Metal- and photocatalyst-free benzylic C–H halogenation via an electron donor–acceptor complex

Dejian Cao, Kaiting Sun, Chunjie Qian, Mengqi Fang, Fan Luo and Shihui Liu

Chem. Commun., 2025, 61, 18826
DOI: 10.1039/D5CC04649A

From simple organobromides or olefins to highly value-added bromohydrins: a versatile performance of dimethyl sulfoxide

Song Song, Xiaoqiang Huang, Yu-Feng Liang, Conghui Tang, Xinwei Li and Ning Jiao

Green Chem., 2015, 17, 2727
DOI: 10.1039/C5GC00184F

Organoselenium-catalyzed vicinal dichlorination of unsaturated phosphonates

Xianghua Zeng, Chunhua Gong, Junyong Zhang and Jingli Xie

New J. Chem., 2016, 40, 7866
DOI: 10.1039/C6NJ00658B

Dibrominated addition and substitution of alkenes catalyzed by Mn2(CO)10

Xianheng Song, Shanshui Meng, Hong Zhang, Yi Jiang, Albert S. C. Chan and Yong Zou

Chem. Commun., 2021, 57, 13385
DOI: 10.1039/D1CC04534B

A bromo-capped diruthenium(i,i) N-heterocyclic carbene compound for in situ bromine generation with NBS: catalytic olefin aziridination reactions

Gargi Sengupta, Pragati Pandey, Subhabrata De, Ramesh Ramapanicker and Jitendra K. Bera

Dalton Trans., 2018, 47, 11917
DOI: 10.1039/C8DT01851K

Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid

Song Song, Xinwei Li, Xiang Sun, Yizhi Yuan and Ning Jiao

Green Chem., 2015, 17, 3285
DOI: 10.1039/C5GC00528K

A simple and highly diasteroselective approach for the vicinal dichlorination of functional olefins

Xianghua Zeng, Chunhua Gong, Junyong Zhang and Jingli Xie

RSC Adv., 2016, 6, 85182
DOI: 10.1039/C6RA20101F

Eosin Y-catalyzed photooxidation of triarylphosphines under visible light irradiation and aerobic conditions

Yanbin Zhang, Cong Ye, Shijie Li, Aishun Ding, Guangxin Gu and Hao Guo

RSC Adv., 2017, 7, 13240
DOI: 10.1039/C6RA25469A

Oxidative halogenation enabled by 2-haloethanol and aqueous H2O2 under metal-free conditions

Jingran Zhang, Haofeng Shi, Dongke Zhang, Jiaxin He, Yuli Sun, Fengxia Sun and Yunfei Du

Green Synthesis and Catalysis, 2024
DOI: 10.1016/j.gresc.2024.09.009

Anti‐1,2‐Dibromination of Unsaturated Compounds Using Tetrabromomethane and TBHP: A Simple and Inexpensive Approach

Bappa Manna, Gyanendra Chaudhary, Aman Verma, Anshuman Kumar, Mukesh Nirmal, Akash Shrivastav, Deepti Verma and Amit Prabhakar

Asian J Org Chem, 2026, 15
DOI: 10.1002/ajoc.70369

Catalyst-Free 1,2-Dibromination of Alkenes Using 1,3-Dibromo-5,5-dimethylhydantoin (DBDMH) as a Bromine Source

Lei Wang, Lele Zhai, Jinyan Chen, Yulin Gong, Peng Wang, Huilin Li and Xuegong She

J. Org. Chem., 2022, 87, 3177
DOI: 10.1021/acs.joc.1c02906

α-Bromoacetate as a Mild and Safe Brominating Agent in the Light-Driven Vicinal Dibromination of Unactivated Alkenes and Alkynes

Harshvardhan Singh, Supuni I. N. Hewa Inaththappulige, Raj K. Tak and Ramesh Giri

Org. Lett., 2024, 26, 5478
DOI: 10.1021/acs.orglett.4c01778

Bromination of Olefins with HBr and DMSO

Megha Karki and Jakob Magolan

J. Org. Chem., 2015, 80, 3701
DOI: 10.1021/acs.joc.5b00211

Enantioselective Synthesis of anti–syn-Trihalides and anti–syn–anti-Tetrahalides via Asymmetric β-Elimination

Yu Tan, Shilong Luo, Dongmei Li, Nan Zhang, Shiqi Jia, Yidong Liu, Wenling Qin, Choong Eui Song and Hailong Yan

J. Am. Chem. Soc., 2017, 139, 6431
DOI: 10.1021/jacs.7b02076

Thiophane‐Catalyzed Umpolung of N‐Bromoimides for Dibromination of Olefins

Miao Wang, Teng Niu and Changming Xu

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400055

ChemInform Abstract: Triphenylphosphine Oxide‐Catalyzed Stereoselective Poly‐ and Dibromination of Unsaturated Compounds.

Tian‐Yang Yu, Yao Wang, Xiu‐Qin Hu and Peng‐Fei Xu

ChemInform, 2014, 45
DOI: 10.1002/chin.201451041

PPh3O as an Activating Reagent for One-Pot Stereoselective Syntheses of Di- and Polybrominated Esters from Simple Aldehydes

Tian-Yang Yu, Hao Wei, Yong-Chun Luo, Yao Wang, Zhu-Yin Wang and Peng-Fei Xu

J. Org. Chem., 2016, 81, 2730
DOI: 10.1021/acs.joc.5b02618

Reactions of Alkynyl Aryl Phosphine Oxide with Oxalyl Bromide

Peng Zhao, Zhenjie Gan, Zhuo Li, Lili Wang and Zheng Duan

Chinese Journal of Organic Chemistry, 2024, 44, 3753
DOI: 10.6023/cjoc202405014

Enantioselective anti-Dihalogenation of Electron-Deficient Olefin: A Triplet Halo-Radical Pylon Intermediate

Dong Zhang, Maoping Pu, Zhenzhong Liu, Yuqiao Zhou, Zhendong Yang, Xiaohua Liu, Yun-Dong Wu and Xiaoming Feng

J. Am. Chem. Soc., 2023, 145, 4808
DOI: 10.1021/jacs.2c13810

Production mechanism of active species on the oxidative bromination following perhydrolase activity

Hideyasu China, Yutaka Okada and Hiroyasu Ogino

J. Phys. Org. Chem., 2016, 29, 84
DOI: 10.1002/poc.3490

Facile NBS/DMSO mediated dibromination of olefins including selected natural products and glycals

Hafiz Ul Lah, Shabir Ahmad Mir, Gulzar Hussain, Rafiq Ahmad Wani and Syed Khalid Yousuf

J Chem Sci, 2022, 134
DOI: 10.1007/s12039-021-02003-3

Non-centrosymmetric triclinic polymorph of bis(triphenylphosphine oxide)copper(II) dibromide: Crystal structure, magnetic properties, and DFT calculations

A.S. Berezin

Journal of Molecular Structure, 2026, 1353, 144733
DOI: 10.1016/j.molstruc.2025.144733

A General Method for the Dibromination of Vicinal sp3 C–H Bonds Exploiting Weak Solvent–Substrate Noncovalent Interactions

Zaojuan Qi, Weihe Li, Yanning Niu, Enrico Benassi and Bo Qian

Org. Lett., 2021, 23, 2399
DOI: 10.1021/acs.orglett.0c04235

Bromination of 1,1-diarylethylenes with bromoethane

Ze Yu, Jialiang Jiang, Hongtai Chen and Xiangyang Tang

Synthetic Communications, 2021, 51, 2544
DOI: 10.1080/00397911.2021.1943751