Alejandro Julián, Jefferson Guzmán, E. A. Jaseer, Francisco J. Fernández‐Alvarez, Raquel Royo, Víctor Polo, Pilar García‐Orduña, Fernando J. Lahoz and Luis A. Oro

Chemistry A European J, 2017, 23, 11898
DOI: 10.1002/chem.201702246

Novel versatile synthesis method for amides, carbamates and ureas employing a Grignard base, an amine and an ester

Omolola Gbadebo, Karen Fox, Grace Sutton, Paul V. Murphy, Dennis Smith and Patrick O'Leary

Results in Chemistry, 2022, 4, 100253
DOI: 10.1016/j.rechem.2021.100253

Guanidine-Catalyzed Reductive Amination of Carbon Dioxide with Silanes: Switching between Pathways and Suppressing Catalyst Deactivation

Rachel L. Nicholls, James A. McManus, Christopher M. Rayner, José A. Morales-Serna, Andrew J. P. White and Bao N. Nguyen

ACS Catal., 2018, 8, 3678
DOI: 10.1021/acscatal.7b04108

CuH-Catalyzed Selective N-Methylation of Amines Using Paraformaldehyde as a C1 Source

Diedie Wang, Wanglv Lang, Wan Wang, Qizhuang Zou, Chunliang Yang, Fei Liu and Tianxiang Zhao

ACS Omega, 2023, 8, 30640
DOI: 10.1021/acsomega.3c04332

Achieving Diverse CO2 Conversions through On-Demand Installation of Multivariate Catalytic Sites into One Prototypical Metal–Organic Framework

Songlin Deng, Yang-Yang Xiong, Cheng-Xia Chen, Qing-Hua Dai, Yin-Xian Chen, Wei Geng, Zi-Ying Liang, Wei-Lun Ruan, Zhang-Wen Wei, Mihail Barboiu and Cheng-Yong Su

J. Am. Chem. Soc., 2025, 147, 19996
DOI: 10.1021/jacs.5c05028

Metal-Free N-Formylation of Amines with CO2 and Hydrosilane by Nitrogen-Doped Graphene Nanosheets

Qiujuan Shen, Xuehua Chen, Yiyuan Tan, Jinzhu Chen, Limin Chen and Shaozao Tan

ACS Appl. Mater. Interfaces, 2019, 11, 38838
DOI: 10.1021/acsami.9b14509

Reduction of CO2 by Hydrosilanes in the Presence of Formamidinates of Group 13 and 12 Elements

Weiheng Huang, Thierry Roisnel, Vincent Dorcet, Clement Orione and Evgueni Kirillov

Organometallics, 2020, 39, 698
DOI: 10.1021/acs.organomet.9b00853

Imidazolium hydrogen carbonate ionic liquids: Versatile organocatalysts for chemical conversion of CO2 into valuable chemicals

Guangcai Long, Dongsheng Wu, Hongyan Pan, Tianxiang Zhao and Xingbang Hu

Journal of CO2 Utilization, 2020, 39, 101155
DOI: 10.1016/j.jcou.2020.101155

1,4‐Dioxane‐Tuned Catalyst‐Free Methylation of Amines by CO2 and NaBH4

Zhiqiang Guo, Bo Zhang, Xuehong Wei and Chanjuan Xi

ChemSusChem, 2018, 11, 2296
DOI: 10.1002/cssc.201801037

Selective N-Methylation of Aniline to N-Methylaniline with CO2 and H2 by CeO2-supported Cu Sub-nanoparticle Catalyst

Masazumi Tamura, Ayaka Miura, Yu Gu, Yoshinao Nakagawa and Keiichi Tomishige

Chem. Lett., 2017, 46, 1243
DOI: 10.1246/cl.170419

Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines

Xiao‐Fang Liu, Xiao‐Ya Li, Chang Qiao, Hong‐Chen Fu and Liang‐Nian He

Angewandte Chemie, 2017, 129, 7533
DOI: 10.1002/ange.201702734

Waste Recycling: Ionic Liquid-Catalyzed 4-Electron Reduction of CO2 with Amines and Polymethylhydrosiloxane Combining Experimental and Theoretical Study

Xiao-Ya Li, Su-Su Zheng, Xiao-Fang Liu, Zhi-Wen Yang, Tian-You Tan, Ao Yu and Liang-Nian He

ACS Sustainable Chem. Eng., 2018, 6, 8130
DOI: 10.1021/acssuschemeng.8b02352

Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines

Yue Hu, Jinliang Song, Chao Xie, Haoran Wu, Zhenpeng Wang, Tao Jiang, Lei Wu, Yu Wang and Buxing Han

ACS Sustainable Chem. Eng., 2018, 6, 11228
DOI: 10.1021/acssuschemeng.8b03245

Highly Efficient Thiolate‐Based Ionic Liquid Catalysts for Reduction of CO2: Selective N‐Functionalization of Amines to Form N‐Formamides and N‐Methylamines

Jiakai Wu, Junping Niu, Lu Hou, Siliu Cheng, Ruijun Xie and Ning Zhu

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304315

Selective Metal‐Free Hydrosilylation of CO2 Catalyzed by Triphenylborane in Highly Polar, Aprotic Solvents

Debabrata Mukherjee, Daniel F. Sauer, Alessandro Zanardi and Jun Okuda

Chemistry A European J, 2016, 22, 7730
DOI: 10.1002/chem.201601006

Organoboron‐Functionalized Metal‐Organic Nanosheets for Highly Efficient CO2 Fixation Mediated by Frustrated Lewis Pairs

Cheng‐Xia Chen, Haiping Wang, Hassan Rabaâ, Yang‐Yang Xiong, Peter VanNatta, Zhang‐Wen Wei, Abdullah M. Al‐Enizi, Ayman Nafady and Shengqian Ma

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202416497

Boron-Catalyzed O–H Bond Insertion of α-Aryl α-Diazoesters in Water

Htet Htet San, Shi-Jun Wang, Min Jiang and Xiang-Ying Tang

Org. Lett., 2018, 20, 4672
DOI: 10.1021/acs.orglett.8b01988

Synthesis of chemicals using CO2 as a building block under mild conditions

Zhenzhen Yang, Xiang Gao and Zhimin Liu

Current Opinion in Green and Sustainable Chemistry, 2016, 1, 13
DOI: 10.1016/j.cogsc.2016.06.001

Recyclable polymerized Lewis acid poly-BPh(C6F5)2 catalyzed selective N-formylation and N-methylation of amines with carbon dioxide and phenylsilanes

Gaowen Zhai, Qiang Liu, Jialan Ji, Youting Wu, Jiao Geng and Xingbang Hu

Journal of CO2 Utilization, 2022, 61, 102052
DOI: 10.1016/j.jcou.2022.102052

Construction of a triaminoguanidine- and imidazolium-bifunctionalized ionic porous organic polymer gel as a metal-free heterogeneous catalyst for N-formylation of amines and amides with CO2 under ambient conditions

Jie Xu, Di Chen, Zhaobin Ye, Shasha Ma, Yuanlong Wang and Jianyong Zhang

Journal of Catalysis, 2026, 453, 116512
DOI: 10.1016/j.jcat.2025.116512

Directly Bridging Indoles to 3,3′‐Bisindolylmethanes by Using Carboxylic Acids and Hydrosilanes under Mild Conditions

Chang Qiao, Xiao‐Fang Liu, Hong‐Chen Fu, Hao‐Peng Yang, Zhi‐Bo Zhang and Liang‐Nian He

Chemistry An Asian Journal, 2018, 13, 2664
DOI: 10.1002/asia.201800766

Katalytische reduktive N‐Alkylierungen unter Verwendung von CO2 und Carbonsäurederivaten: Aktuelle Entwicklungen

Jose R. Cabrero‐Antonino, Rosa Adam and Matthias Beller

Angewandte Chemie, 2019, 131, 12950
DOI: 10.1002/ange.201810121

Pivotal Role of the Basic Character of Organic and Salt Catalysts in C−N Bond Forming Reactions of Amines with CO2

Martin Hulla and Paul J. Dyson

Angewandte Chemie, 2020, 132, 1014
DOI: 10.1002/ange.201906942

Platinum nanoparticles as recyclable heterogeneous catalyst for selective methylation of amines and imines with formic acid: Indirect utilization of CO2

Weishuang Li, Feng Yan, Shuang Cai, Liang Ding, Bojie Li, Bingqing Zhang, Yaoyao Zhang and Lei Zhu

Journal of Saudi Chemical Society, 2022, 26, 101421
DOI: 10.1016/j.jscs.2022.101421

Efficient Conversion of Greenhouse Gas of CO2into Carbon Products with Desirable Structures via Molten Carbonates Electrolysis

Mengpei Jiang, Zhida Li, Yanyan Yu, Hongjun Wu, Wei Li, Deqiang Ji, Yue Liu, Zhouwen He and Zhonghai Zhang

J. Electrochem. Soc., 2017, 164, D1022
DOI: 10.1149/2.1561714jes

Theoretical investigations on the methylation of N H bond using CO 2 and hydrosilane catalyzed by Zinc II complexes: Mechanism and ligand effect

