High activity and stability in the cross-coupling of aryl halides with disulfides over Cu-doped hierarchically porous zeolite ZSM-5

Wenqian Fu, Taotao Liu, Zhongxue Fang, Yuli Ma, Xiang Zheng, Wenchang Wang, Xiaojun Ni, Maolin Hu and Tiandi Tang

Chem. Commun., 2015, 51, 5890
DOI: 10.1039/C4CC10417J

Open-air oxidative Mizoroki–Heck reaction of arylsulfonyl hydrazides with alkenes

On Ying Yuen, Chau Ming So and Fuk Yee Kwong

RSC Adv., 2016, 6, 27584
DOI: 10.1039/C6RA03188A

Recent developments in palladium-catalyzed C–S bond formation

Jianxiao Li, Shaorong Yang, Wanqing Wu and Huanfeng Jiang

Org. Chem. Front., 2020, 7, 1395
DOI: 10.1039/D0QO00377H

Copper-catalyzed oxidative alkenylation of C(sp3)–H bonds via benzyl or alkyl radical addition to β-nitrostyrenes

Shengrong Guo, Yanqin Yuan and Jiannan Xiang

New J. Chem., 2015, 39, 3093
DOI: 10.1039/C4NJ02416H

CuI anchored onto mesoporous SBA-16 functionalized by aminated 3-glycidyloxypropyltrimethoxysilane with thiosemicarbazide (SBA-16/GPTMS-TSC-CuI): a heterogeneous mesostructured catalyst for S-arylation reaction under solvent-free conditions

Sara S. E. Ghodsinia and Batool Akhlaghinia

Green Chem., 2019, 21, 3029
DOI: 10.1039/C8GC03931C

Synthesis of thiophosphates through a three-component reaction by using sulfur dioxide as the sulfur source

Xinxing Gong, Jiahao Chen, Jianhe Liu and Jie Wu

Org. Chem. Front., 2017, 4, 2221
DOI: 10.1039/C7QO00634A

Direct thiolation of aza-heteroaromatic N-oxides with disulfides via copper-catalyzed regioselective C–H bond activation

Miao Lai, Ke Zhai, Chuance Cheng, Zhiyong Wu and Mingqin Zhao

Org. Chem. Front., 2018, 5, 2986
DOI: 10.1039/C8QO00840J

Solvent-free and room temperature visible light-induced C–H activation: CdS as a highly efficient photo-induced reusable nano-catalyst for the C–H functionalization cyclization of t-amines and C–C double and triple bonds

Somayeh Firoozi, Mona Hosseini-Sarvari and Mehdi Koohgard

Green Chem., 2018, 20, 5540
DOI: 10.1039/C8GC03297A

Visible-light-promoted C(sp3)–H thiolation of aliphatic ethers with thiosulfonates

Wen-Zhu Bi, Qing-Pu Liu, Chen-Yu Li, Wen-Jie Zhang, Su-Xiang Feng, Yang Geng, Xiao-Lan Chen and Ling-Bo Qu

New J. Chem., 2023, 47, 9035
DOI: 10.1039/D3NJ01029E

Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen

Hui Miao, Fenhua Wang, Shuangliu Zhou, Guangchao Zhang and Yang Li

Org. Biomol. Chem., 2015, 13, 4647
DOI: 10.1039/C5OB00139K

An iodine-mediated new avenue to sulfonylation employing N-hydroxy aryl sulfonamide as a sulfonylating agent

Dushyant Singh Raghuvanshi and Narsingh Verma

Org. Biomol. Chem., 2021, 19, 4760
DOI: 10.1039/D1OB00036E

Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3C–H functionalisation

Arghya Banerjee, Sourav Kumar Santra, Aniket Mishra, Nilufa Khatun and Bhisma K. Patel

Org. Biomol. Chem., 2015, 13, 1307
DOI: 10.1039/C4OB01962H

Recyclable imidazolium ion-tagged nickel catalyst for microwave-assisted C–S cross-coupling in water using sulfonyl hydrazide as the sulfur source

Vaishali Saini and Bharti Khungar

New J. Chem., 2018, 42, 12796
DOI: 10.1039/C8NJ00904J

Oxidant controlled regioselective mono- and di-functionalization reactions of coumarins

Arghya Banerjee, Sourav Kumar Santra, Nilufa Khatun, Wajid Ali and Bhisma K. Patel

Chem. Commun., 2015, 51, 15422
DOI: 10.1039/C5CC06200D

Transition metal catalysed direct sulfanylation of unreactive C–H bonds: an overview of the last two decades

Daniel S. Rampon, Diego Seckler, Eduardo Q. Luz, Douglas B. Paixão, Allya Larroza, Paulo H. Schneider and Diego Alves

Org. Biomol. Chem., 2022, 20, 6072
DOI: 10.1039/D2OB00986B

Autoinductive thiolation/oxygenation of alkenes at room temperature

Qingquan Lu, Huamin Wang, Pan Peng, Chao Liu, Zhiyuan Huang, Yi Luo and Aiwen Lei

Org. Chem. Front., 2015, 2, 908
DOI: 10.1039/C5QO00102A

Metal-free NaI/TBHP-mediated sulfonylation of thiols with sulfonyl hydrazides

Qian Chen, Yulin Huang, Xiaofeng Wang, Jiawei Wu and Guodian Yu

Org. Biomol. Chem., 2018, 16, 1713
DOI: 10.1039/C8OB00244D

Pd-catalyzed desulfitative and denitrogenative Suzuki-type reaction of arylsulfonyl hydrazides

Shuangling Zhong, Chenggang Sun, Sen Dou and Wencong Liu

RSC Adv., 2015, 5, 27029
DOI: 10.1039/C5RA01363A

N-Hydroxy sulfonamides as new sulfenylating agents for the functionalization of aromatic compounds

Fu-Xiang Wang, Shao-Da Zhou, Chengming Wang and Shi-Kai Tian

Org. Biomol. Chem., 2017, 15, 5284
DOI: 10.1039/C7OB01390F

Palladium-catalyzed C-3 desulfitative arylation of indolizines with sodium arylsulfinates and arylsulfonyl hydrazides

Chunjie Wang, Huali Jia, Zhiwei Li, Hui Zhang and Baoli Zhao

RSC Adv., 2016, 6, 21814
DOI: 10.1039/C5RA25504J

Copper-mediated direct thiolation of aryl C–H bonds with disulfides

Ke-Zuan Deng, Li-Li Zhang, Ye-Feng Chen, He-Xin Xie, Xiao-Bo Xu, Cheng-Cai Xia and Ya-Fei Ji

Org. Biomol. Chem., 2019, 17, 7055
DOI: 10.1039/C9OB01255A

Synthesis of N-alkyl-3-sulfonylindoles and N-alkyl-3-sulfanylindoles by cascade annulation of 2-alkynyl-N,N-dialkylanilines

Jatuporn Meesin, Manat Pohmakotr, Vichai Reutrakul, Darunee Soorukram, Pawaret Leowanawat and Chutima Kuhakarn

Org. Biomol. Chem., 2017, 15, 3662
DOI: 10.1039/C7OB00366H

A method for accessing sulfanylfurans from homopropargylic alcohols and sulfonyl hydrazides

Xiaodong Yang and Rulong Yan

Org. Biomol. Chem., 2017, 15, 3571
DOI: 10.1039/C7OB00566K

Manganese catalysed sulfenylation of N-methyl amides with arenesulfonyl hydrazides

Jinwei Sun, Yi Wang and Yi Pan

Org. Biomol. Chem., 2015, 13, 3878
DOI: 10.1039/C5OB00133A

Synthesis and nano-Pd catalyzed chemoselective oxidation of symmetrical and unsymmetrical sulfides

Xing Li, Jia Du, Yongli Zhang, Honghong Chang, Wenchao Gao and Wenlong Wei

Org. Biomol. Chem., 2019, 17, 3048
DOI: 10.1039/C8OB03209B

Copper-catalyzed direct trifluoromethylthiolation of indoles by tert-butyl 2-((trifluoromethyl)sulfonyl)hydrazine-1-carboxylate

Kui Lu, Quan Li, Xiaolan Xi, Yuna Huang, Zhi Gong, Peng Yu and Xia Zhao

Org. Chem. Front., 2018, 5, 3088
DOI: 10.1039/C8QO00779A

Synthesis of α-sulfenylated carbonyl compounds under metal-free conditions

Dan Mou, Yuanyuan Wu, Linda Wang, Ying Fu and Zhengyin Du

Org. Biomol. Chem., 2024, 22, 274
DOI: 10.1039/D3OB01796F

(2-Chlorobenzoyloxy)copper(i) catalyzed C–S cross-coupling of di(hetero)aryl disulfides with aryl boronic acids under base-free conditions

