Quantitative pyrrole protection was achieved through a self-driven pathway by the combinational assistance of solvent water and dissociative weak H+.
One-pot cascade biocatalysis for conversion of biobased L-phenylalanine into both enantiomers of phenylalaninol.
Inherently chiral calix[4]arenes, which have triazole and amine-based functional/receptor groups asymmetrically arranged at the wide rim of a cone macrocycle, can be readily prepared through desymmetrization of a calix[4]arene triamine.
We report a continuous, solvent-free method for aldimine synthesis using single-screw extrusion that achieves near-quantitative yields with water as the sole byproduct.
Compared to EtOH or EtOH/water, ACN/water solution produced better conducting hexagonal nanofiber of (2,5-diphenyl-2H-1,2,3-triazole-4-carbonyl)-L-phenylalaninate. The fibers from ACN/water can carry 100 nA current upon the applied voltage of 0.56 V.