Issue 10, 2013
From the journal:

Polymer Chemistry

Triphenylphosphine as phosphorus catalyst for reversible chain-transfer catalyzed polymerization (RTCP)

Liangjiu Bai,a   Lifen Zhang,a   Yuan Liu,a   Xiangqiang Pan,a   Zhenping Cheng*a  and  Xiulin Zhu*a  

* Corresponding authors

a Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China
E-mail: chengzhenping@suda.edu.cn, xlzhu@suda.edu.cn
Fax: +86-512-65882787

Abstract

Triphenylphosphine (TPP) was used as the catalyst for reversible chain-transfer catalyzed polymerizations (RTCPs) of styrene and methyl methacrylate for the first time. The polymerizations showed the typical features of “living”/controlled radical polymerization, and well-defined polymers with designable molecular weights and narrow molecular weight distributions (Mw/Mn < 1.35) were obtained. In addition, RTCP of styrene using TPP as a novel catalyst not only could be conducted in the presence of a limited amount of air but also did not destroy the controllability over polymerizations.

Graphical abstract: Triphenylphosphine as phosphorus catalyst for reversible chain-transfer catalyzed polymerization (RTCP)

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Article information

DOI
https://doi.org/10.1039/C3PY00187C
Article type
Paper
Submitted
05 Chw 2013
Accepted
03 Maw 2013
First published
04 Maw 2013

Polym. Chem., 2013,4, 3069-3076

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Triphenylphosphine as phosphorus catalyst for reversible chain-transfer catalyzed polymerization (RTCP)

L. Bai, L. Zhang, Y. Liu, X. Pan, Z. Cheng and X. Zhu, Polym. Chem., 2013, 4, 3069 DOI: 10.1039/C3PY00187C

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