Weiyi Li and Chan Kyung Kim

Journal of CO2 Utilization, 2017, 20, 178
DOI: 10.1016/j.jcou.2017.05.016

Advancements and Challenges in Reductive Methylation of Carbon Dioxide

Yubo Long, Meilin Tang, Yixin Liao, Shiqi Xu, Haobing Deng, Jinyao Liu, Peiru Chen, Jinwu Zhao and Wenfang Xiong

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.70054

Sustainable Catalyst-free N-formylation using CO2 as a Carbon Source

Zhengyi Li, Song Yang and Hu Li

COS, 2022, 19, 187
DOI: 10.2174/1570179418666211022160149

What Fluorine Can Do in CO2 Chemistry: Applications from Homogeneous to Heterogeneous Systems

Hao Chen, Zhenzhen Yang, Chi‐Linh Do‐Thanh and Sheng Dai

ChemSusChem, 2020, 13, 6182
DOI: 10.1002/cssc.202001638

N-Methylation of Aniline Derivatives with CO2 and Phenylsilane Catalyzed by Lanthanum Hydridotriarylborate Complexes bearing a Nitrogen Tridentate Ligand

Koichi Shinohara, Hayato Tsurugi and Kazushi Mashima

ACS Catal., 2022, 12, 8220
DOI: 10.1021/acscatal.2c01658

A versatile way for the synthesis of monomethylamines by reduction of N-substituted carbonylimidazoles with the NaBH4/I2 system

Lin Chen, Xuan Zhou, Zhiyong Chen, Changxu Wang, Shunjie Wang and Hanbing Teng

Beilstein J. Org. Chem., 2022, 18, 1032
DOI: 10.3762/bjoc.18.104

Sodium Hypochlorite Pentahydrate as a Chlorinating Reagent: Application to the Tandem Conversion of β,γ-Unsaturated Carboxylic Acids to α,β-Unsaturated Lactones

Michio Iwaoka, Reo Shimada, Masaki Kuroda, Takehito Ikeda and Eduardo E. Alberto

Processes, 2024, 12, 1102
DOI: 10.3390/pr12061102

Synthesis of Ureas from CO2

Hua Wang, Zhuo Xin and Yuehui Li

Top Curr Chem (Z), 2017, 375
DOI: 10.1007/s41061-017-0137-4

Hydroxyl Group-Regulated Active Nano-Pd/C Catalyst Generation via in Situ Reduction of Pd(NH3)xCly/C for N-Formylation of Amines with CO2/H2

Yujing Zhang, Hongli Wang, Hangkong Yuan and Feng Shi

ACS Sustainable Chem. Eng., 2017, 5, 5758
DOI: 10.1021/acssuschemeng.7b00363

Organoboron‐Functionalized Metal‐Organic Nanosheets for Highly Efficient CO2 Fixation Mediated by Frustrated Lewis Pairs

Cheng‐Xia Chen, Haiping Wang, Hassan Rabaâ, Yang‐Yang Xiong, Peter VanNatta, Zhang‐Wen Wei, Abdullah M. Al‐Enizi, Ayman Nafady and Shengqian Ma

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202416497

N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes

Pengpeng Ju, Jinzhu Chen, Aibing Chen, Limin Chen and Yifeng Yu

ACS Sustainable Chem. Eng., 2017, 5, 2516
DOI: 10.1021/acssuschemeng.6b02865

Reductive CO2 Fixation via Tandem C–C and C–N Bond Formation: Synthesis of Spiro-indolepyrrolidines

Dao-Yong Zhu, Lei Fang, Hui Han, Yazhou Wang and Ji-Bao Xia

Org. Lett., 2017, 19, 4259
DOI: 10.1021/acs.orglett.7b01906

CO2-Driven N-Formylation/N-Methylation of Amines Using C-Scorpionate Metal Complexes

Inês A. S. Matias, Anna M. Trzeciak, Paulina Pąchalska, Ana P. C. Ribeiro and Luísa M. D. R. S. Martins

Molecules, 2024, 29, 870
DOI: 10.3390/molecules29040870

Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines

Xiao‐Fang Liu, Xiao‐Ya Li, Chang Qiao, Hong‐Chen Fu and Liang‐Nian He

Angew Chem Int Ed, 2017, 56, 7425
DOI: 10.1002/anie.201702734

The Catalytic Reduction of Carboxylic Acid Derivatives and CO2 by Metal Nanoparticles on Lewis‐Acidic Supports