Yan Guo, Zheng-Jun Quan, Yu-Xia Da, Zhang Zhang and Xi-Cun Wang

RSC Adv., 2015, 5, 45479
DOI: 10.1039/C5RA05594F

Copper-catalyzed radical 1,2-cyclization of indoles with arylsulfonyl hydrazides: access to 2-thiolated 3H-pyrrolo[1,2-a]indoles

Jiawei Zhu, Song Sun, Minfang Xia, Ning Gu and Jiang Cheng

Org. Chem. Front., 2017, 4, 2153
DOI: 10.1039/C7QO00478H

Iodine-catalysed regioselective thiolation of flavonoids using sulfonyl hydrazides as sulfenylation reagents

Xia Zhao, Zhijie Deng, Aoqi Wei, Boyang Li and Kui Lu

Org. Biomol. Chem., 2016, 14, 7304
DOI: 10.1039/C6OB01006G

TfNHNHBoc as a SCF3 source for the sulfenylation of indoles

Jing-Yu Guo, Rui-Han Dai, Wen-Cong Xu, Ruo-Xin Wu and Shi-Kai Tian

Chem. Commun., 2018, 54, 8980
DOI: 10.1039/C8CC04600J

Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Sheng-Ping Liu, Lan Yang, Yan-Hong He and Zhi Guan

Org. Chem. Front., 2024, 11, 7001
DOI: 10.1039/D4QO01488J

Metal- and solvent-free direct C–H thiolation of aromatic compounds with sulfonyl chlorides

Feng Zhao, Qi Tan, Dahan Wang and Guo-Jun Deng

Green Chem., 2020, 22, 427
DOI: 10.1039/C9GC03384J

Direct construction of 2-alkylbenzo-1,3-azoles via C–H activation of alkanes for C–C and C–X (X = O, S) bond formation

Arvind K. Yadav and Lal Dhar S. Yadav

Org. Biomol. Chem., 2015, 13, 2606
DOI: 10.1039/C4OB02488E

Regioselective thiolation of electron rich arenes and heterocycles in recyclable catalytic media

Dushyant Singh Raghuvanshi and Narsingh Verma

RSC Adv., 2017, 7, 22860
DOI: 10.1039/C7RA02350B

Iodine-catalyzed thiolation of electron-rich aromatics using sulfonyl hydrazides as sulfenylation reagents

Xia Zhao, Tianjiao Li, Lipeng Zhang and Kui Lu

Org. Biomol. Chem., 2016, 14, 1131
DOI: 10.1039/C5OB02193F

Double C–S bond formation via C–H bond functionalization: synthesis of benzothiazoles and naphtho[2,1-d]thiazoles from N-substituted arylamines and elemental sulfur

Xiaoming Zhu, Yuzhong Yang, Genhua Xiao, Jianxin Song, Yun Liang and Guobo Deng

Chem. Commun., 2017, 53, 11917
DOI: 10.1039/C7CC07366F

The fast and efficient KI/H2O2 mediated 2-sulfonylation of indoles and N-methylpyrrole in water

Jun Zhang, Zhong Wang, Lingjuan Chen, Yan Liu, Ping Liu and Bin Dai

RSC Adv., 2018, 8, 41651
DOI: 10.1039/C8RA09367A

Chemoselective cross-coupling reaction of sodium sulfinates with phenols under aqueous conditions

Fuhong Xiao, Shuqing Chen, Jinxin Tian, Huawen Huang, Yuejin Liu and Guo-Jun Deng

Green Chem., 2016, 18, 1538
DOI: 10.1039/C5GC02292D

Iodine-catalyzed expeditious synthesis of sulfonamides from sulfonyl hydrazides and amines

Sirilata Yotphan, Ladawan Sumunnee, Danupat Beukeaw, Chonchanok Buathongjan and Vichai Reutrakul

Org. Biomol. Chem., 2016, 14, 590
DOI: 10.1039/C5OB02075A

I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles

Jiwen Yuan, Xu Ma, Hong Yi, Chao Liu and Aiwen Lei

Chem. Commun., 2014, 50, 14386
DOI: 10.1039/C4CC05661B

Metal free sulfenylation of active methylene compounds and indole: TBATB mediated synthesis

Rajjakfur Rahaman, Namita Devi and Pranjit Barman

Tetrahedron Letters, 2015, 56, 4224
DOI: 10.1016/j.tetlet.2015.05.062

CuCl2-promoted decomposition of sulfonyl hydrazides for the synthesis of thiosulfonates

