Catalyst-free synthesis of α,α-disubstituted carboxylic acid derivatives under ambient conditions via a Wolff rearrangement reaction

Xin Ji, Zhikun Zhang, Yuzhu Wang, Yazhe Han, Huiling Peng, Fangzhu Li and Lu Liu

Org. Chem. Front., 2021, 8, 6916
DOI: 10.1039/D1QO01265G

Single-atom editing for the construction of boron-containing heterocycles

Xue Li, Yi-Ming Chen and Zhi-Gang Xu

Org. Chem. Front., 2025, 12, 3521
DOI: 10.1039/D5QO00210A

Recent advances in the construction of tetracoordinate boron compounds

Xue Li, Guan Zhang and Qiuling Song

Chem. Commun., 2023, 59, 3812
DOI: 10.1039/D2CC06982B

Demethyl oxidative halogenation of diacyl dimethylsulfonium methylides

Duo Fu, Changmeng Xi and Jiaxi Xu

Org. Biomol. Chem., 2023, 21, 3991
DOI: 10.1039/D3OB00499F

Synthesis of cyclopropanes via palladium-catalyzed [2+1] annulations of sulfoxonium ylides and norbornenes

Wenguang Li, Yongqi Yu, Heyun Sheng, Man Cao, Ming Chen, Wenchao Gao, Xu Zhang, Fengyun Su and Ting Li

Chem. Commun., 2025, 61, 10835
DOI: 10.1039/D5CC02783G

Copper-catalyzed P–H insertion reactions of sulfoxonium ylides

Xinzhi Zhang, Yangyang Zhang, Cuijian Liang and Jun Jiang

Org. Biomol. Chem., 2021, 19, 5767
DOI: 10.1039/D1OB00948F

Highly efficient synthesis of furan-2-ylmethylboranes by a copper-catalyzed three-component cascade strategy

Chengrui Hang, Fei Lu, Daan Song, Guanghui Wang and Ximei Zhao

New J. Chem., 2025, 49, 3006
DOI: 10.1039/D4NJ05074F

Iridium-catalyzed arylation of sulfoxonium ylides and arylboronic acids: a straightforward preparation of α-aryl ketones

Bing Shu, Xiao-Tong Wang, Zi-Xuan Shen, Tong Che, Mei Zhong, Jia-Lin Song, Hua-Jie Kang, Hui Xie, Luyong Zhang and Shang-Shi Zhang

Org. Chem. Front., 2020, 7, 1802
DOI: 10.1039/D0QO00543F

Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes

Xinyu Wang and Zhaobin Wang

Org. Chem. Front., 2024, 11, 2241
DOI: 10.1039/D4QO00136B

Rhodium-catalyzed C–H α-fluoroalkenylation/annulation of β-ketosulfoxonium ylides with 2,2-difluorovinyl tosylate/oxadiazolones

Jia-Lin Song, Zi-Feng Yang, Sheng Fang, Wang-Liang Chen, Lian-Bao Ye, Xiang Liu and Bing Shu

Chem. Commun., 2024, 60, 15000
DOI: 10.1039/D4CC05621C

Ir(iii)-catalyzed selective C–H acylmethylation and dicarbonylation of indolizines with β-ketosulfoxonium ylides

Zi-Feng Yang, Yuan-Jie Meng, Xin-Xing Liu, Jiaohang Wei, Wen-Rong Wu, Xiang Liu, Shang-Shi Zhang and Pengju Feng

Chem. Commun., 2025, 61, 15441
DOI: 10.1039/D5CC04380H

A copper-catalyzed B–H bond insertion reaction of azide–ynamide with borane adductsviaα-imino copper carbenes

Chen-Yong Weng, Guang-Yu Zhu, Bo-Han Zhu, Peng-Cheng Qian, Xin-Qi Zhu, Jin-Mei Zhou and Long-Wu Ye

Org. Chem. Front., 2022, 9, 2773
DOI: 10.1039/D2QO00457G

Photoinduced catalyst-free borylation of alkenyl triflates with Lewis base complexes of boranes

Zhi-Peng Ye, Si-Jia Yang, Zhi-Lin Liu, Jie Gao, Yong-Qing Ye, Hong-Bin Chen, Peng-Ju Xia, Kai Chen, Hao-Yue Xiang and Hua Yang

