Rupesh E. Patre, Sanjib Mal, Pankaj R. Nilkanth, Sujit K. Ghorai, Sudhindra H. Deshpande, Myriem El Qacemi, Tomas Smejkal, Sitaram Pal and Bhanu N. Manjunath

Chem. Commun., 2017, 53, 2382
DOI: 10.1039/C6CC07679C

Synthesis of silyl formates, formamides, and aldehydes via solvent-free organocatalytic hydrosilylation of CO2

Takumi Murata, Mahoko Hiyoshi, Manussada Ratanasak, Jun-ya Hasegawa and Tadashi Ema

Chem. Commun., 2020, 56, 5783
DOI: 10.1039/D0CC01371D

Triazinetriamine-derived porous organic polymer-supported copper nanoparticles (Cu-NPs@TzTa-POP): an efficient catalyst for the synthesis of N-methylated products via CO2 fixation and primary carbamates from alcohols and urea

Najirul Haque, Surajit Biswas, Priyanka Basu, Imdadul Haque Biswas, Resmin Khatun, Aslam Khan and Sk Manirul Islam

New J. Chem., 2020, 44, 15446
DOI: 10.1039/D0NJ02798G

Tungstate catalysis: pressure-switched 2- and 6-electron reductive functionalization of CO2 with amines and phenylsilane

Mei-Yan Wang, Ning Wang, Xiao-Fang Liu, Chang Qiao and Liang-Nian He

Green Chem., 2018, 20, 1564
DOI: 10.1039/C7GC03416D

Catalyst-free reductive cyclization of bis(2-aminophenyl) disulfide with CO2 in the presence of BH3NH3 to synthesize 2-unsubstituted benzothiazole derivatives

Xiao Li, Zhenbao Liu, Hailong Hong, Limin Han and Ning Zhu

RSC Adv., 2022, 12, 18107
DOI: 10.1039/D2RA03134E

Catalyst-free CO2 hydrogenation with BH3NH3 in water: DFT mechanistic insights

Zheng-Wang Qu, Hui Zhu, Rainer Streubel and Stefan Grimme

Phys. Chem. Chem. Phys., 2022, 24, 14159
DOI: 10.1039/D2CP00590E

Eco-friendly acetylcholine-carboxylate bio-ionic liquids for controllable N-methylation and N-formylation using ambient CO2 at low temperatures

Wenfeng Zhao, Xiaoping Chi, Hu Li, Jian He, Jingxuan Long, Yufei Xu and Song Yang

Green Chem., 2019, 21, 567
DOI: 10.1039/C8GC03549K

SelectiveN-formylation/N-methylation of amines andN-formylation of amides and carbamates with carbon dioxide and hydrosilanes: promotion of the basic counter anions of the zinc catalyst

Qiao Zhang, Xiao-Tao Lin, Norihisa Fukaya, Tadahiro Fujitani, Kazuhiko Sato and Jun-Chul Choi

Green Chem., 2020, 22, 8414
DOI: 10.1039/D0GC02890H

Transformative reduction of carbon dioxide through organocatalysis with silanes

Ria Ayu Pramudita and Ken Motokura

Green Chem., 2018, 20, 4834
DOI: 10.1039/C8GC02052C

Selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes and methylamines from cyclic amines and CO2/H2 catalyzed by an ionic liquid–Pd/C system

Ruipeng Li, Yanfei Zhao, Huan Wang, Junfeng Xiang, Yunyan Wu, Bo Yu, Buxing Han and Zhimin Liu

Chem. Sci., 2019, 10, 9822
DOI: 10.1039/C9SC03242H

Catalyst-free N-formylation of amines using BH3NH3 and CO2 under mild conditions

Tian-Xiang Zhao, Gao-Wen Zhai, Jian Liang, Ping Li, Xing-Bang Hu and You-Ting Wu

Chem. Commun., 2017, 53, 8046
DOI: 10.1039/C7CC03860G

From CO2 activation to catalytic reduction: a metal-free approach

Sreejyothi P. and Swadhin K. Mandal

Chem. Sci., 2020, 11, 10571
DOI: 10.1039/D0SC03528A

A Keggin-based hybrid solid emerged as a promising candidate for CO2-mediated photocatalytic N-formylation of amines

Parul Sood, Sakshi Bhatt, Harshita Bagdwal, Arti Joshi, Ashi Singh, Suman L. Jain and Monika Singh

J. Mater. Chem. A, 2024, 12, 19168
DOI: 10.1039/D4TA02432J

Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the perrhenate anion

Danny S. Morris, Catherine Weetman, Julian T. C. Wennmacher, Mirza Cokoja, Markus Drees, Fritz E. Kühn and Jason B. Love

Catal. Sci. Technol., 2017, 7, 2838
DOI: 10.1039/C7CY00772H

Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO2, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Yu Lu, Zhong-Hua Gao, Xiang-Yu Chen, Jiandong Guo, Zheyuan Liu, Yanfeng Dang, Song Ye and Zhi-Xiang Wang

Chem. Sci., 2017, 8, 7637
DOI: 10.1039/C7SC00824D

Diphenylsilane as a coupling reagent for amide bond formation

Morgane Sayes and André B. Charette

Green Chem., 2017, 19, 5060
DOI: 10.1039/C7GC02643A

Synthesis of formamides containing unsaturated groups by N-formylation of amines using CO2 with H2

Hangyu Liu, Qingqing Mei, Qingling Xu, Jinliang Song, Huizhen Liu and Buxing Han

Green Chem., 2017, 19, 196
DOI: 10.1039/C6GC02243J

Mechanism of iron complexes catalyzed in the N-formylation of amines with CO2 and H2: the superior performance of N–H ligand methylated complexes

Xinyu Shen, Wenjuan Wang, Qiong Wang, Jianbiao Liu, Fang Huang, Chuanzhi Sun, Chong Yang and Dezhan Chen

Phys. Chem. Chem. Phys., 2021, 23, 16675
DOI: 10.1039/D1CP00608H

Theoretical study of reductive CO2 functionalization with amines and phenylsilanes: what kind of solvents can be used as catalysts?

Pan Du, Xinyue Liu, Xinyi Dong, Nianyang Li, Rui Liu, Li Li and Jiyang Zhao

Catal. Sci. Technol., 2023, 13, 5333
DOI: 10.1039/D3CY00682D

Recent advances in N-formylation of amines and nitroarenes using efficient (nano)catalysts in eco-friendly media

Mahmoud Nasrollahzadeh, Narjes Motahharifar, Mohaddeseh Sajjadi, Amir Moradzadeh Aghbolagh, Mohammadreza Shokouhimehr and Rajender S. Varma

Green Chem., 2019, 21, 5144
DOI: 10.1039/C9GC01822K

Co(dppbsa)-catalyzed reductive N,N-dimethylation of nitroaromatics with CO2 and hydrosilane

Shuang-Shuang Ma, Rui Sun, Zi-Heng Zhang, Peng-Xin Guan, Jin-Qing Lin, Chun-Shan Li and Bao-Hua Xu

Green Chem., 2023, 25, 8625
DOI: 10.1039/D3GC02517A

Catalyst-free N-methylation of amines using CO2

Huiying Niu, Lijun Lu, Renyi Shi, Chien-Wei Chiang and Aiwen Lei

Chem. Commun., 2017, 53, 1148
DOI: 10.1039/C6CC09072A

The dilemma between acid and base catalysis in the synthesis of benzimidazole from o-phenylenediamine and carbon dioxide

Martin Hulla, Simon Nussbaum, Alexy R. Bonnin and Paul J. Dyson

Chem. Commun., 2019, 55, 13089
DOI: 10.1039/C9CC06156H

DIC–borane-catalyzed selective methylation of primary amines with CO2 using boranes as reducing agents

He Zhang, Yanmeng Zhang and Ke Gao

Org. Chem. Front., 2023, 10, 2491
DOI: 10.1039/D3QO00058C

N-Formylation of amines utilizing CO2by a heterogeneous metal–organic framework supported single-site cobalt catalyst

Rajashree Newar, Rahul Kalita, Naved Akhtar, Neha Antil, Manav Chauhan and Kuntal Manna

Catal. Sci. Technol., 2022, 12, 6795
DOI: 10.1039/D2CY01231F

OrganocatalyticN-formylation of amines by CO2in batch and continuous flow

Nicola Zanda, Ludovica Primitivo, Moreshwar Chaudhari, Arjan W. Kleij and Miquel À. Pericàs

Org. Chem. Front., 2023, 10, 375
DOI: 10.1039/D2QO01711C

Biomass-derived N-doped porous carbon: an efficient metal-free catalyst for methylation of amines with CO2

Feiying Tang, Liqiang Wang and You-Nian Liu

Green Chem., 2019, 21, 6252
DOI: 10.1039/C9GC03277K

Direct N-formylation of nitroarenes with CO2

Ni Shen, Shi-Jing Zhai, Chi Wai Cheung and Jun-An Ma

Chem. Commun., 2020, 56, 9620
DOI: 10.1039/D0CC03098H

Deoxygenative CO2 conversions with triphenylborane and phenylsilane in the presence of secondary amines or nitrogen-containing aromatics

Takumi Murata, Mahoko Hiyoshi, Shinsuke Maekawa, Yuta Saiki, Manussada Ratanasak, Jun-ya Hasegawa and Tadashi Ema

Green Chem., 2022, 24, 2385
DOI: 10.1039/D1GC04599G

A bifunctional cationic porous organic polymer based on a Salen-(Al) metalloligand for the cycloaddition of carbon dioxide to produce cyclic carbonates

Tao-Tao Liu, Jun Liang, Yuan-Biao Huang and Rong Cao

Chem. Commun., 2016, 52, 13288
DOI: 10.1039/C6CC07662A

Tetrabutylphosphonium-Based Ionic Liquid Catalyzed CO2 Transformation at Ambient Conditions: A Case of Synthesis of α-Alkylidene Cyclic Carbonates

Yunyan Wu, Yanfei Zhao, Ruipeng Li, Bo Yu, Yu Chen, Xinwei Liu, Cailing Wu, Xiaoying Luo and Zhimin Liu

ACS Catal., 2017, 7, 6251
DOI: 10.1021/acscatal.7b01422

An efficient method for the N-formylation of amines under catalyst- and additive-free conditions

Zhuo-Wei Xu, Wen-Yi Xu, Xiao-Jun Pei, Fei Tang and Yi-Si Feng

Tetrahedron Letters, 2019, 60, 1254
DOI: 10.1016/j.tetlet.2019.03.071

Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines

Yue Hu, Jinliang Song, Chao Xie, Haoran Wu, Zhenpeng Wang, Tao Jiang, Lei Wu, Yu Wang and Buxing Han

ACS Sustainable Chem. Eng., 2018, 6, 11228
DOI: 10.1021/acssuschemeng.8b03245

Photochemical fixation of carbon dioxide for N-formylation of amine using Cu(II) embedded BiVO4 nanocomposite under visible light

Pankaj Kumar Prajapati, Sandhya Saini, Neha Nandal and Suman L. Jain

Journal of CO2 Utilization, 2021, 45, 101402
DOI: 10.1016/j.jcou.2020.101402

A polymeric ionic liquid catalyst for the N-formylation and N-methylation of amines using CO2/PhSiH3

Aswin Gopakumar, Loris Lombardo, Zhaofu Fei, Serhii Shyshkanov, Dmitry Vasilyev, Arunraj Chidambaram, Kyriakos Stylianou, Andreas Züttel and Paul J. Dyson