Junsu Kim, Sanggil Park, Hyungjun Kim and Jinho Kim

Tetrahedron Letters, 2020, 61, 152112
DOI: 10.1016/j.tetlet.2020.152112

Metal‐Free Thiolation of Imidazopyridines with Functionalized Haloalkanes Using Elemental Sulfur

Jun‐Rong Zhang, Ling‐Zhi Zhan, Liang Wei, Yun‐Yun Ning, Xiao‐Lin Zhong, Jing‐Xiong Lai, Li Xu and Ri‐Yuan Tang

Adv Synth Catal, 2018, 360, 533
DOI: 10.1002/adsc.201701190

By‐Product‐Catalyzed Redox‐Neutral Sulfenylation/Deiodination/Aromatization of Cyclic Alkenyl Iodides with Sulfonyl Hydrazides

Fu‐Lai Yang, Yang Gui, Bang‐Kui Yu, You‐Xiang Jin and Shi‐Kai Tian

Adv Synth Catal, 2016, 358, 3368
DOI: 10.1002/adsc.201600795

Iodine-Mediated Thiolation of Substituted Naphthols/Naphthylamines and Arylsulfonyl Hydrazides via C(sp2)–H Bond Functionalization

Xing Kang, Rulong Yan, Guiqin Yu, Xiaobo Pang, Xingxing Liu, Xiaoni Li, Likui Xiang and Guosheng Huang

J. Org. Chem., 2014, 79, 10605
DOI: 10.1021/jo501778h

Cu-catalyzed direct C-H thiolation of electron-rich arenes with arylsulfonyl hydrazides

Lingjuan Chen, Ping Liu, Jianglong Wu and Bin Dai

Tetrahedron, 2018, 74, 1513
DOI: 10.1016/j.tet.2018.02.014

FeBr3-catalyzed regioselective intramolecular sulfenoamination of unactivated terminal olefins

Lin-Chuang Zheng, Lin Li, Lili Duan and Yue-Ming Li

Tetrahedron, 2019, 75, 130619
DOI: 10.1016/j.tet.2019.130619

I2‐Promoted Direct C−H Sulfenylation of Isoquinolin‐1(2H)‐ones with Sulfonyl Chlorides

Cai‐Yun Yang, Xia Li, Bo Liu and Guo‐Li Huang

Eur J Org Chem, 2021, 2021, 117
DOI: 10.1002/ejoc.202001371

Intermolecular cyclization of N-methylanilines and maleimides to tetrahydroquinolines via K2S2O8 promoted C(sp3)–H activation

Arvind K. Yadav and Lal Dhar S. Yadav

Tetrahedron Letters, 2016, 57, 1489
DOI: 10.1016/j.tetlet.2016.02.078

A Direct Metal-Free Decarboxylative Sulfono Functionalization (DSF) of Cinnamic Acids to α,β-Unsaturated Phenyl Sulfones

Rahul Singh, Bharat Kumar Allam, Neetu Singh, Kumkum Kumari, Satish Kumar Singh and Krishna Nand Singh

Org. Lett., 2015, 17, 2656
DOI: 10.1021/acs.orglett.5b01037

TBAI/K2S2O8 Initiated Radical Cyclization to Synthesize β‐ Arylsulfonyl Naphthalenes from Homopropargylic Alcohols and Sulfonyl Hydrazides

Xiaodong Yang, Lianbiao Zhao, Bingxiang Yuan, Zhenjie Qi and Rulong Yan

Adv Synth Catal, 2017, 359, 3248
DOI: 10.1002/adsc.201700634

Efficient Cu-catalyzed one-pot odorless synthesis of sulfides from triphenyltin chloride, aryl halides and S 8 in PEG

Abed Rostami, Amin Rostami, Nasser Iranpoor and Mohammad Ali Zolfigol

Tetrahedron Letters, 2016, 57, 192
DOI: 10.1016/j.tetlet.2015.11.093

External Oxidant‐Free Oxidative Tandem Cyclization: NaI‐Catalyzed Thiolation for the Synthesis of 3‐Thiosubstituted Pyrroles

Bingxiang Yuan, Yong Jiang, Zhenjie Qi, Xin Guan, Ting Wang and Rulong Yan

Adv Synth Catal, 2019, 361, 5112
DOI: 10.1002/adsc.201900620

Surfactant-Type Catalyst for Aerobic Oxidative Coupling of Hydrazine with Thiol in Water