Org. Chem. Front., 2023, 10, 5667
DOI: 10.1039/D3QO01418E

Visible-light-driven PhSSPh-catalysed regioselective hydroborylation of α,β-unsaturated carbonyl compounds with NHC-boranes

Xinghua Liu, Yujing Shen, Cheng Lu, Yongchan Jian, Shuangshuang Xia, Zhaoliang Gao, Yihan Zheng, Yuanyuan An and Yubin Wang

Chem. Commun., 2022, 58, 8380
DOI: 10.1039/D2CC02846H

Fe-Catalyzed B–H and N–H insertion reactions of iodonium ylides

Hejun An, Zhi Cui, Jinchao Liang, Xingxing Ma, Jinglong Chen and Qiuling Song

Org. Chem. Front., 2025, 12, 4058
DOI: 10.1039/D4QO01916D

Catalytic asymmetric cyclopropanation of sulfoxonium ylides catalyzed by a chiral-at-metal rhodium complex

Siliang Ming, Jian Yang, Shi Wu, Gang Yao, Hongwei Xiong, Yu Du and Jun Gong

Org. Chem. Front., 2022, 9, 5147
DOI: 10.1039/D2QO01068B

Asymmetric transformations from sulfoxonium ylides

Clarice A. D. Caiuby, Lucas G. Furniel and Antonio C. B. Burtoloso

Chem. Sci., 2022, 13, 1192
DOI: 10.1039/D1SC05708A

Modular synthesis of divergent thiofunctionalized sulfoxonium ylides

Qiong Hu, Mei-Zhu Bao, Yuan-Jie Meng, Xin-Xing Liu, Wen-Xuan Zou, Jia-Lin Song, Jiaohang Wei, Dan-Ting Shen, Xiang Liu, Xiaohui Cao and Shang-Shi Zhang

Org. Chem. Front., 2024, 11, 6223
DOI: 10.1039/D4QO01347F

Post-coordination of Ru(ii) controlled regioselective B(4)–H acylmethylation of o-carboranes with sulfoxonium ylides

Hou-Ji Cao, Jia-Xin Li, Jia-Hui Yan, Miao-Xin Liu, Qianyi Zhao, Jie Zhang, Ju Zhang and Hong Yan

Chem. Sci., 2025, 16, 9406
DOI: 10.1039/D5SC01576F

Sulfoxonium ylides: simple compounds with chameleonic reactivity

Giorgiana Denisa Bisag, Silvia Ruggieri, Mariafrancesca Fochi and Luca Bernardi

Org. Biomol. Chem., 2020, 18, 8793
DOI: 10.1039/D0OB01822H

One-pot synthesis of 3-trifluoromethylbenzo[b][1,4]oxazines from CF3-imidoyl sulfoxonium ylides with 2-bromophenols

Mingshi Pan, Yixin Tong, Xiaodong Qiu, Xiaobao Zeng and Biao Xiong

Chem. Commun., 2022, 58, 12443
DOI: 10.1039/D2CC04863A

Iridium-catalyzed [(5+1)−1] annulation of pyridinium 1,4-zwitterionic thiolates and sulfoxonium ylides: a versatile platform to indolizines

Sheng Fang, Wang-Liang Chen, Yuan-Jie Meng, Shang-Shi Zhang, Peng-Ju Feng and Bing Shu

Chem. Commun., 2025, 61, 14725
DOI: 10.1039/D5CC03199K

Tunable electrochemical diverse sulfurization of sulfoxonium ylides with disulfides

Xinwei Hu, Kaihui Zhong and Zhixiong Ruan

Chem. Commun., 2024, 60, 8573
DOI: 10.1039/D4CC02479F

Metal-free cascade O–H double insertion between I(III)/S(VI)-ylides, carboxylic acids, and alcohols: modular access to unsymmetrical α,α-O,O-substituted ketones

Jiaohang Wei, Wen-Xuan Zou, Qiong Hu, Mei-Zhu Bao, Dan-Ting Shen, Lin Xiao, Jia-Lin Song, Xiang Liu and Shang-Shi Zhang