Journal of CO2 Utilization, 2020, 41, 101240
DOI: 10.1016/j.jcou.2020.101240

Homogeneous Catalysis in N‐Formylation/N‐Methylation Utilizing Carbon Dioxide as the C1 Source

Indranil Dutta, Sandeep Suryabhan Gholap, Mohammad Misbahur Rahman, Davin Tan, Lili Zhang, Shashikant U. Dighe and Kuo‐Wei Huang

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400497

Covalent organic framework-supported Zn single atom catalyst for highly efficient N-formylation of amines with CO2 under mild conditions

Qiang Cao, Long-Long Zhang, Chang Zhou, Jing-Hui He, Antonio Marcomini and Jian-Mei Lu

Applied Catalysis B: Environmental, 2021, 294, 120238
DOI: 10.1016/j.apcatb.2021.120238

CuH-Catalyzed Selective N-Methylation of Amines Using Paraformaldehyde as a C1 Source

Diedie Wang, Wanglv Lang, Wan Wang, Qizhuang Zou, Chunliang Yang, Fei Liu and Tianxiang Zhao

ACS Omega, 2023, 8, 30640
DOI: 10.1021/acsomega.3c04332

Reductive Coupling of CO2, Primary Amine, and Aldehyde at Room Temperature: A Versatile Approach to Unsymmetrically N,N‐Disubstituted Formamides

Zhengang Ke, Leiduan Hao, Xiang Gao, Hongye Zhang, Yanfei Zhao, Bo Yu, Zhenzhen Yang, Yu Chen and Zhimin Liu

Chemistry A European J, 2017, 23, 9721
DOI: 10.1002/chem.201701420

Recent advances in organic synthesis with CO2 as C1 synthon

Gaoqing Yuan, Caorong Qi, Wanqing Wu and Huanfeng Jiang

Current Opinion in Green and Sustainable Chemistry, 2017, 3, 22
DOI: 10.1016/j.cogsc.2016.11.006

Photoinduced Oxidative Formylation of N,N-Dimethylanilines with Molecular Oxygen without External Photocatalyst

Shuai Yang, Pinhua Li, Zhihui Wang and Lei Wang

Org. Lett., 2017, 19, 3386
DOI: 10.1021/acs.orglett.7b01230

N-formylation and N-methylation of amines using metal-free N-heterocyclic carbene catalysts and CO2 as carbon source

Felix D Bobbink, Shoubhik Das and Paul J Dyson

Nat Protoc, 2017, 12, 417
DOI: 10.1038/nprot.2016.175

Synthesis of New Class of Copper(II) Complex-Based FeNi3/KCC-1 for the N-Formylation of Amines Using Dihydrogen and Carbon Dioxide

Rahele Zhiani, Seyed Mahdi Saadati, Mahboobeh Zahedifar and Seyed Mohsen Sadeghzadeh

Catal Lett, 2018, 148, 2487
DOI: 10.1007/s10562-018-2475-4

N-Methyl-N-arylformamides: Synthesis and Interaction of with Carbonic Anhydrase (PDB: 3FW3) and Nuclease (PDB: 6O70) Enzymes via In Silico Molecular Docking

R. A. Rather, B. A. Lone, G. Khanum and T. Ara

Russ J Gen Chem, 2023, 93, 175
DOI: 10.1134/S1070363223010231

Ionic Liquid-Promoted Formylation of N(sp2)-Heteroarenes with CO2/H2 over Pd/C

Ruipeng Li, Yanfei Zhao, Huan Wang, Dongyang Li, Yunyan Wu, Hongye Zhang, Minhao Tang and Zhimin Liu

ACS Sustainable Chem. Eng., 2021, 9, 2507
DOI: 10.1021/acssuschemeng.0c07903

Bimolecular reduction of carbon dioxide: double synthons for alkynes trifunctionalization

Wenfang Xiong, Xiaobin Tan, Hongjian Liu, Baiyao Zhu, Jinwu Zhao, Jianxiao Li, Chaorong Qi and Huanfeng Jiang

Sci. China Chem., 2024, 67, 841
DOI: 10.1007/s11426-023-1804-4

Guanidine-Catalyzed Reductive Amination of Carbon Dioxide with Silanes: Switching between Pathways and Suppressing Catalyst Deactivation

Rachel L. Nicholls, James A. McManus, Christopher M. Rayner, José A. Morales-Serna, Andrew J. P. White and Bao N. Nguyen

ACS Catal., 2018, 8, 3678
DOI: 10.1021/acscatal.7b04108

Zinc Powder Catalysed Formylation and Urealation of Amines Using CO2 as a C1 Building Block†

Chongyang Du and Yaofeng Chen

Chin. J. Chem., 2020, 38, 1057
DOI: 10.1002/cjoc.202000072

Zinc phthalocyanine as an efficient catalyst for halogen-free synthesis of formamides from amines via carbon dioxide hydrosilylation under mild conditions

Rongchang Luo, Xiaowei Lin, Jing Lu, Xiantai Zhou and Hongbing Ji

Chinese Journal of Catalysis, 2017, 38, 1382
DOI: 10.1016/S1872-2067(17)62877-8

Formate-Catalyzed Selective Reduction of Carbon Dioxide to Formate Products Using Hydrosilanes

Ken Motokura, Chihiro Nakagawa, Ria Ayu Pramudita and Yuichi Manaka

ACS Sustainable Chem. Eng., 2019, 7, 11056
DOI: 10.1021/acssuschemeng.9b02172

Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex

Hanna H. Cramer, Basujit Chatterjee, Thomas Weyhermüller, Christophe Werlé and Walter Leitner