Takashi Toyao, S. M. A. Hakim Siddiki, Kenichi Kon and Ken‐ichi Shimizu

The Chemical Record, 2018, 18, 1374
DOI: 10.1002/tcr.201800061

Selektive katalytische Synthesen mit Kohlendioxid und Wasserstoff: Katalyse‐Schach an der Nahtstelle zwischen Energie und Chemie

Jürgen Klankermayer, Sebastian Wesselbaum, Kassem Beydoun and Walter Leitner

Angewandte Chemie, 2016, 128, 7416
DOI: 10.1002/ange.201507458

Chemoselective Synthesis of Carbamates using CO2 as Carbon Source

Daniel Riemer, Pradipbhai Hirapara and Shoubhik Das

ChemSusChem, 2016, 9, 1916
DOI: 10.1002/cssc.201600521

Organosilicon compounds in supercritical carbon dioxide: Synthesis, polymerization, modification, and production of new materials

M. A. Pigaleva, I. V. Elmanovich, M. N. Temnikov, M. O. Gallyamov and A. M. Muzafarov

Polym. Sci. Ser. B, 2016, 58, 235
DOI: 10.1134/S1560090416030118

Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment

Jens Artz, Thomas E. Müller, Katharina Thenert, Johanna Kleinekorte, Raoul Meys, André Sternberg, André Bardow and Walter Leitner

Chem. Rev., 2018, 118, 434
DOI: 10.1021/acs.chemrev.7b00435

Insights into Naturally Occurring Compound Catalyzed Formylation and Methylation Reactions of Amines with CO2: The Origins of Chemoselectivity

Zhen Yue, Jiyang Zhao, Pan Du and Guang-Xiang Liu

ACS Sustainable Chem. Eng., 2020, 8, 11967
DOI: 10.1021/acssuschemeng.0c02325

Homogeneous Catalytic Reduction of CO2 with Silicon‐Hydrides, State of the Art

Francisco J. Fernández‐Alvarez and Luis A. Oro

ChemCatChem, 2018, 10, 4783
DOI: 10.1002/cctc.201800699

Ruthenium-promoted reductive transformation of CO2

Xuedong Li, Xing He, Xiaofang Liu and Liang-Nian He

Sci. China Chem., 2017, 60, 841
DOI: 10.1007/s11426-016-0473-5

Combining Isocyanides with Carbon Dioxide in Palladium-Catalyzed Heterocycle Synthesis: N3-Substituted Quinazoline-2,4(1H,3H)-diones via a Three-Component Reaction

Pieter Mampuys, Helfried Neumann, Sergey Sergeyev, Romano V. A. Orru, Haijun Jiao, Anke Spannenberg, Bert U. W. Maes and Matthias Beller

ACS Catal., 2017, 7, 5549
DOI: 10.1021/acscatal.7b01503

Zwitterionic Covalent Organic Frameworks as Catalysts for Hierarchical Reduction of CO2 with Amine and Hydrosilane

Zhen-Jie Mu, Xuesong Ding, Zhi-Yan Chen and Bao-Hang Han

ACS Appl. Mater. Interfaces, 2018, 10, 41350
DOI: 10.1021/acsami.8b14671

Progress in Catalysis Transformation of Carbon Dioxide through Hydrosilylation

Zijie Song, Jun Liu, Ying Bai, Jiayun Li and Jiajian Peng

Chinese Journal of Organic Chemistry, 2023, 43, 2068
DOI: 10.6023/cjoc202210024

Pivotal Role of the Basic Character of Organic and Salt Catalysts in C−N Bond Forming Reactions of Amines with CO2

Martin Hulla and Paul J. Dyson

Angew Chem Int Ed, 2020, 59, 1002
DOI: 10.1002/anie.201906942

Iron‐Catalyzed Selective N‐Methylation and N‐Formylation of Amines with CO2

Wen‐Duo Li, Dao‐Yong Zhu, Gang Li, Jie Chen and Ji‐Bao Xia

Adv Synth Catal, 2019, 361, 5098
DOI: 10.1002/adsc.201900906

Homogeneous and Heterogeneous Frustrated Lewis Pairs for the Activation and Transformation of CO2

Tao Du, Peng Zhang, Zhen Jiao, Jiancheng Zhou and Yuxiao Ding

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400208

Selective Formylation and Methylation of Amines using Carbon Dioxide and Hydrosilane Catalyzed by Alkali-Metal Carbonates

Chi Fang, Chunlei Lu, Muhua Liu, Yiling Zhu, Yao Fu and Bo-Lin Lin

ACS Catal., 2016, 6, 7876
DOI: 10.1021/acscatal.6b01856

DFT Study of Functional Reduction of CO2 with BH3NMe3: The Real Role of Organic Catalyst TBD

