Issue 37, 2009
From the journal:

Chemical Communications

Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide†

Chengbao Nia  and  Philip P. Power*a  

* Corresponding authors

a University of California, One Shields Avenue, Davis, USA
E-mail: pppower@ucdavis.edu
Fax: +1 530-752-8995
Tel: +1 530-752-691

Abstract

The iron(II) diaryl FeAr′2 (1) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) reacts cleanly with O2 or CO to afford the monomeric, two-coordinate bis(aryloxide) Fe(OAr′)2 (2) or the η2-acyl–carbonyl complex (η2-Ar′C[double bond, length as m-dash]O)2Fe(CO)2 (3) viaoxygen or CO insertion into the Fe–C bonds; complex 2 has a strictly linear geometry and shows remarkable resistance to O2oxidation.

Graphical abstract: Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B912312A
Article type
Communication
Submitted
23 jun 2009
Accepted
24 jul 2009
First published
17 aug 2009

Chem. Commun., 2009, 5543-5545

Permissions

Request permissions

Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide

C. Ni and P. P. Power, Chem. Commun., 2009, 5543 DOI: 10.1039/B912312A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements