Systematic comparison of the structure of homoleptic tetradentate N2O2-type Schiff base complexes of tetravalent f-elements (M(iv) = Ce, Th, U, Np, and Pu) in solid state and in solution

Thomas Radoske, Roger Kloditz, Sebastian Fichter, Juliane März, Peter Kaden, Michael Patzschke, Moritz Schmidt, Thorsten Stumpf, Olaf Walter and Atsushi Ikeda-Ohno

Dalton Trans., 2020, 49, 17559
DOI: 10.1039/D0DT03405C

Employing a template synthesis to access diastereopure Np(iv) and U(iv) complexes and analysis of their 5f orbitals in bonding

Stephanie H. Carpenter, María J. Beltrán-Leiva, Shikha Sharma, Michael L. Tarlton, James T. Moore, Andrew J. Gaunt, Enrique R. Batista, Aaron M. Tondreau and Ping Yang

Inorg. Chem. Front., 2024, 11, 3731
DOI: 10.1039/D4QI00810C

Crystallization of colourless hexanitratoneptunate(iv) with anhydrous H+ countercations trapped in a hydrogen bonded polymer with diamide linkers

Koichiro Takao, Juliane März, Moe Matsuoka, Takanori Mashita, Hiroyuki Kazama and Satoru Tsushima

RSC Adv., 2020, 10, 6082
DOI: 10.1039/C9RA10090C

Isostructural σ-hydrocarbyl phospholide complexes of uranium, neptunium, and plutonium

Michaela Černá, John A. Seed, Sara Garrido Fernandez, Michael T. Janicke, Brian L. Scott, George F. S. Whitehead, Andrew J. Gaunt and Conrad A. P. Goodwin

Chem. Commun., 2022, 58, 13278
DOI: 10.1039/D2CC04803E

Non-aqueous neptunium and plutonium redox behaviour in THF – access to a rare Np(iii) synthetic precursor

Scott A. Pattenaude, Nickolas H. Anderson, Suzanne C. Bart, Andrew J. Gaunt and Brian L. Scott

Chem. Commun., 2018, 54, 6113
DOI: 10.1039/C8CC02611D

Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids

Steven P. Kelley, Volodymyr Smetana, Stephen D. Emerson, Anja-Verena Mudring and Robin D. Rogers

Chem. Commun., 2020, 56, 4232
DOI: 10.1039/C9CC09852F

Coordination chemistry of 2,2′-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu

Joseph A. Macor, Jessie L. Brown, Justin N. Cross, Scott R. Daly, Andrew J. Gaunt, Gregory S. Girolami, Michael T. Janicke, Stosh A. Kozimor, Mary P. Neu, Angela C. Olson, Sean D. Reilly and Brian L. Scott

Dalton Trans., 2015, 44, 18923
DOI: 10.1039/C5DT02976G

Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold

Jessie L. Brown, Andrew J. Gaunt, David M. King, Stephen T. Liddle, Sean D. Reilly, Brian L. Scott and Ashley J. Wooles

Chem. Commun., 2016, 52, 5428
DOI: 10.1039/C6CC01656A

Chemical and spectroscopic characterization of plutonium tetrafluoride

Jared S. Kinyon, Eliel Villa-Aleman, Elodia Ciprian, Amy E. Hixon, Bryan J. Foley, Jonathan H. Christian, Jason R. Darvin, Don D. Dick, Amanda J. Casella, Lucas E. Sweet, Edgar C. Buck, Forrest D. Heller, Aaron D. Nicholas, Cody A. Nizinski and Richard A. Clark

Dalton Trans., 2024, 53, 19166
DOI: 10.1039/D4DT02509A

Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand

Jing Su, Thibault Cheisson, Alex McSkimming, Conrad A. P. Goodwin, Ida M. DiMucci, Thomas Albrecht-Schönzart, Brian L. Scott, Enrique R. Batista, Andrew J. Gaunt, Stosh A. Kozimor, Ping Yang and Eric J. Schelter