Xuanhe Ren, Shanyu Tang, Longjia Li, Jiao Li, Helong Liang, Ganzhong Li, Guanyu Yang, Heng Li and Bingxin Yuan

J. Org. Chem., 2019, 84, 8683
DOI: 10.1021/acs.joc.9b00451

Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

Irina P. Beletskaya and Valentine P. Ananikov

Chem. Rev., 2022, 122, 16110
DOI: 10.1021/acs.chemrev.1c00836

Nickel‐Catalyzed CS Bond Formation: Synthesis of Aryl Sulfides from Arylsulfonyl Hydrazides and Boronic Acids

Rahul Singh, Bharat Kumar Allam, Neetu Singh, Kumkum Kumari, Satish Kumar Singh and Krishna Nand Singh

Adv Synth Catal, 2015, 357, 1181
DOI: 10.1002/adsc.201400983

Iodophor-/H2O2-Mediated 2-Sulfonylation of Indoles and N-Methylpyrrole in Aqueous Phase

Yashuai Liu, Yutong Yuan, Jing He, Sheng Han and Yan Liu

Molecules, 2024, 29, 3564
DOI: 10.3390/molecules29153564

FeBr3-catalyzed regioselective hydroxysulfenylation of N-allylsulfonamides with sulfonyl hydrazides

Zhong-Qi Xu, Lin-Chuang Zheng, Lin Li, Lili Duan and Yue-Ming Li

Tetrahedron, 2019, 75, 643
DOI: 10.1016/j.tet.2018.12.044

Catalytic advances in direct functionalizations using arylated hydrazines as the building blocks

Shilpi Balgotra, Praveen Kumar Verma, Ram A. Vishwakarma and Sanghapal D. Sawant

Catalysis Reviews, 2020, 62, 406
DOI: 10.1080/01614940.2019.1702191

Annulation of 1-(2-Aminoaryl)pyrroles, Ethers with Elemental Sulfur To Give 1,3,6-Benzothiadiazepine Derivatives through Double C–S Bond Formation and C–O Cleavage of Ethers

Jie Zhang, Chuwen Song, Linfeng Sheng, Ping Liu and Peipei Sun

J. Org. Chem., 2019, 84, 2191
DOI: 10.1021/acs.joc.8b03187

Iodine Catalysed Synthesis of Luminescent β‐Carboline Tethered Thiazolo[4,5‐c]carbazole and Naphtho[2,1‐d]thiazole Derivatives and Estimation of their Light Emitting Properties

Manpreet Singh, Pamita Awasthi and Virender Singh

Eur J Org Chem, 2020, 2020, 1023
DOI: 10.1002/ejoc.201901908

Transition Metal‐Free Sulfenylation of C−H Bonds for C−S Bond Formation in Recent Years: Mechanistic Approach and Promising Future

Mohit Saroha, Jayant Sindhu, Sudhir Kumar, Kuldip K. Bhasin, Jitender M. Khurana, Rajender S. Varma and Deepak Tomar

ChemistrySelect, 2021, 6, 13077
DOI: 10.1002/slct.202102042

Copper-Catalyzed Thioetherification Reactions of Alkyl Halides, Triphenyltin Chloride, and Arylboronic Acids with Nitroarenes in the Presence of Sulfur Sources

Abed Rostami, Amin Rostami and Arash Ghaderi

J. Org. Chem., 2015, 80, 8694
DOI: 10.1021/acs.joc.5b01248

Ruthenium-catalyzed direct thiolation of alkanes and ethers using arylsulfonyl chlorides as a sulfur source

Shengrong Guo, Weimin He, Jiannan Xiang and Yanqin Yuan

Tetrahedron Letters, 2015, 56, 2159
DOI: 10.1016/j.tetlet.2015.01.068

Using the Thiyl Radical for Aliphatic Hydrogen‐Atom Transfer: Thiolation of Unactivated C−H Bonds

Liubov I. Panferova, Mikhail O. Zubkov, Vladimir A. Kokorekin, Vitalij V. Levin and Alexander D. Dilman

Angew Chem Int Ed, 2021, 60, 2849
DOI: 10.1002/anie.202011400

Visible-Light-Mediated Alkylation of Thiophenols via Electron Donor–Acceptor Complexes Formed between Two Reactants

Yi-Ping Cai, Fang-Yuan Nie and Qin-Hua Song

J. Org. Chem., 2021, 86, 12419
DOI: 10.1021/acs.joc.1c01433

Copper-Catalyzed C–S Formation for the Synthesis of Benzyl Phenyl Sulfides from Dithiocarbamates

