Green synthesis of hypercrosslinked polymers for CO2 capture and conversion: recent advances, opportunities, and challenges

Wenliang Song, Yunxin Tang, Byeong Yeol Moon, Qian Liao, Hailang Xu, Qing Hou, Heng Zhang, Deng-Guang Yu, Yaozu Liao and Il Kim

Green Chem., 2024, 26, 2476
DOI: 10.1039/D3GC04222G

Hypercrosslinked polymers (HCPs) for CO2 capture and catalytic conversion: synthesis, functionalization, and applications

Saif Ullah, Jiarui Hu, Sughra Manzoor and Bien Tan

J. Mater. Chem. A, 2025, 13, 35082
DOI: 10.1039/D5TA04419G

Heavy metal elimination using hyper-cross-linked waste polycarbonate resin as an effective adsorbent: experimental and RSM optimization

Mobina Khakbaz, Ahad Ghaemi and Gity Mir Mohamad Sadeghi

Iran Polym J, 2023, 32, 947
DOI: 10.1007/s13726-023-01176-7

Dibromomethane Knitted Highly Porous Hyper‐Cross‐Linked Polymers for Efficient High‐Pressure Methane Storage

Shoukun Yang, Zicheng Zhong, Jiarui Hu, Xiaoyan Wang and Bien Tan

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202307579

Recent research progress in the synthesis, characterization and applications of hyper cross-linked polymer

Saqlain Raza, Shahid Nazeer, Amin Abid and Aorij Kanwal

J Polym Res, 2023, 30
DOI: 10.1007/s10965-023-03783-7

Hypercrosslinked Polymers for Volatile and Very Volatile Organic Compound Capture Beyond Commercial Benchmarks

Paul Schweng, Elias Rippatha, Clemens Schwarzinger and Robert T. Woodward

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202513362

Versatile Hyper-Cross-Linked Polymers Derived from Waste Polystyrene: Synthesis, Properties, and Intentional Recycling

Wenliang Song, Yuheng Wen, Zeyu Wang, Hailang Xu, Qian Liao, Yunxin Tang, Deng-Guang Yu and Il Kim

Langmuir, 2024, 40, 16670
DOI: 10.1021/acs.langmuir.4c01041

Hypercrosslinked natural biopolymers with quasi-unimodal micropores for carbon capture

Liang Ding, Yue Wu, Guanchu Lu, Yixuan Zhang, Mariolino Carta, Xianfeng Fan and Cher Hon Lau

Carbon Capture Science & Technology, 2024, 13, 100305
DOI: 10.1016/j.ccst.2024.100305

In-situ construction of different Lewis acids in hyper-cross-linked polymer as water-resistant adsorbent for efficient Hg0 removal

Yifan Xu, Xinyu Wu, Limin Liu, Yueqing Xu, Cheng Chen, Yi Wang, Cheng Zhang, Xiaoshuo Liu, Chengyan Li and Houhu Zhang

Chemical Engineering Journal, 2024, 488, 150572
DOI: 10.1016/j.cej.2024.150572

Amine-Appended Hyper-Crosslinked Polymers for Direct Air Capture of CO2

Tristan L. Spreng, David Danaci, Preshti D. Ram, Daryl R. Williams, Ronny Pini and Camille Petit

ACS Sustainable Chem. Eng., 2026
DOI: 10.1021/acssuschemeng.5c08715

Magnetic hypercrosslinked polymer microspheres for the detection, spatial distribution, source identification and potential risks assessment of five polycyclic aromatic hydrocarbons in city river of plateau lake, Southwest China

Sitao Wang, Xiaolan Zhang, Qingqing Zhou, Zhimin Liu and Zhigang Xu

Journal of Hazardous Materials, 2024, 476, 135026
DOI: 10.1016/j.jhazmat.2024.135026

Facile synthesis of magnetic hyper-crosslinked porous polymer for efficient extraction and sensitive determination of nitroimidazole antibiotics