Angewandte Chemie, 2020, 132, 15804
DOI: 10.1002/ange.202004463

Decarboxylative N-Formylation of Amines with Glyoxylic Acid Promoted by H2O2

Jiwei Wu, Yuting Zhang, Jingyi Yang, Lingxiang Yu, Shaoqing Zhang, Jie Zhou, Zirong Li, Xiaolan Xu and Huajian Xu

J. Org. Chem., 2023, 88, 13590
DOI: 10.1021/acs.joc.3c01270

Electrochemical N-Formylation of Amines via Decarboxylation of Glyoxylic Acid

Dian-Zhao Lin and Jing-Mei Huang

Org. Lett., 2018, 20, 2112
DOI: 10.1021/acs.orglett.8b00698

Synthesis of chemicals using CO2 as a building block under mild conditions

Zhenzhen Yang, Xiang Gao and Zhimin Liu

Current Opinion in Green and Sustainable Chemistry, 2016, 1, 13
DOI: 10.1016/j.cogsc.2016.06.001

Recyclable polymerized Lewis acid poly-BPh(C6F5)2 catalyzed selective N-formylation and N-methylation of amines with carbon dioxide and phenylsilanes

Gaowen Zhai, Qiang Liu, Jialan Ji, Youting Wu, Jiao Geng and Xingbang Hu

Journal of CO2 Utilization, 2022, 61, 102052
DOI: 10.1016/j.jcou.2022.102052

Bifunctional Heterogeneous Ru/POP Catalyst Embedded with Alkali for the N-Formylation of Amine and CO2

Guoqing Wang, Miao Jiang, Guangjun Ji, Zhao Sun, Cunyao Li, Li Yan and Yunjie Ding

ACS Sustainable Chem. Eng., 2020, 8, 5576
DOI: 10.1021/acssuschemeng.9b07471

Metallosalen‐Based Ionic Porous Polymers as Bifunctional Catalysts for the Conversion of CO2 into Valuable Chemicals

Rongchang Luo, Yaju Chen, Qian He, Xiaowei Lin, Qihang Xu, Xiaohui He, Wuying Zhang, Xiantai Zhou and Hongbing Ji

ChemSusChem, 2017, 10, 1526
DOI: 10.1002/cssc.201601846

CO2 as a C1 Source: B(C6F5)3-Catalyzed Cyclization of o-Phenylene-diamines To Construct Benzimidazoles in the Presence of Hydrosilane

Zhenbei Zhang, Qiangsheng Sun, Chungu Xia and Wei Sun

Org. Lett., 2016, 18, 6316
DOI: 10.1021/acs.orglett.6b03030

Cooperative Catalytic Activation of Si−H Bonds: CO2‐Based Synthesis of Formamides from Amines and Hydrosilanes under Mild Conditions

Rongchang Luo, Xiaowei Lin, Yaju Chen, Wuying Zhang, Xiantai Zhou and Hongbing Ji

ChemSusChem, 2017, 10, 1224
DOI: 10.1002/cssc.201601490

The Base‐Promoted Annulation of 2‐Hydrazinyl Pyridine and CO2 toward Triazolones

Xiaopeng Wu, Song Sun, Bingbing Wang and Jiang Cheng

Adv Synth Catal, 2017, 359, 3855
DOI: 10.1002/adsc.201700869

Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines

Xiao‐Fang Liu, Xiao‐Ya Li, Chang Qiao, Hong‐Chen Fu and Liang‐Nian He

Angewandte Chemie, 2017, 129, 7533
DOI: 10.1002/ange.201702734

K2S2O8-Mediated Denitrogenative Formal Transformylation of Amines with Formylhydrazine in Water

Anjali Gupta and Joydev K. Laha

Org. Lett., 2024, 26, 10013
DOI: 10.1021/acs.orglett.4c03870

A Titanium Dioxide Supported Gold Nanoparticle Catalyst for the Selective N‐Formylation of Functionalized Amines with Carbon Dioxide and Hydrogen

Takato Mitsudome, Teppei Urayama, Shu Fujita, Zen Maeno, Tomoo Mizugaki, Koichiro Jitsukawa and Kiyotomi Kaneda

ChemCatChem, 2017, 9, 3632
DOI: 10.1002/cctc.201700726

Homogeneous Catalytic Reduction of CO2 with Silicon‐Hydrides, State of the Art

Francisco J. Fernández‐Alvarez and Luis A. Oro

ChemCatChem, 2018, 10, 4783
DOI: 10.1002/cctc.201800699

N-Formylation of Carbon Dioxide and Amines with EDTA as a Recyclable Catalyst under Ambient Conditions

Qiqi Zhou, Yu Chen, Xuexin Yuan, Hai-Jian Yang, Qingqing Jiang, Juncheng Hu and Cun-Yue Guo

Catalysts, 2024, 14, 492
DOI: 10.3390/catal14080492

Solvent- and catalyst-freeN-formylations of amines at ambient condition: Exploring the usability of aromatic formates asN-formylating agents

Shaikh Batuta and Naznin Ara Begum

Synthetic Communications, 2017, 47, 137
DOI: 10.1080/00397911.2016.1255334

DBU‐Catalyzed Selective N‐Methylation and N‐Formylation of Amines with CO2 and Polymethylhydrosiloxane

Gang Li, Jie Chen, Dao‐Yong Zhu, Ye Chen and Ji‐Bao Xia

Adv Synth Catal, 2018, 360, 2364
DOI: 10.1002/adsc.201800140

Fully-automated radiosynthesis of the amyloid tracer [11C] PiB via direct [11C]CO2 fixation-reduction