Zhaowei Li, Jianing Zhao, Yongjian Wang and Ao Yu

J. Org. Chem., 2024, 89, 6149
DOI: 10.1021/acs.joc.4c00130

C−N Bond Formation Using Paraformaldehyde as C1 Source – Recent Advances

Zhiqiang Guo, Jinglong Wu and Xuehong Wei

Asian J Org Chem, 2024, 13
DOI: 10.1002/ajoc.202300553

Bimolecular reduction of carbon dioxide: double synthons for alkynes trifunctionalization

Wenfang Xiong, Xiaobin Tan, Hongjian Liu, Baiyao Zhu, Jinwu Zhao, Jianxiao Li, Chaorong Qi and Huanfeng Jiang

Sci. China Chem., 2024, 67, 841
DOI: 10.1007/s11426-023-1804-4

The DMSO-Catalyzed CO2 Reduction with 9-BBN as a Source for the Selective N-Formylation, Room Temperature N-Methylation of Amines, N-Hydroxymethylation of Heterocycles, and C–N Couplings

Ashok Kumar, Rohit Gupta and Ganesan Mani

J. Org. Chem., 2025, 90, 10316
DOI: 10.1021/acs.joc.5c00965

DBU‐Catalyzed Selective N‐Methylation and N‐Formylation of Amines with CO2 and Polymethylhydrosiloxane

Gang Li, Jie Chen, Dao‐Yong Zhu, Ye Chen and Ji‐Bao Xia

Adv Synth Catal, 2018, 360, 2364
DOI: 10.1002/adsc.201800140

Efficient and Selective N‐Methylation of Nitroarenes under Mild Reaction Conditions

Elena Pedrajas, Iván Sorribes, Eva Guillamón, Kathrin Junge, Matthias Beller and Rosa Llusar

Chemistry A European J, 2017, 23, 13205
DOI: 10.1002/chem.201702783

Catalytic Reductive N‐Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments

Jose R. Cabrero‐Antonino, Rosa Adam and Matthias Beller

Angew Chem Int Ed, 2019, 58, 12820
DOI: 10.1002/anie.201810121

Zinc Powder Catalysed Formylation and Urealation of Amines Using CO2 as a C1 Building Block†

Chongyang Du and Yaofeng Chen

Chin. J. Chem., 2020, 38, 1057
DOI: 10.1002/cjoc.202000072

Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry

Jürgen Klankermayer, Sebastian Wesselbaum, Kassem Beydoun and Walter Leitner

Angew Chem Int Ed, 2016, 55, 7296
DOI: 10.1002/anie.201507458

Homogeneous Catalysis in N‐Formylation/N‐Methylation Utilizing Carbon Dioxide as the C1 Source

Indranil Dutta, Sandeep Suryabhan Gholap, Mohammad Misbahur Rahman, Davin Tan, Lili Zhang, Shashikant U. Dighe and Kuo‐Wei Huang

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400497

Unsupported Nanoporous Palladium Catalyst for N‐Formylation of Amines Using CO2 as a Sustainable C1 Source

Jixiao Wang, Shihong Li, Yunpeng Wang, Xiujuan Feng, Yoshinori Yamamoto and Ming Bao

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200064

ChemInform Abstract: B(C6F5)3‐Catalyzed Methylation of Amines Using CO2 as a C1 Building Block.

Zhenzhen Yang, Bo Yu, Hongye Zhang, Yanfei Zhao, Guipeng Ji, Zhishuang Ma, Xiang Gao and Zhimin Liu

ChemInform, 2015, 46
DOI: 10.1002/chin.201550068

Fluoride‐Catalyzed Methylation of Amines by Reductive Functionalization of CO2 with Hydrosilanes

Xiao‐Fang Liu, Ran Ma, Chang Qiao, Han Cao and Liang‐Nian He

Chemistry A European J, 2016, 22, 16489
DOI: 10.1002/chem.201603688

A review on recent developments in N-methylation using CO2

Shanshan Lin, Jianguo Liu and Longlong Ma

Journal of CO2 Utilization, 2021, 54, 101759
DOI: 10.1016/j.jcou.2021.101759

A Theoretical Study on the Mechanism of Methylation of N‐methylaniline with CO2 and Silyl Hydrides

Weiyi Li and Chan Kyung Kim

Bulletin Korean Chem Soc, 2017, 38, 12
DOI: 10.1002/bkcs.11011

DMF-promoted reductive functionalization of CO2 with secondary amines and phenylsilane to methylamines

Xiao-Fang Liu, Chang Qiao, Xiao-Ya Li and Liang-Nian He

Pure and Applied Chemistry, 2018, 90, 1099
DOI: 10.1515/pac-2017-0304