Yu Zhou, Cheng-Li Yang, Lei Ye and Zhi-Bing Dong

Synthesis, 2022, 54, 4104
DOI: 10.1055/a-1817-2079

Piperidine Promoted Direct Sulfenylation of 2‐Naphthol with Aryl Thiols under Aqueous Conditions

Fuhong Xiao, Jingxin Tian, Qiaoyan Xing, Huawen Huang, Guo‐Jun Deng and Yuejin Liu

ChemistrySelect, 2017, 2, 428
DOI: 10.1002/slct.201601549

ChemInform Abstract: Palladium‐Catalyzed Thiolation of Alkanes and Ethers with Arylsulfonyl Hydrazides.

Sheng‐rong Guo, Wei‐ming He, Jian‐nan Xiang and Yan‐qin Yuan

ChemInform, 2015, 46
DOI: 10.1002/chin.201501108

Recent Advances of Oxidative Radical Cross‐Coupling Reactions: Direct α‐C(sp3)–H Bond Functionalization of Ethers and Alcohols

Sheng‐rong Guo, Pailla Santhosh Kumar and Minghua Yang

Adv Synth Catal, 2017, 359, 2
DOI: 10.1002/adsc.201600467

A practical synthesis of aryl sulfones via cross-coupling of sulfonyl hydrazides with aryltriazenes using copper/ionic liquid combination

Anand Kumar Pandey, Saurabh Kumar, Rahul Singh and Krishna Nand Singh

Tetrahedron, 2018, 74, 6704
DOI: 10.1016/j.tet.2018.09.059

Palladium-catalyzed direct thiolation of ethers with sodium sulfinates

Shengrong Guo, Weimin He, Jiannan Xiang and Yanqin Yuan

Tetrahedron Letters, 2014, 55, 6407
DOI: 10.1016/j.tetlet.2014.09.098

Metal-Free Iodine-Catalyzed Synthesis of Fully Substituted Pyrazoles and Its Sulphenylation

Jun Sun, Jiang-Kai Qiu, Yi-Long Zhu, Cheng Guo, Wen-Juan Hao, Bo Jiang and Shu-Jiang Tu

J. Org. Chem., 2015, 80, 8217
DOI: 10.1021/acs.joc.5b01280

Metal-free tetra-n-butylammonium bromide-mediated aerobic oxidative synthesis of β-ketosulfones from styrenes

Xin Wan, Kai Sun and Guisheng Zhang

Sci. China Chem., 2017, 60, 353
DOI: 10.1007/s11426-016-0284-2

Copper-catalyzed thiolation of imidazo[1,2-a]pyridines with (hetero)aryl thiols using molecular oxygen

Zhishuo Zheng, Deyu Qi and Lei Shi

Catalysis Communications, 2015, 66, 83
DOI: 10.1016/j.catcom.2015.03.023

Using the Thiyl Radical for Aliphatic Hydrogen‐Atom Transfer: Thiolation of Unactivated C−H Bonds

Liubov I. Panferova, Mikhail O. Zubkov, Vladimir A. Kokorekin, Vitalij V. Levin and Alexander D. Dilman

Angewandte Chemie, 2021, 133, 2885
DOI: 10.1002/ange.202011400

Synthesis of diaryl sulfides via nickel ferrite‐catalysed C─S bond formation in green media

Shiva Farzin, Abdollah Rahimi, Kamran Amiri, Abed Rostami and Amin Rostami

Applied Organom Chemis, 2018, 32
DOI: 10.1002/aoc.4409

Synthesis of Thioethers and Thioesters with Alkyl Arylsulfinates as the Sulfenylation Agent under Metal‐Free Conditions

Yahui Li, Fengxiang Zhu, Zechao Wang and Xiao‐Feng Wu

Chemistry An Asian Journal, 2016, 11, 3503
DOI: 10.1002/asia.201601376

Potassium iodide promoted thiolation of pyrazolones and benzofurans using aryl sulfonyl chlorides as sulfenylation reagents

Xia Zhao, Xiaoyu Lu, Aoqi Wei, Xiaoliang Jia, Jun Chen and Kui Lu

Tetrahedron Letters, 2016, 57, 5330
DOI: 10.1016/j.tetlet.2016.10.053

Radical approaches to C–S bonds

Zijun Wu and Derek A. Pratt

Nat Rev Chem, 2023, 7, 573
DOI: 10.1038/s41570-023-00505-x

Iodine‐Mediated Synthesis of Aromatic Thioethers with Aromatic Amines and Sulfonyl Hydrazides in High Regioselectivity via C(sp2)H Bond Functionalization