Org. Chem. Front., 2024, 11, 3234
DOI: 10.1039/D4QO00453A

A cascade indazolone-directed Ir(iii)- and Rh(iii)-catalyzed C(sp2)–H functionalization/[4 + 2] annulation of 1-arylindazolones with sulfoxonium ylides to access chemically divergent 8H-indazolo [1,2-a]cinnolines

Yi-Chuan Zheng, Bing Shu, Yao-Fu Zeng, Shao-Yong Chen, Jia-Lin Song, Yan-Zhi Liu, Lin Xiao, Xu-Ge Liu, Xuanxuan Zhang and Shang-Shi Zhang

Org. Chem. Front., 2022, 9, 5185
DOI: 10.1039/D2QO00871H

Uncommon carbene insertion reactions

Ming-Yao Huang and Shou-Fei Zhu

Chem. Sci., 2021, 12, 15790
DOI: 10.1039/D1SC03328J

Brønsted acid-catalyzed homogeneous O–H and S–H insertion reactions under metal- and ligand-free conditions

Zhipeng Zhang, Zhiqin He, Yuxing Xie, Tiantong He, Yaofeng Fu, Yang Yu and Fei Huang

Org. Chem. Front., 2021, 8, 1233
DOI: 10.1039/D0QO01401J

Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds

Li Li, Kun Deng, Yajie Xing, Cheng Ma, Shao-Fei Ni, Zhaofeng Wang and Yong Huang

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-34401-7

Synthesis of Pyrazolo[1,2‐a]cinnolines via Rhodium(III)‐Catalyzed [4+2] Annulation Reactions of Pyrazolidinones with Sulfoxonium Ylides

Shulei Hu, Xu Han, Xiong Xie, Feifei Fang, Yong Wang, Abdusaid Saidahmatov, Hong Liu and Jiang Wang

Adv Synth Catal, 2021, 363, 3311
DOI: 10.1002/adsc.202100324

Synthesis of Sulfo(xo)nium Diacylmethylides

Duo Fu and Jiaxi Xu

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400390

Carbene B−H Insertion Reactions for C−B Bond Formation

Ximei Zhao, Guanghui Wang and A. Stephen K. Hashmi

ChemCatChem, 2021, 13, 4299
DOI: 10.1002/cctc.202100914

Enantioselective Indole Insertion Reactions of α-Carbonyl Sulfoxonium Ylides

Alexandria N. Leveille, Radell Echemendía, Anita E. Mattson and Antonio C. B. Burtoloso

Org. Lett., 2021, 23, 9446
DOI: 10.1021/acs.orglett.1c03627

Gold-Catalyzed Cyclization/Hydroboration of 1,6-Enynes: Synthesis of Bicyclo[3.1.0]hexane Boranes

Guanghui Wang, Yongqiang Wang, Zengzeng Li, Haotian Li, Mingwu Yu, Maofu Pang and Ximei Zhao

Org. Lett., 2022, 24, 9425
DOI: 10.1021/acs.orglett.2c03812

Synthesis of α-Boryl Ketones via Hydration or Oxidation of B(MIDA)-Decorated Alkynes

Zhi-Hao Chen, Xiao-Xuan Su, Qingjiang Li, Jia-Qiang Wu, Tian-Miao Ou and Honggen Wang

Org. Lett., 2023, 25, 1099
DOI: 10.1021/acs.orglett.2c04343

Mechanistic investigation of the [VO(acac)2]-catalyzed acid-functionalization over olefin-functionalization using DFT studies

Fathima Febin Koothradan, Vikiho Wotsa, Payyeri Krishna, P. P. Hiba Sherin and Chinnappan Sivasankar

Inorganica Chimica Acta, 2025, 585, 122750
DOI: 10.1016/j.ica.2025.122750

Modular Access to Diverse Amphoteric α-Boryl Aldehydes or Borylated Heterocycles via Photoredox Catalysis

Jiang-Tao Li, Gang Fang, Guan-Yu Wu and Chun-Xiang Zhuo

ACS Catal., 2023, 13, 12648
DOI: 10.1021/acscatal.3c03474

High-throughput experimentation and machine learning-promoted synthesis of α-phosphoryloxy ketones via Ru-catalyzed P(O)O-H insertion reactions of sulfoxonium ylides

