Oxidation-induced ambiphilicity triggers N–N bond formation and dinitrogen release in octahedral terminal molybdenum(v) nitrido complexes

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Chem. Sci., 2024, 15, 5152
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Dinitrogen reduction to ammonia with a pincer-Mo complex: new insights into the mechanism of nitride-to-ammonia conversion

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Chem. Sci., 2025, 16, 7347
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Catalytic reduction of dinitrogen to ammonia using molybdenum porphyrin complexes

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Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH3, N2H4, H2O, H2)

Maximilian Auer, Janina Bolten, Klaus Eichele, Hartmut Schubert, Christian P. Sindlinger and Lars Wesemann

Chem. Sci., 2023, 14, 514
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Spontaneous Ammonia Activation Through Coordination‐Induced Bond Weakening in Molybdenum Complexes of a Dianionic Pentadentate Ligand Platform**

C. Christopher Almquist, Nicole Removski, Thayalan Rajeshkumar, Benjamin S. Gelfand, Laurent Maron and Warren E. Piers

Angewandte Chemie, 2022, 134
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Bypassing the Nitrido Wall Using a Redox‐Active Isocyanide: Nucleophilic Attack on CO by a Rhenium Nitride Complex

Alexander S. Hegg, Ryan S. Donnelly, Jeremy E. Weber, Robert H. Crabtree, Brandon Q. Mercado and Patrick L. Holland

Angewandte Chemie, 2025, 137
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Oxidation of Ammonia Catalyzed by a Molecular Iron Complex: Translating Chemical Catalysis to Mediated Electrocatalysis

Liang Liu, Samantha I. Johnson, Aaron M. Appel and R. Morris Bullock

Angew Chem Int Ed, 2024, 63
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N–H Bond Activation of Ammonia by a Redox-Active Carboranyl Diphosphine

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J. Am. Chem. Soc., 2024, 146, 33159
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Facile Addition of B–H and B–B Bonds to an Iron(IV) Nitride Complex

Bao G. Tran, Veronica Carta, Maren Pink, Kenneth G. Caulton and Jeremy M. Smith

Inorg. Chem., 2022, 61, 19800
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Hydrogen Atom Abstraction from an OsII(NH3)2 Complex Generates an OsIV(NH2)2 Complex: Experimental and Computational Analysis of the N–H Bond Dissociation Free Energies and Reactivity

Peter L. Dunn, Melissa Barona, Samantha I. Johnson, Simone Raugei and R. Morris Bullock

Inorg. Chem., 2022, 61, 15325
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Molecular Complexes for Catalytic Ammonia Oxidation to Dinitrogen and the Cleavage of N−H Bonds

David N. Stephens and Michael T. Mock

Eur J Inorg Chem, 2024, 27
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Spontaneous Ammonia Activation Through Coordination‐Induced Bond Weakening in Molybdenum Complexes of a Dianionic Pentadentate Ligand Platform**

C. Christopher Almquist, Nicole Removski, Thayalan Rajeshkumar, Benjamin S. Gelfand, Laurent Maron and Warren E. Piers

Angew Chem Int Ed, 2022, 61
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Oxidation of Ammonia Catalyzed by a Molecular Iron Complex: Translating Chemical Catalysis to Mediated Electrocatalysis

Liang Liu, Samantha I. Johnson, Aaron M. Appel and R. Morris Bullock

Angewandte Chemie, 2024, 136
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Nitrogen Fixation by Manganese Complexes – Waiting for the Rush?

Quentin Le Dé, Dmitry A. Valyaev and Antoine Simonneau

Chemistry A European J, 2024, 30
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Bypassing the Nitrido Wall Using a Redox‐Active Isocyanide: Nucleophilic Attack on CO by a Rhenium Nitride Complex

Alexander S. Hegg, Ryan S. Donnelly, Jeremy E. Weber, Robert H. Crabtree, Brandon Q. Mercado and Patrick L. Holland

Angew Chem Int Ed, 2025, 64
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Isocyanide Ligation Enables Electrochemical Ammonia Formation in a Synthetic Cycle for N2 Fixation

Jeremy E. Weber, Noah D. McMillion, Alexander S. Hegg, Ashlee E. Wertz, Mehrnaz Aliahmadi, Brandon Q. Mercado, Robert H. Crabtree, Hannah S. Shafaat, Alexander J. M. Miller and Patrick L. Holland

J. Am. Chem. Soc., 2024, 146, 33595
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Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile‐ versus Proton‐Coupled Electron Transfer

Maximilian Fritz, Severine Rupp, Ciara I. Kiene, Sesha Kisan, Joshua Telser, Christian Würtele, Vera Krewald and Sven Schneider

Angew Chem Int Ed, 2022, 61
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Oxidorhenium(V) and Rhenium(III) Complexes with Arylselenolato and ‐tellurolato Ligands

Bruno Noschang Cabral, Jéssica Fonseca Rodrigues, Maximilian Roca Jungfer, Anke Krebs, Adelheid Hagenbach, Ernesto Schulz Lang and Ulrich Abram

Eur J Inorg Chem, 2023, 26
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Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile‐ versus Proton‐Coupled Electron Transfer

Maximilian Fritz, Severine Rupp, Ciara I. Kiene, Sesha Kisan, Joshua Telser, Christian Würtele, Vera Krewald and Sven Schneider

Angewandte Chemie, 2022, 134
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