Yihang He, Jinjin Tao, Xin Zhang, Jing Guo, Yixuanfei Gao, Yajuan Hu, Jintao Yu, Qianqian Wang and Qiuhua Wu

Microchemical Journal, 2024, 200, 110285
DOI: 10.1016/j.microc.2024.110285

High‐Capacity Volumetric Methane Storage in Hyper‐Cross‐Linked Porous Polymers via Flexibility Engineering of Building Units

Jiarui Hu, Hui Gao, Xiaoyan Wang and Bien Tan

Advanced Materials, 2025, 37
DOI: 10.1002/adma.202418005

Triphenylene-based porous polymer for selective CO2 capture with molecular modeling insights and CO2/N2 separation performance indicators for vacuum swing adsorption

Mosim Ansari, Ismail Abdulazeez, Abuzar Khan, Aasif Helal, M. Nasiruzzaman Shaikh, Fares Ahmed Turkestani and Mohd Yusuf Khan

Chemical Engineering Journal, 2026, 528, 172415
DOI: 10.1016/j.cej.2025.172415

Hypercrosslinked polymers with hierarchical pores synthesized using biphenyl crosslinker for carbon dioxide capture

Saumya Krishnan, Athira R. Sujatha, Princy Deni Raju and Chettiyam Veettil Suneesh

Journal of Solid State Chemistry, 2024, 334, 124683
DOI: 10.1016/j.jssc.2024.124683

Multiple Phenolic Hydroxyl-Modified Hyper-Crosslinked Polymers and Their Efficient Adsorptive Removal of o-Nitrophenol from Water

Yiwen Cao, Juan Zhong, Zhongke Dai, You Wang, Yuli Fu, Fa Zhou, Jianhan Huang and You-Nian Liu

Ind. Eng. Chem. Res., 2023, 62, 15166
DOI: 10.1021/acs.iecr.3c02001

Hypervernetzte Polymere zur Abscheidung von flüchtigen und sehr flüchtigen organischen Verbindungen jenseits kommerzieller Adsorptionsmittel

Paul Schweng, Elias Rippatha, Clemens Schwarzinger and Robert T. Woodward

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202513362

Analyzing Environmental Impacts of Hypercrosslinked Polymers Produced from Continuous Flow Synthesis for Water Treatment

Nadhita Chanchaona and Cher Hon Lau

Ind. Eng. Chem. Res., 2023, 62, 9046
DOI: 10.1021/acs.iecr.3c00829

Upcycling phenyl-based waste: hypercrosslinking strategies and applications

Jie Mao, Fengming Hua, Huahui Pan, Yujun Zhu, Jianguo Chang, Xin Tan, Wenlong Lu, Zhijie Chen, Baohua Jia and Lei Ding

Chemical Engineering Journal, 2026, 527, 171337
DOI: 10.1016/j.cej.2025.171337

Assessing the environmental impacts of flow and batch syntheses of hypercrosslinked polymers for low-pressure CO2 adsorption

Nadhita Chanchaona and Cher Hon Lau

Separation and Purification Technology, 2024, 329, 125145
DOI: 10.1016/j.seppur.2023.125145

Experimental and kinetic evaluation on cobalt Salen conjugated organic polymers for CO2 cycloaddition reactions and iodine vapor adsorption

Tingchun Zhu, Shuangshuo Li, Meiqi Sun, Ningning Li, Xuanbo Liu, Yuhang Zhang, Tao Chang, Yongjing Hao and Zheng Zhu

Journal of Molecular Liquids, 2024, 401, 124651
DOI: 10.1016/j.molliq.2024.124651

Amine-functionalized mesoporous silica derived from natural phyllosilicate for efficient CO2 adsorption

Xiaoyu Li, Kang Peng, Xueqi Zhao, Keping Zhao, Haoran Li, Yanrong Zhao and Bo Zhang

