Oxidative addition of diaryldichalcogenides to the diferrocenylphosphenium ion: synthesis, structure and organocatalytic activity†
Corina
Stoian, 
‡a
Thomas J.
Kuczmera,
b
Pim
Puylaert,
a
Enno
Lork,
a
Boris J.
Nachtsheim,
*b
Emanuel
Hupf
*a
and
Jens
Beckmann
*a
‡a
Thomas J.
Kuczmera,
b
Pim
Puylaert,
a
Enno
Lork,
a
Boris J.
Nachtsheim,
*b
Emanuel
Hupf
*a
and
Jens
Beckmann
*a
Abstract
The reaction of the phosphenium ion [Fc2P]+ with dichalcogenides gace rise to the respective phosphonium ions [Fc2P(ChR)2]+ (Ch = S, Se, Te; R = Ph, Fc, biphen), which were employed in chalcogen bond mediated Michael additions.
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