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High molecular weight thiophene-containing conjugated polymers were successfully synthesized by Suzuki polycondensation of aryl dibromides and 2,5-thiophenebis(boronic acid) derivatives by using a new thiophene-containing bulky phosphorous compound as the ligand for a zerovalent palladium catalyst.

Graphical abstract: Synthesis of thiophene-containing conjugated polymers from 2,5-thiophenebis(boronic ester)s by Suzuki polycondensation

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