Xiaobo Pang, Likui Xiang, Xiaodong Yang and Rulong Yan

Adv Synth Catal, 2016, 358, 321
DOI: 10.1002/adsc.201500943

Efficient C−S Bond Formation by Direct Functionalization of C(sp3)−H Bond Adjacent to Heteroatoms under Metal‐Free Conditions

Feng Zhao, Qi Tan, Dahan Wang, Jinjin Chen and Guo‐Jun Deng

Adv Synth Catal, 2019, 361, 4075
DOI: 10.1002/adsc.201900666

Facial synthesis of sulfinic esters via copper-catalyzed reaction of sulfonyl hydrazides with alcohols in air

Lingjuan Chen, Jiangxin Pu, Ping Liu and Bin Dai

Journal of Saudi Chemical Society, 2019, 23, 1102
DOI: 10.1016/j.jscs.2018.10.007

I2-Catalyzed Multicomponent Reactions for Accessing Densely Functionalized Pyrazolo[1,5-a]pyrimidines and Their Disulphenylated Derivatives

Jun Sun, Jiang-Kai Qiu, Bo Jiang, Wen-Juan Hao, Cheng Guo and Shu-Jiang Tu

J. Org. Chem., 2016, 81, 3321
DOI: 10.1021/acs.joc.6b00332

TfNHNHBoc as a Trifluoromethylating Agent for Vicinal Difunctionalization of Terminal Alkenes

Jing-Yu Guo, Ruo-Xin Wu, Ji-Kang Jin and Shi-Kai Tian

Org. Lett., 2016, 18, 3850
DOI: 10.1021/acs.orglett.6b01862

Copper‐Catalyzed Sulfenylation of Boronic Acids with Sulfonyl Hydrazides

Ting‐Ting Wang, Fu‐Lai Yang and Shi‐Kai Tian

Adv Synth Catal, 2015, 357, 928
DOI: 10.1002/adsc.201400995

Engineered C–S Bond Construction

Chin-Fa Lee, R. Sidick Basha and Satpal Singh Badsara

Top Curr Chem (Z), 2018, 376
DOI: 10.1007/s41061-018-0203-6

Copper(I) Bromide‐Dimethyl Sulfide‐Catalyzed Direct Sulfanylation of 4‐Hydroxycoumarins and 4‐Hydroxyquinolinones with Arylsulfonylhydrazides and Selective Fluorescence Switch‐ On Sensing of Cadmium(II) Ion in Water

Sanjay Paul, Rajeev Shrestha, T. N. J. I. Edison, Yong Rok Lee and Sung Hong Kim

Adv Synth Catal, 2016, 358, 3050
DOI: 10.1002/adsc.201600429

AlCl3-promoted thiolation of acyl C–H bonds with arylsulfonyl hydrazides

Jie Chen, Jincheng Mao, Yue He, Daqing Shi, Binyang Zou and Guoqi Zhang

Tetrahedron, 2015, 71, 9496
DOI: 10.1016/j.tet.2015.10.030

Efficient nanostructure design: cyanuric chloride-based high energy metal organic framework (EMOF) for di-aryl sulfides synthesis under solvent-free conditions

Mahsa Morvati, Pouya Ghamari Kargar and Ghodsieh Bagherzade

Inorganic Chemistry Communications, 2025, 182, 115420
DOI: 10.1016/j.inoche.2025.115420

Synthesis of α,α-Disulfenylated Aldehydes via Oxidative Transformation of Tertiary Amines

Xin Huang, Jichao Wang, Zhangqin Ni, Sichang Wang and Yuanjiang Pan

Org. Lett., 2015, 17, 5488
DOI: 10.1021/acs.orglett.5b02876

Thiol-free route to diaryl sulfides by Cu catalyzed coupling of sodium thiosulfate with aryl halides

Najmeh Nowrouzi, Mohammad Abbasi and Hadis Latifi

Chinese Journal of Catalysis, 2016, 37, 1550
DOI: 10.1016/S1872-2067(16)62486-5

Cyclization of N-Arylacrylamides via Radical Arylsulfenylation of Carbon–Carbon Double Bonds with Sulfonyl Hydrazides

Fu-Xiang Wang and Shi-Kai Tian

J. Org. Chem., 2015, 80, 12697
DOI: 10.1021/acs.joc.5b02322

Visible-Light-Promoted Thioetherification Reactions via Electron Donor–Acceptor Complexes between Active Esters and Sulfinates