An Lin, Jingyuan Liu, Yougen Xu, Haiting Wu, Yating Chen, Yan Zhang, Lebin Su, Xiaodan Zhao and Kuangbiao Liao

Sci. China Chem., 2025, 68, 679
DOI: 10.1007/s11426-024-2313-5

A Cascade Rh(III)‐catalyzed C−H Activation/Chemodivergent Annulation of N‐carbamoylindoles with Sulfoxonium Ylides for the Synthesis of Dihydropyrimidoindolone and Tricyclic [1,3]Oxazino[3,4‐a]indol‐1‐ones Derivatives

Hui Xie, Mei Zhong, Hua‐Jie Kang, Bing Shu and Shang‐Shi Zhang

Adv Synth Catal, 2021, 363, 1436
DOI: 10.1002/adsc.202001380

Electrochemical Selenylation of Sulfoxonium Ylides for the Synthesis of gem-Diselenides as Antimicrobials against Fungi

Zhongnan Xu, Jiwen Yao, Kaihui Zhong, Shuimu Lin, Xinwei Hu and Zhixiong Ruan

J. Org. Chem., 2023, 88, 5572
DOI: 10.1021/acs.joc.3c00091

Enantioselective Intramolecular Iridium-Catalyzed Cyclopropanation of α-Carbonyl Sulfoxonium Ylides

Lucas Vidal, Pan-Pan Chen, Eva Nicolas, Andrew Hackett, Craig M. Robertson, Kendall N. Houk and Christophe Aïssa

Org. Lett., 2022, 24, 8503
DOI: 10.1021/acs.orglett.2c03396

High‐Throughput Experimentation and Machine Learning‐Assisted Optimization of Iridium‐Catalyzed Cross‐Dimerization of Sulfoxonium Ylides

Yougen Xu, Yadong Gao, Lebin Su, Haiting Wu, Hao Tian, Majian Zeng, Chunqiu Xu, Xinwei Zhu and Kuangbiao Liao

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202313638

Pathway to Construct α-Acyloxy Esters by B(C6F5)3-Catalyzed O–H Insertion of Carboxylic Acids with Sulfoxonium Ylides

Shuran Xu, Qingyao Zhang, Yuanyuan Li, Cankun Luo, Ruizhi Lai, Li Guo, Li Hai, Guanghui Lv and Yong Wu

J. Org. Chem., 2023, 88, 15335
DOI: 10.1021/acs.joc.3c01830

Insertion of Alkylidene Carbenes into B–H Bonds

Ji-Min Yang, Feng-Kai Guo, Yu-Tao Zhao, Qiao Zhang, Ming-Yao Huang, Mao-Lin Li, Shou-Fei Zhu and Qi-Lin Zhou

J. Am. Chem. Soc., 2020, 142, 20924
DOI: 10.1021/jacs.0c09596

Application of Sulfoxonium Ylides or Iodonium Ylides in Rhodium‐Catalyzed Synthesis of Phenanthrenes

Xiao Liu, Bingxin Zhou, Kelu Yan, Jiangwei Wen, Qiuyun Li, Xutong Wang and Xiu Wang

Adv Synth Catal, 2024, 366, 1744
DOI: 10.1002/adsc.202301451

Dirhodium‐Catalyzed Enantioselective B−H Bond Insertion of gem‐Diaryl Carbenes: Efficient Access to gem‐Diarylmethine Boranes

Yu‐Tao Zhao, Yu‐Xuan Su, Xiao‐Yu Li, Liang‐Liang Yang, Ming‐Yao Huang and Shou‐Fei Zhu

Angewandte Chemie, 2021, 133, 24416
DOI: 10.1002/ange.202109447

Progress in the Syntheses of α-Boryl Carbonyl Compounds

Zhihao Chen, Qi Fan, Biaolin Yin, Qingjiang Li and Honggen Wang

Chinese Journal of Organic Chemistry, 2023, 43, 1706
DOI: 10.6023/cjoc202303025

Cyclic Sulfoxonium Ylides: Synthesis and Chemospecific Reactivity in the Catalytic Alkylation of Indoles

