Herein, the chemical synthesis of new thiazole-based benzenesulfonamide-linked morpholine 4a,b–7via late-stage thiazolation of the corresponding thiosemicarbazone 3 is reported.
Different synthetic strategies towards possibly photoswitchable bis-zirconocenes are discussed. UV-vis spectroscopic and olefin polymerization reactivity studies are described.
Zr imido chemistry: well-defined silica-supported Zr imido complexes via Surface Organometallic Chemistry, oxo/imido heterometathesis and comparison with Ti analogs.
Two new corrosion inhibitors were synthesized and applied to steel in 1.0 M HCl. The corrosion resistance was probed by electrochemical and theoretical methods. The study reveals significant intersections between electrochemical aspects and theory.
The synthesis of 4-thio-D-galactonic acid 1,4-thiolactone (5), 4-deoxy-D-galactono-1,4-lactam (14), and N-substituted lactam derivatives (20a–f) is described. These glycomimetics are inhibitors of P. fellutanum β-galactofuranosidase.