Applied Clay Science, 2024, 256, 107433
DOI: 10.1016/j.clay.2024.107433

Improved porosity and CO2 capturing capacity in carboxyl enriched hyper-cross-linked polymers via side chain engineering of fluorene derivatives based building units

Shuangshuang Hou, Hui Gao, Peixuan Xie, Shiwei Jin, Fengtian Wu and Bien Tan

Separation and Purification Technology, 2026, 382, 135792
DOI: 10.1016/j.seppur.2025.135792

Effect of Different Oxygen-Containing Groups on the Nanopore Diameter of Hyper-Crosslinked Resins for Gas Adsorption/Separation

Chuanhong Wang, Xuefang Chen, Shimiao Yao, Fen Peng, Lian Xiong, Haijun Guo, Hairong Zhang and Xinde Chen

ACS Appl. Nano Mater., 2024, 7, 415
DOI: 10.1021/acsanm.3c04616

Methoxyl-Containing Hyper-Crosslinked Polymer from Largely Bio-Based Biphenyl Methyl Ether and Its Application in Lithium-Sulfur Battery

Apparav K. Wale, Anoushka K. Das, Nita R. Patil, Manjusha V. Shelke, Ashootosh V. Ambade and Prakash P. Wadgaonkar

Reactive and Functional Polymers, 2025, 207, 106139
DOI: 10.1016/j.reactfunctpolym.2024.106139

Hyper-Cross-Linked Resin Modified by a Micropore Polymer for Gas Adsorption and Separation

Chuanhong Wang, Xuefang Chen, Shimiao Yao, Fen Peng, Lian Xiong, Haijun Guo, Hairong Zhang and Xinde Chen

Langmuir, 2024, 40, 12465
DOI: 10.1021/acs.langmuir.4c00863

Microreactors in multiphase flows, strong exothermic, high viscosity and high solids content chemical processes

Jibing Guo, Hongyu Huang, Xin Yuan, Yirong Feng, Jiming Yang, Ning Zhu, Shuangfei Zhao, Wei He and Kai Guo

Chemical Engineering Journal, 2025, 526, 171027
DOI: 10.1016/j.cej.2025.171027

Heterogeneous Catalytic Oxidations with In Situ‐Generated Hypervalent Iodine‐Based Porous Organic Polymers

Parag Tamuly, Keshaba Nanda Parida, Stéphane Quideau and Jarugu Narasimha Moorthy

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403402

Hypercrosslinked polymer membranes via interfacial polymerization for organic dye separations

Qingyin Li, Shuqing Li, Caimei Yu, Zhen Zhan, Guang Cheng, Bien Tan and Shijie Ren

Commun Mater, 2024, 5
DOI: 10.1038/s43246-024-00668-0

Continuous flow chemistry for molecular synthesis

Sarah E. Raby-Buck, Jonathan Devlin, Prachi Gupta, Claudio Battilocchio, Marcus Baumann, Anastasios Polyzos, Anna G. Slater and Duncan L. Browne

Nat Rev Methods Primers, 2025, 5
DOI: 10.1038/s43586-025-00414-x

Green and High-Efficiency Room Temperature Synthesis of Hypercrosslinked Polymers in Acidic Ionic Liquids with Enhanced Adsorption Performance

Yanting Huang, Hui Zhang, Cong Zhao, Wanmei Li, Pengfei Zhang and Yuqi Ke

ACS Appl. Polym. Mater., 2025, 7, 7482
DOI: 10.1021/acsapm.5c01124

Unraveling HCPs-derived porous carbon: Synthesis, pore formation and rapid potassium-ion storage

Zhengyang Liu, Tao Yang, Yan Song, Ning Zhao, Shijie Wu, Zihui Ma, Xiangjie Gong, Xiaodong Tian and Zhanjun Liu

Chemical Engineering Journal, 2025, 510, 161615
DOI: 10.1016/j.cej.2025.161615