Clarice A. D. Caiuby, Lucas Vidal, Antonio C. B. Burtoloso and Christophe Aïssa

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202201643

Sulfoxonium Ylides as Carbene Precursors in Rhodium‐Catalyzed Sommelet‐Hauser Rearrangement for the Synthesis of S/Se‐Containing Compounds

Cankun Luo, Zhiqian Lin, Yingdi Hao, Pengfei Jia, Ruizhi Lai, Li Guo, Yuan Yao and Yong Wu

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300690

Copper-catalyzed N–H insertion reactions from sulfoxonium ylides

Lucas G. Furniel and Antonio C.B. Burtoloso

Tetrahedron, 2020, 76, 131313
DOI: 10.1016/j.tet.2020.131313

Borylfuroxans: Synthesis and Applications

Weibin Xie, Masahiko Hayashi and Ryosuke Matsubara

Org. Lett., 2021, 23, 4317
DOI: 10.1021/acs.orglett.1c01250

Direct synthesis of α-functionalized amides via heteroatom–hydrogen insertion reactions using amide-sulfoxonium ylides

Haiting Wu, Yougen Xu, An Lin, Zhi Wang, Huanjun Chen, Xinwei Zhu, Yadong Gao and Lebin Su

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-54532-3

Ruthenium-Catalyzed Chemoselective N–H Bond Insertion Reactions of 2-Pyridones/7-Azaindoles with Sulfoxonium Ylides

Xiaofeng Liu, Ying Shao and Jiangtao Sun

Org. Lett., 2021, 23, 1038
DOI: 10.1021/acs.orglett.0c04229

Pd-Catalyzed Sequential Formation of C–C Bonds: A New Strategy for the Synthesis of (E)-α,β-Unsaturated Carbonyl Compounds from Sulfoxonium Ylides and 1-Iodo-2-((2-methylallyl)oxy)benzene Compounds

Miao Hu, Ziying Wu, Biao Yao, Jianxiao Li, Wanqing Wu and Huanfeng Jiang

J. Org. Chem., 2021, 86, 11545
DOI: 10.1021/acs.joc.1c01119

Catalysts Based on the C−H⋅⋅⋅M Weak Interaction: Synthesis, Characterization and Catalytic Application of Bis(pyrazolyl)borate Cu(I) Complexes in Carbene Insertion into Heteroatom Hydrogen Bonds

Qianyi Zhao, Qiu‐Yue Yao, Ting Dou, Ting Xu, Jie Zhang and Xuenian Chen

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202200552

Three‐Component α‐Thienylation/Oxylation Cascade of IIII/SVI‐Ylides via Photoinduced EDA Complex Activation

Zelong Du, Li Li and Zhaofeng Wang

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401438

Rhodium‐Catalyzed Direct Vinylene Annulation of Sulfoxonium Ylides and N‐carbamoylindoles with Vinylene Carbonate

Jia‐Lin Song, Lin Xiao, Shao‐Yong Chen, Yi‐Chuan Zheng, Yan‐Zhi Liu, Shang‐Shi Zhang and Bing Shu

Adv Synth Catal, 2023, 365, 1457
DOI: 10.1002/adsc.202300135

Divergent Synthesis of Tetrasubstituted Phenols via [3 + 3] Cycloaddition Reaction of Vinyl Sulfoxonnium Ylides with Cyclopropenones

Shao-Yong Chen, Yao-Fu Zeng, Wen-Xuan Zou, Dan-Ting Shen, Yi-Chuan Zheng, Jia-Lin Song and Shang-Shi Zhang

Org. Lett., 2023, 25, 4286
DOI: 10.1021/acs.orglett.3c01327

Theoretical investigation on switchable [3 + 3] cycloaddition of vinyl sulfoxonnium ylide with cyclopropenone for divergent synthesis of phenol

Nan Lu, Chengxia Miao and Xiaozheng Lan

Computational and Theoretical Chemistry, 2023, 1230, 114373
DOI: 10.1016/j.comptc.2023.114373

Dirhodium‐Catalyzed Enantioselective B−H Bond Insertion of gem‐Diaryl Carbenes: Efficient Access to gem‐Diarylmethine Boranes

