Issue 16, 2002
From the journal:

Chemical Communications

Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group

K. Noro,a   Y. Ozawa,*b   M. Taguchia  and  A. Yagasaki*a  

* Corresponding authors

a Department of Chemistry, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Japan
E-mail: yagasaki@kwansei.ac.jp
Fax: +81 795 65 9077
Tel: +81 795 65 8396

b Department of Material Science, Himeji Institute of Technology, Harima Science Garden City, Kamigori, Japan

Abstract

A novel tetranuclear mixed valence cationic Pt molecular oxide [{(Me3P)2Pt}3Pt(OH)6]4+ is obtained by reacting H2Pt(OH)6 and (Me3P)2Pt2+, whose NMR spectra suggest the existence of another species in solution that may serve as a starting point for further synthesis of Pt molecular oxides.

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Article information

DOI
https://doi.org/10.1039/B204804C
Article type
Communication
Submitted
17 Mai 2002
Accepted
02 Gor 2002
First published
15 Gor 2002

Chem. Commun., 2002, 1770-1771

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Isolation of a new mixed valence Pt molecular oxide using phosphine as protecting group

K. Noro, Y. Ozawa, M. Taguchi and A. Yagasaki, Chem. Commun., 2002, 1770 DOI: 10.1039/B204804C

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