 mar 2016

RSC Adv., 2016,6, 31161-31166

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Luminescent sensing from a new Zn(II) metal–organic framework

J. Liu, J. Wu, F. Li, W. Liu, B. Li, J. Wang, Q. Li, R. Yadav and A. Kumar, RSC Adv., 2016, 6, 31161 DOI: 10.1039/C6RA01709F

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