Pablo Buccino, Eduardo Savio and Williams Porcal

EJNMMI radiopharm. chem., 2019, 4
DOI: 10.1186/s41181-019-0065-4

Catalyst-free fixation of carbon dioxide into value-added chemicals: a review

Cong Chien Truong and Dinesh Kumar Mishra

Environ Chem Lett, 2021, 19, 911
DOI: 10.1007/s10311-020-01121-7

Mechanistic Insights on the Functionalization of CO2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate‐Functionalized Bis‐NHC Catalyst

Ana I. Ojeda‐Amador, Julen Munarriz, Pablo Alamán‐Valtierra, Víctor Polo, Raquel Puerta‐Oteo, M. Victoria Jiménez, Francisco J. Fernández‐Alvarez and Jesús J. Pérez‐Torrente

ChemCatChem, 2019, 11, 5524
DOI: 10.1002/cctc.201901687

Manganese(I) Catalyzed CO2 Reduction Processes in Homogenous Phase

Sylwia Kostera and Luca Gonsalvi

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301391

Crown ether as organocatalyst for reductive upgrading of CO2 to N-containing benzoheterocyclics and N-formamides

Ruxu Yao, Youjie Li, Jiahuan Wang, Jinzhu Chen and Yisheng Xu

Journal of Catalysis, 2023, 418, 78
DOI: 10.1016/j.jcat.2023.01.005

Chemical fixation of CO2 with aniline derivatives: A new avenue to the synthesis of functionalized azole compounds (A review)

Esmail Vessally, Khadijeh Didehban, Mirzaagha Babazadeh, Akram Hosseinian and Ladan Edjlali

Journal of CO2 Utilization, 2017, 21, 480
DOI: 10.1016/j.jcou.2017.08.013

The DMSO-Catalyzed CO2 Reduction with 9-BBN as a Source for the Selective N-Formylation, Room Temperature N-Methylation of Amines, N-Hydroxymethylation of Heterocycles, and C–N Couplings

Ashok Kumar, Rohit Gupta and Ganesan Mani

J. Org. Chem., 2025, 90, 10316
DOI: 10.1021/acs.joc.5c00965

A green, efficient, and rapid procedure for the hydrogenation of nitroarenes to formanilides in water

Yingying Wang, Zhajun Zhan, Yang Zhou, Min Lei and Lihong Hu

Monatsh Chem, 2018, 149, 527
DOI: 10.1007/s00706-017-2071-0

Dihydrolevoglucosenone as a bio-based catalytic solvent for efficient reductive-transformation of CO2 with amines into formamides and benzothiazoles

Haitao Yu, Dongkun Yu, Zhimin Xue, Baolong Zhang and Tiancheng Mu

Chemical Engineering Journal, 2022, 431, 133397
DOI: 10.1016/j.cej.2021.133397

Recent Advances in Homogeneous Carbonylation Using CO2 as CO Surrogate

Lu Wang, Wei Sun and Chao Liu

Chin. J. Chem., 2018, 36, 353
DOI: 10.1002/cjoc.201700746

Base-assisted transfer hydrogenation of CO2 to formate with ammonia borane in water under mild conditions

Tianxiang Zhao, Cheng Li, Xingbang Hu, Fei Liu and Youting Wu

International Journal of Hydrogen Energy, 2021, 46, 15716
DOI: 10.1016/j.ijhydene.2021.02.015

Co2 Be a Catalyst? Yes, Evidence from N-Formylation of Aliphatic Amines with Dmf in Presence of Co2

Xiao-Chao Chen, Lin Guo, Yin-Qing Yao, Kai-Chun Zhao, Yong Lu and Ye Liu

SSRN Journal, 2022
DOI: 10.2139/ssrn.4010457

DMF-promoted reductive functionalization of CO2 with secondary amines and phenylsilane to methylamines

Xiao-Fang Liu, Chang Qiao, Xiao-Ya Li and Liang-Nian He

Pure and Applied Chemistry, 2018, 90, 1099
DOI: 10.1515/pac-2017-0304

Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes

Jefferson Guzmán, Adrián Torguet, Pilar García-Orduña, Fernando J. Lahoz, Luis A. Oro and Francisco J. Fernández-Alvarez

Journal of Organometallic Chemistry, 2019, 897, 50
DOI: 10.1016/j.jorganchem.2019.06.010

Iron-catalyzed reductive strecker reaction

Fachao Yan, Zijun Huang, Chen-Xia Du, Jian-Fei Bai and Yuehui Li

Journal of Catalysis, 2021, 395, 188
DOI: 10.1016/j.jcat.2021.01.003

Recent Advances in the Protection of Amine Functionality: A Review

Jyoti Omprakash Rathi and Ganapati Subray Shankarling

ChemistrySelect, 2020, 5, 6861
DOI: 10.1002/slct.202000764

Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex

Hanna H. Cramer, Basujit Chatterjee, Thomas Weyhermüller, Christophe Werlé and Walter Leitner

Angew Chem Int Ed, 2020, 59, 15674
DOI: 10.1002/anie.202004463

Bis(N‐Heterocyclic Carbene) Manganese(I) Complexes in Catalytic N‐Formylation/N‐Methylation of Amines Using Carbon Dioxide and Phenylsilane

Chiara Masaro, Giammarco Meloni, Marco Baron, Claudia Graiff, Cristina Tubaro and Beatriz Royo

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302273

Fluoride‐Catalyzed Methylation of Amines by Reductive Functionalization of CO2 with Hydrosilanes

Xiao‐Fang Liu, Ran Ma, Chang Qiao, Han Cao and Liang‐Nian He

Chemistry A European J, 2016, 22, 16489
DOI: 10.1002/chem.201603688

Photocatalytic promoting dimethylformamide (DMF) decomposition to in-situ generation of self-supplied CO for carbonylative Suzuki reaction

Xue Feng and Zhaohui Li

Journal of Photochemistry and Photobiology A: Chemistry, 2017, 337, 19
DOI: 10.1016/j.jphotochem.2017.01.002