Yu‐Tao Zhao, Yu‐Xuan Su, Xiao‐Yu Li, Liang‐Liang Yang, Ming‐Yao Huang and Shou‐Fei Zhu

Angew Chem Int Ed, 2021, 60, 24214
DOI: 10.1002/anie.202109447

Rhodium(III)‐Catalyzed Cross‐Coupling of Sulfoxonium Ylides with Quinoline‐8‐carboxaldehydes for Synthesis of Quinoline‐1,3‐diketones

Xue‐Li Lyu, Shi‐Sheng Huang, Yuan‐Qiong Huang, Hong‐Jian Song, Yu‐Xiu Liu, Yong‐Qiang Li, Shao‐Xiang Yang and Qing‐Min Wang

Asian J Org Chem, 2021, 10, 176
DOI: 10.1002/ajoc.202000581

Iridium‐Catalyzed [4+2] Annulations of β‐Keto Sulfoxonium Ylides and o‐Phenylenediamines: Mild and Facile Synthesis of Quinoxaline Derivatives

Xiao‐Tong Wang, Jia‐Lin Song, Mei Zhong, Hua‐Jie Kang, Hui Xie, Tong Che, Bing Shu, Dongming Peng, Luyong Zhang and Shang‐Shi Zhang

Eur J Org Chem, 2020, 2020, 3635
DOI: 10.1002/ejoc.202000411

Iridium-Catalyzed Diastereo- and Enantioselective [4 + 1] Cycloaddition of Hydroxyallyl Anilines with Sulfoxonium Ylides

Chunlan He, Yaping Tang, Shengbiao Tang and Jiangtao Sun

Org. Lett., 2023, 25, 4621
DOI: 10.1021/acs.orglett.3c01217

Bidirectional Iterative Approach to Sequence-Defined Unsaturated Oligoesters

Srashti Bhardwaj, Dinesh Kumar Gopalakrishnan, Divya Garg and Janakiram Vaitla

JACS Au, 2023, 3, 252
DOI: 10.1021/jacsau.2c00641

[Cp*IrCl2]2-Catalyzed Amidocarbonation of Olefins with Sulfoxonium Ylides toward Functionalized Isoindolin-1-ones

Qi Yang, Junxue Bai, Han Yang, Yang Yao, Yingming Yao, Jianwei Sun and Song Sun

Org. Lett., 2023, 25, 7148
DOI: 10.1021/acs.orglett.3c02654

Unprecedented Dual Radical Initiation in Visible-Light Photoredox-Catalyzed X–H (X = Si and B) Insertions of Sulfoxonium Ylides

Mengyu Xu, Yujing Wang, Rui Fu and Xiaoguang Bao

ACS Catal., 2025, 15, 7003
DOI: 10.1021/acscatal.5c01823

Catalytic Hydrogen Transfer Reactions

Shou‐Fei Zhu

Chin. J. Chem., 2021, 39, 3211
DOI: 10.1002/cjoc.202100449

A Platform for the Synthesis of Diverse Phosphonyl and Thiofunctionalized Sulfoxonium Ylides

Wen-Xuan Zou, Qiong Hu, Dan-Ting Shen, Wen-Rong Wu, Jiaohang Wei, Zi-Feng Yang, Mei-Zhu Bao, Xiang Liu and Shang-Shi Zhang

Org. Lett., 2024, 26, 5811
DOI: 10.1021/acs.orglett.4c02000

An Improved Protocol for the Synthesis of Carbonyl Sulfoxonium Ylides

João H. de Souza, Jorge A. M. Vargas and Antonio C. B. Burtoloso

Synthesis, 2024, 56, 758
DOI: 10.1055/a-2222-3695

Stereoselective ZnCl2-Catalyzed B–H Bond Insertion of Vinyl Carbenes Generated from Cyclopropenes for the Synthesis of Allylboranes

Ximei Zhao, Jian Jia, Zengzeng Li, Haotian Li, Yongqiang Wang and Guanghui Wang

J. Org. Chem., 2022, 87, 13053
DOI: 10.1021/acs.joc.2c01568

Enantioselective S−H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides

Patrícia B. Momo, Alexandria N. Leveille, Elliot H. E. Farrar, Matthew N. Grayson, Anita E. Mattson and Antonio C. B. Burtoloso