Xiao Xu and Qin-Hua Song

J. Org. Chem., 2025, 90, 9918
DOI: 10.1021/acs.joc.5c00949

Metal complex catalysis in the chemistry of lower diamondoids

Ravil I. Khusnutdinov and Nina A. Shchadneva

Russ. Chem. Rev., 2019, 88, 800
DOI: 10.1070/RCR4881

Silver-Catalyzed Direct Thiolation of Quinones by Activation of Aryl Disulfides to Synthesize Quinonyl Aryl Thioethers

Cheng Zhang, Jesse McClure and C. James Chou

J. Org. Chem., 2015, 80, 4919
DOI: 10.1021/acs.joc.5b00247

Catalyst-free, direct electrochemical trifluoromethylation/cyclization of N-arylacrylamides using TfNHNHBoc as a CF3 source

Han Wang, Yongbin Xie, Yicheng Zhou, Nannan Cen and Wenbo Chen

Chinese Chemical Letters, 2022, 33, 221
DOI: 10.1016/j.cclet.2021.06.008

Electrosynthesis of Mono- and Disulfides Based on C5–C8 Cycloalkanes, Hydrogen Sulfide, and Isomeric Dibutyl Disulfides

E. V. Shinkar’, A. V. Shvetsova, A. O. Okhlobystin and N. T. Berberova

Russ J Electrochem, 2020, 56, 285
DOI: 10.1134/S1023193520040138

Visible light photoredox catalysis with N-hydroxyphthalimide for [4+2] cyclization between N-methylanilines and maleimides

Arvind K. Yadav and Lal Dhar S. Yadav

Tetrahedron Letters, 2017, 58, 552
DOI: 10.1016/j.tetlet.2016.12.077

α-Csp3–H Bond Functionalization of Simple Ethers in Radical Reactions

Yanping Feng, Xiajuan Ye, Dayun Huang and Sheng-rong Guo

Synthesis, 2022, 54, 315
DOI: 10.1055/a-1631-1606

Transition Metal‐Promoted Direct CS and CSe Bond Formation from Csp3H Bonds

Douglas B. Paixão, Diego Seckler, Carla M. B. Gomes, Gul Badshah, Gabriel P. Bueno, Paulo H. Schneider, Ricardo S. Schwab and Daniel S. Rampon

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500111

Regioselective Cross-Couplings of Coumarins and Flavones with Ethers via C(sp3)–H Functionalization

Ben Niu, Wannian Zhao, Yingcai Ding, Zhaogang Bian, Charles U. Pittman, Aihua Zhou and Haibo Ge

J. Org. Chem., 2015, 80, 7251
DOI: 10.1021/acs.joc.5b00800

The Applications of Sulfinic Acids, Sodium Sulfinates, or Sulfonyl Hydrazides in the Radical Cyclization

Yangyang Li, Dayun Huang, Danfeng Deng and Sheng-Rong Guo

COC, 2022, 26, 369
DOI: 10.2174/1385272826666220222110614

Copper‐Catalyzed Aerobic Oxidative Reaction of Sulfonyl Hydrazides with Alcohols: An Easy Access to Sulfinates

Bingnan Du, Zan Li, Ping Qian, Jianlin Han and Yi Pan

Chemistry An Asian Journal, 2016, 11, 478
DOI: 10.1002/asia.201501262

Iron‐Catalyzed Synthesis of Substituted Thiazoles from Enamines and Elemental Sulfur through C−S Bond Formation

Mingzhong Wu, Yong Jiang, Zhenyu An, Zhenjie Qi and Rulong Yan

Adv Synth Catal, 2018, 360, 4236
DOI: 10.1002/adsc.201800693

Synthesis of 2-Aryl and 3-Aryl Benzo[b]furan Thioethers Using Aryl Sulfonyl Hydrazides as Sulfenylation Reagents

Xia Zhao, Lipeng Zhang, Xiaoyu Lu, Tianjiao Li and Kui Lu

J. Org. Chem., 2015, 80, 2918
DOI: 10.1021/acs.joc.5b00146

Sulfonyl Hydrazides in Organic Synthesis: A Review of Recent Studies

Shuangte Zhao, Kaijun Chen, Ling Zhang, Weiguang Yang and Dayun Huang

Adv Synth Catal, 2020, 362, 3516
DOI: 10.1002/adsc.202000466