Natural Product Glycine Betaine as an Efficient Catalyst for Transformation of CO2 with Amines to Synthesize N-Substituted Compounds

Chao Xie, Jinliang Song, Haoran Wu, Baowen Zhou, Congyi Wu and Buxing Han

ACS Sustainable Chem. Eng., 2017, 5, 7086
DOI: 10.1021/acssuschemeng.7b01287

Iron‐Rich Natural Mineral Gibeon Meteorite Catalyzed N‐formylation of Amines using CO2 as the C1 Source

Aswin Gopakumar, Ismail Akçok, Loris Lombardo, Florian Le Formal, Arnaud Magrez, Kevin Sivula and Paul J. Dyson

ChemistrySelect, 2018, 3, 10271
DOI: 10.1002/slct.201802646

Mesoporous Sn(IV) Doping DFNS Supported BaMnO3 Nanoparticles for Formylation of Amines Using Carbon Dioxide

Jie Yang, Liujie Wang, Aili Sun and Rahele Zhiani

Catal Lett, 2021, 151, 573
DOI: 10.1007/s10562-020-03307-8

Graphitic Carbon Nitride as Photocatalyst for the Direct Formylation of Anilines

Giuseppe Sportelli, Gaia Grando, Manuela Bevilacqua, Giacomo Filippini, Michele Melchionna and Paolo Fornasiero

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301718

Synthesis of benzimidazoles from o -phenylenediamines and DMF derivatives in the presence of PhSiH 3

Jianhua Zhu, Zhenbei Zhang, Chengxia Miao, Wei Liu and Wei Sun

Tetrahedron, 2017, 73, 3458
DOI: 10.1016/j.tet.2017.05.018

Triethylamine Catalyzed Reductive CO2 to Form N‐Formylation of Amines and Hydrazides

Xiu‐Zhi Wei, Qiqi Lu, Jianguo Liu and Longlong Ma

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202201727

Iron‐Catalyzed Selective N‐Methylation and N‐Formylation of Amines with CO2

Wen‐Duo Li, Dao‐Yong Zhu, Gang Li, Jie Chen and Ji‐Bao Xia

Adv Synth Catal, 2019, 361, 5098
DOI: 10.1002/adsc.201900906

Sulfonate-Grafted Metal–Organic Frameworks for Reductive Functionalization of CO2 to Benzimidazoles and N-Formamides

Zecheng Ye and Jinzhu Chen

ACS Catal., 2021, 11, 13983
DOI: 10.1021/acscatal.1c03329

Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO2 Fixation Reactions

Piyali Bhanja, Arindam Modak and Asim Bhaumik

Chemistry A European J, 2018, 24, 7278
DOI: 10.1002/chem.201800075

Efficient N-formylation of carbon dioxide and amines with alkanolamine as eco-friendly catalyst under mild conditions

Qin Wen, Xuexin Yuan, Qiqi Zhou, Hai-Jian Yang, Qingqing Jiang, Juncheng Hu and Cun-Yue Guo

Journal of CO2 Utilization, 2023, 69, 102398
DOI: 10.1016/j.jcou.2023.102398

Pivotal Role of the Basic Character of Organic and Salt Catalysts in C−N Bond Forming Reactions of Amines with CO2

Martin Hulla and Paul J. Dyson

Angew Chem Int Ed, 2020, 59, 1002
DOI: 10.1002/anie.201906942

Mechanism of BPh3‐Catalyzed N‐Methylation of Amines with CO2 and Phenylsilane: Cooperative Activation of Hydrosilane

Manussada Ratanasak, Takumi Murata, Taishin Adachi, Jun‐ya Hasegawa and Tadashi Ema

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202202210

Chemoselective Synthesis of Carbamates using CO2 as Carbon Source

Daniel Riemer, Pradipbhai Hirapara and Shoubhik Das

ChemSusChem, 2016, 9, 1916
DOI: 10.1002/cssc.201600521

Mechanistic Study of the N-Formylation of Amines with Carbon Dioxide and Hydrosilanes

Martin Hulla, Gabor Laurenczy and Paul J. Dyson

ACS Catal., 2018, 8, 10619
DOI: 10.1021/acscatal.8b03274

Carbon Dioxide Based N‐Formylation of Amines Catalyzed by Fluoride and Hydroxide Anions

Martin Hulla, Felix D. Bobbink, Shoubhik Das and Paul J. Dyson

ChemCatChem, 2016, 8, 3338
DOI: 10.1002/cctc.201601027

ChemInform Abstract: Solvent‐Promoted Catalyst‐Free N‐Formylation of Amines Using Carbon Dioxide under Ambient Conditions.

Hui Lv, Qi Xing, Chengtao Yue, Ziqiang Lei and Fuwei Li

ChemInform, 2016, 47
DOI: 10.1002/chin.201637039

Catalyst-free hierarchical reduction of CO2 with BH3N(C2H5)3 for selective N-methylation and N-formylation of amines

Qizhuang Zou, Yun Yi, Tianxiang Zhao, Fei Liu, Chao Kang and Xingbang Hu

Journal of CO2 Utilization, 2021, 50, 101590
DOI: 10.1016/j.jcou.2021.101590

Reductive formylation of amines with CO 2 using sodium borohydride: A catalyst-free route

Leiduan Hao, Hongye Zhang, Xiaoying Luo, Cailing Wu, Yanfei Zhao, Xinwei Liu, Xiang Gao, Yu Chen and Zhimin Liu

Journal of CO2 Utilization, 2017, 22, 208
DOI: 10.1016/j.jcou.2017.10.007

Photoinduced Direct Formylation of Anilines: Aerobic Oxidation Using an Odd Alternate Hydrocarbon Phenalenyl-Based Photocatalyst