Angewandte Chemie, 2020, 132, 15684
DOI: 10.1002/ange.202005563

Copper-Catalyzed Cyclization of N-Propargyl Ynamides with Borane Adducts through B–H Bond Insertion

Guang-Yu Zhu, Tong-Yi Zhai, Xiao Li, Chong-Yang Shi, Xin-Qi Zhu and Long-Wu Ye

Org. Lett., 2021, 23, 8067
DOI: 10.1021/acs.orglett.1c03092

Additive-free synthesis of β-keto phosphorodithioates via geminal hydro-phosphorodithiolation of sulfoxonium ylides with P4S10 and alcohols

Jindong Hao, Yufen Lv, Shuyue Tian, Chao Ma, Wenxiu Cui, Huilan Yue, Wei Wei and Dong Yi

Chinese Chemical Letters, 2024, 35, 109513
DOI: 10.1016/j.cclet.2024.109513

High‐Throughput Experimentation and Machine Learning‐Assisted Optimization of Iridium‐Catalyzed Cross‐Dimerization of Sulfoxonium Ylides

Yougen Xu, Yadong Gao, Lebin Su, Haiting Wu, Hao Tian, Majian Zeng, Chunqiu Xu, Xinwei Zhu and Kuangbiao Liao

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202313638

Divergent Construction of α,α-Difunctionalized Ketones via [1,2]-Sigmatropic Rearrangement/Alkylation-Hydroxylation/Dialkylation of I(III)/S(VI) Ylides

Shang-Shi Zhang, Jiaohang Wei, Qiong Hu, Zi-Feng Yang, Wen-Xuan Zou, Dan-Ting Shen, Mei-Zhu Bao and Xiang Liu

Org. Lett., 2025, 27, 3709
DOI: 10.1021/acs.orglett.5c00852

Electrochemical synthesis of α-thiocyanato-α-carbonyl sulfoxonium ylides

Li-Ming Zhang, Da-Fu Yuan, Zi-Hao Fu, Hao-Ran Li, Ming Li, Li-Rong Wen and Lin-Bao Zhang

Tetrahedron Letters, 2022, 109, 154165
DOI: 10.1016/j.tetlet.2022.154165

Lithium Bromide-Promoted Formal C(sp3)–H Bond Insertion Reactions of β-Carbonyl Esters with Sulfoxonium Ylides to Synthesize 1,4-Dicarbonyl Compounds

Hailin Guo, Yuhao Ding, Jingwen Fan, Zhiyong Li and Guolin Cheng

J. Org. Chem., 2024, 89, 6974
DOI: 10.1021/acs.joc.4c00336

Enantioselective S−H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides

Patrícia B. Momo, Alexandria N. Leveille, Elliot H. E. Farrar, Matthew N. Grayson, Anita E. Mattson and Antonio C. B. Burtoloso

Angew Chem Int Ed, 2020, 59, 15554
DOI: 10.1002/anie.202005563

Perhaloacylation of α-Carbonyl Sulfoxonium Ylides

Varun Anand and Namrata Rastogi

J. Org. Chem., 2025, 90, 2479
DOI: 10.1021/acs.joc.4c03067

Isocyanide-Based Multicomponent Reaction: Cascade α-Acyloxylation/Carboxamidation and [3 + 1+1] Cyclization of I(III)/S(VI)-Ylides

Dan-Ting Shen, Wen-Rong Wu, Wen-Xuan Zou, Qiong Hu, Jiaohang Wei, Mei-Zhu Bao, Xiang Liu and Shang-Shi Zhang

Org. Lett., 2024, 26, 6263
DOI: 10.1021/acs.orglett.4c02255

Catalyst‐Free Direct Hydrocarbonation of Terminal Alkynes Toward E‐Alkene Substituted Stabilized Sulfoxonium Ylides

Haiting Wu, Yougen Xu, An Lin, Jingyuan Liu, Huanjun Chen, Shimin Xie and Lebin Su

Advanced Science, 2025, 12
DOI: 10.1002/advs.202417362