Vishali Pathania, Gaurav Kumar and Sudipta Raha Roy

J. Org. Chem., 2025, 90, 7476
DOI: 10.1021/acs.joc.5c00932

Mild Access to N‐Formylation of Primary Amines using Ethers as C1 Synthons under Metal‐Free Conditions

Mohana Reddy Mutra, Ganesh Kumar Dhandabani and Jeh‐Jeng Wang

Adv Synth Catal, 2018, 360, 3960
DOI: 10.1002/adsc.201800783

Selective Formylation and Methylation of Amines using Carbon Dioxide and Hydrosilane Catalyzed by Alkali-Metal Carbonates

Chi Fang, Chunlei Lu, Muhua Liu, Yiling Zhu, Yao Fu and Bo-Lin Lin

ACS Catal., 2016, 6, 7876
DOI: 10.1021/acscatal.6b01856

Solvent-Promoted Catalyst-Free Recycling of Waste Polyester and Polycarbonate Materials

Qiao Zhang, Chenyang Hu, Peng-Yuan Li, Fu-Quan Bai, Xuan Pang and Xuesi Chen

ACS Macro Lett., 2024, 151
DOI: 10.1021/acsmacrolett.3c00581

Highly Efficient Binuclear Copper‐catalyzed Oxidation of N,N‐Dimethylanilines with O2

Yuxia Liu, Yonggang Yan, Dong Xue, Zhongfu Wang, Jianliang Xiao and Chao Wang

ChemCatChem, 2020, 12, 2221
DOI: 10.1002/cctc.201901962

Synthesis of benzothiazoles from 2-aminobenzenethiols in the presence of a reusable polythiazolium precatalyst under atmospheric pressure of carbon dioxide

Supill Chun, Sabyuk Yang and Young Keun Chung

Tetrahedron, 2017, 73, 3438
DOI: 10.1016/j.tet.2017.05.003

Supported Palladium Nanoparticles Catalyzed Reductive Carbonylation of Nitroarenes to N‐Arylformamides

Vandna Thakur, Ajay Kumar, Nishtha Sharma, Arun K. Shil and Pralay Das

Adv Synth Catal, 2018, 360, 432
DOI: 10.1002/adsc.201700944

One‐Pot Synthesis of Aldehydes or Alcohols from CO2 via Formamides or Silyl Formates

Fan Yang, Yuta Saiki, Koichi Nakaoka and Tadashi Ema

Adv Synth Catal, 2023, 365, 877
DOI: 10.1002/adsc.202300031

Cationic quaternary ammonium-stabilized Nb oxoclusters catalyze reductive amination of carbon dioxide with hydrosilane

Yuan Ma, Xinjian Wei, Jian Fang, Qingpo Peng, Wen Xu and Zhenshan Hou

Green Chemical Engineering, 2022, 3, 146
DOI: 10.1016/j.gce.2021.11.006

Sustainable Catalyst-free N-formylation using CO2 as a Carbon Source

Zhengyi Li, Song Yang and Hu Li

COS, 2022, 19, 187
DOI: 10.2174/1570179418666211022160149

Direct CO2 Capture and Reduction to High‐End Chemicals with Tetraalkylammonium Borohydrides

Loris Lombardo, Youngdon Ko, Kun Zhao, Heena Yang and Andreas Züttel

Angew Chem Int Ed, 2021, 60, 9580
DOI: 10.1002/anie.202100447

Switchable organocatalysts: Highly efficient reductive functionalization of CO2 to benzimidazoles under mild conditions

Leizhi Zheng, Fei Chen, Jia Liu, Bowen Jiang, Ying Liu, Guangzhi Xu, Xinyao Li and Chengbao Liu

Journal of Environmental Chemical Engineering, 2023, 11, 110709
DOI: 10.1016/j.jece.2023.110709

A Facile Direct Route to N‐(Un)substituted Lactams by Cycloamination of Oxocarboxylic Acids without External Hydrogen

Hu Li, Hongguo Wu, Heng Zhang, Yaqiong Su, Song Yang and Emiel J. M. Hensen

ChemSusChem, 2019, 12, 3778
DOI: 10.1002/cssc.201901780

Can CO2 be a catalyst? Yes, CO2-catalyzed N-formylation of aliphatic amines with DMF

Xiao-Chao Chen, Lin Guo, Guang-Hui Shi, Kai-Chun Zhao, Yong Lu and Ye Liu

Molecular Catalysis, 2022, 528, 112431
DOI: 10.1016/j.mcat.2022.112431

Fe‐catalyzed Selective N‐Formylation Protocol for Amines Using Glycolic Acid as C1 Bio‐Building Block

Tejas A. Gokhale, Prafull A. Jagtap and Bhalchandra M. Bhanage

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301156

Highly Efficient Thiolate‐Based Ionic Liquid Catalysts for Reduction of CO2: Selective N‐Functionalization of Amines to Form N‐Formamides and N‐Methylamines

Jiakai Wu, Junping Niu, Lu Hou, Siliu Cheng, Ruijun Xie and Ning Zhu

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304315

Pivotal Role of the Basic Character of Organic and Salt Catalysts in C−N Bond Forming Reactions of Amines with CO2

Martin Hulla and Paul J. Dyson

Angewandte Chemie, 2020, 132, 1014
DOI: 10.1002/ange.201906942

Design of Lewis base functionalized ionic liquids for the N-formylation of amines with CO2 and hydrosilane: The cation effects

Xiao-Ya Li, Hong-Chen Fu, Xiao-Fang Liu, Shu-Han Yang, Kai-Hong Chen and Liang-Nian He

Catalysis Today, 2020, 356, 563
DOI: 10.1016/j.cattod.2020.01.030

Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions

Federica Bertini, Mathias Glatz, Berthold Stöger, Maurizio Peruzzini, Luis F. Veiros, Karl Kirchner and Luca Gonsalvi

ACS Catal., 2019, 9, 632
DOI: 10.1021/acscatal.8b04106

Metal-Free N-Formylation of Amines with CO2 and Hydrosilane by Nitrogen-Doped Graphene Nanosheets

Qiujuan Shen, Xuehua Chen, Yiyuan Tan, Jinzhu Chen, Limin Chen and Shaozao Tan

ACS Appl. Mater. Interfaces, 2019, 11, 38838
DOI: 10.1021/acsami.9b14509

Heterogeneous Cobalt‐Catalyzed Direct N‐Formylation of Isoquinolines with CO2 and H2

Zhenhong He, Hangyu Liu, Huizhen Liu, Qingli Qian, Qinglei Meng, Qingqing Mei and Buxing Han

ChemCatChem, 2017, 9, 1947
DOI: 10.1002/cctc.201601682

Cobalt(II)‐Catalyzed N‐Acylation of Amines through a Transamidation Reaction

Juan Ma, Feng Zhang, Jingyu Zhang and Hang Gong

Eur J Org Chem, 2018, 2018, 4940
DOI: 10.1002/ejoc.201800253

Lewis Base Promoted Reduction of CO2 with BH3NH3 into Boryl Formates: CO2 as a Carbon Source in Organic Synthesis Under Mild Conditions

Bo Zhang, Gaixia Du, Wei Hang, Sheng Wang and Chanjuan Xi

Eur J Org Chem, 2018, 2018, 1739
DOI: 10.1002/ejoc.201800320

Catalytic CO2 hydrosilylation with [Mn(CO)5Br] under mild reaction conditions

Tania González and Juventino J. García

Polyhedron, 2021, 203, 115242
DOI: 10.1016/j.poly.2021.115242

N,S‐Doped Ordered Mesoporous Carbon: An Effective Catalyst for the Formylation of Anilines and Stabilization of Pd Nanoparticles to Catalyze the Hydrogenation of Nitroarenes

Bagher Eftekhari‐Sis, Maryam Jalalat, Saleh Vahdati‐Khajeh, Maryam Samadi, Maryam Alavinia and Maryam Zirak

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202402858

Transformation of carbon dioxide into valuable chemicals over bifunctional metallosalen catalysts bearing quaternary phosphonium salts

Wuying Zhang, Rongchang Luo, Qihang Xu, Yaju Chen, Xiaowei Lin, Xiantai Zhou and Hongbing Ji

Chinese Journal of Catalysis, 2017, 38, 736
DOI: 10.1016/S1872-2067(17)62802-X

Mild and Selective Carbon Dioxide Hydroboration to Methoxyboranes Catalyzed by Mn(I) PNP Pincer Complexes

Sylwia Kostera, Maurizio Peruzzini, Karl Kirchner and Luca Gonsalvi

ChemCatChem, 2020, 12, 4625
DOI: 10.1002/cctc.202000469

Recent advances in sustainable catalytic production of 5-methyl-2-pyrrolidones from bio-derived levulinate

Yiyuan Jiang, Zao Li, Yuncong Li, Long Chen, Heng Zhang, Hu Li and Song Yang

Fuel, 2023, 334, 126629
DOI: 10.1016/j.fuel.2022.126629

Direct CO2 Capture and Reduction to High‐End Chemicals with Tetraalkylammonium Borohydrides

Loris Lombardo, Youngdon Ko, Kun Zhao, Heena Yang and Andreas Züttel

Angewandte Chemie, 2021, 133, 9666
DOI: 10.1002/ange.202100447

Site‐Selective Decarboxylative Direct Formylation of Nitrogen Heterocycles (Azaindoles, Indoles, Pyrroles) and Anilines Utilizing Glyoxylic Acid

Joydev K. Laha, Mandeep Kaur Hunjan, Tapas Maity and Amitava Hazra

Adv Synth Catal, 2023, 365, 1238
DOI: 10.1002/adsc.202201384

N-Heterocyclic Carbene Moiety in Highly Porous Organic Hollow Nanofibers for Efficient CO2 Conversions: A Comparative Experimental and Theoretical Study

Sudip Bhattacharjee, Anjana Tripathi, Rupak Chatterjee, Ranjit Thapa, Thomas E. Mueller and Asim Bhaumik

ACS Catal., 2024, 14, 718
DOI: 10.1021/acscatal.3c05576

Hydroxyl Group-Regulated Active Nano-Pd/C Catalyst Generation via in Situ Reduction of Pd(NH3)xCly/C for N-Formylation of Amines with CO2/H2

Yujing Zhang, Hongli Wang, Hangkong Yuan and Feng Shi

ACS Sustainable Chem. Eng., 2017, 5, 5758
DOI: 10.1021/acssuschemeng.7b00363

Selective Iron-Catalyzed N-Formylation of Amines using Dihydrogen and Carbon Dioxide

Upul Jayarathne, Nilay Hazari and Wesley H. Bernskoetter

ACS Catal., 2018, 8, 1338
DOI: 10.1021/acscatal.7b03834

Rapid, solvent- and catalyst-free transamidation of aliphatic amines with formamide

Jinting Li, Zihan Zhou, Yinzhe Chen and Qian Zhang

Tetrahedron Letters, 2025, 169, 155754
DOI: 10.1016/j.tetlet.2025.155754

Palladium supported on MRGO@CoAl‐LDH catalyzed reductive carbonylation of nitroarenes and carbonylative Suzuki coupling reactions using formic acid as liquid CO and H2 source

Masoumeh Jadidi Nejad and Akbar Heydari

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6368

Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines

Xiao‐Fang Liu, Xiao‐Ya Li, Chang Qiao, Hong‐Chen Fu and Liang‐Nian He

Angew Chem Int Ed, 2017, 56, 7425
DOI: 10.1002/anie.201702734