Chem. Sci., 2021, 12, 13343
DOI: 10.1039/D1SC03905A

Lewis base adducts of NpCl4

Lauren M. Lopez, Madeleine C. Uible, Matthias Zeller and Suzanne C. Bart

Chem. Commun., 2024, 60, 5956
DOI: 10.1039/D4CC01560F

Product Variation in Reactions of MI3(thf)4 with Bis(Mesitoyl)Phosphide Across the M = U, Np, Pu Series

Stephanie H. Carpenter, Margaret R. Jones, Daniel J. Lussier, Andrew J. Gaunt, Jesse Murillo and Aaron M. Tondreau

Inorg. Chem., 2025, 64, 7263
DOI: 10.1021/acs.inorgchem.4c04433

Preparation of Neptunyl and Plutonyl Acetates To Access Nonaqueous Transuranium Coordination Chemistry

Emily R. Mikeska, Richard E. Wilson, Asmita Sen, Jochen Autschbach and James D. Blakemore

J. Am. Chem. Soc., 2024, 146, 21509
DOI: 10.1021/jacs.4c04613

In-Plane Thorium(IV), Uranium(IV), and Neptunium(IV) Expanded Porphyrin Complexes

James T. Brewster, Daniel N. Mangel, Andrew J. Gaunt, Douglas P. Saunders, Hadiqa Zafar, Vincent M. Lynch, Michael A. Boreen, Mary E. Garner, Conrad A. P. Goodwin, Nicholas S. Settineri, John Arnold and Jonathan L. Sessler

J. Am. Chem. Soc., 2019, 141, 17867
DOI: 10.1021/jacs.9b09123

Synthesis and Characterization of Homo- and Heteroleptic Neptunium(IV) Heteroarylalkenolate Complexes

Dennis Grödler, Peter Kaden, Joseph M. Sperling, Brian M. Rotermund, Benjamin Scheibe, Nicholas B. Beck, Andreas Lichtenberg, Thomas E. Albrecht, Sanjay Mathur and Robert Gericke

Inorg. Chem., 2025, 64, 2321
DOI: 10.1021/acs.inorgchem.4c04521

Venturing Past Uranium: Synthesis of a Np(IV) Polyoxomolybdate–Alkoxide Sandwich Complex

Leyla R. Valerio, Dominic Shiels, Lauren M. Lopez, Andrew W. Mitchell, Matthias Zeller, Suzanne C. Bart and Ellen M. Matson

Inorg. Chem., 2024, 63, 22639
DOI: 10.1021/acs.inorgchem.4c04428

Neptunium Pyridine Dipyrrolide Complexes

Leyla R. Valerio, Andrew W. Mitchell, Lauren M. Lopez, Matthias Zeller, Suzanne C. Bart and Ellen M. Matson

Organometallics, 2025, 44, 439
DOI: 10.1021/acs.organomet.4c00472

Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization

Sebastian Fichter, Sebastian Kaufmann, Peter Kaden, Tobias S. Brunner, Thorsten Stumpf, Peter W. Roesky and Juliane März

Chemistry A European J, 2020, 26, 8867
DOI: 10.1002/chem.202001865

Organometallic Neptunium Chemistry

Polly L. Arnold, Michał S. Dutkiewicz and Olaf Walter

Chem. Rev., 2017, 117, 11460
DOI: 10.1021/acs.chemrev.7b00192

Neptunium Alkoxide Chemistry: Expanding Alkoxides to the Transuranium Elements

Dennis Grödler, Joseph M. Sperling, Brian M. Rotermund, Benjamin Scheibe, Nicholas B. Beck, Sanjay Mathur and Thomas E. Albrecht-Schönzart

Inorg. Chem., 2023, 62, 2513
DOI: 10.1021/acs.inorgchem.2c04338

Comparative Analysis of Tetravalent Actinide Schiff Base Complexes: Influence of Donor and Ligand Backbone on Molecular Geometry and Metal Binding

Tamara M. Duckworth, Robert Gericke, Peter Kaden, Luisa Köhler, Adrian Näder, Juliane März, Michael Patzschke, Thorsten Stumpf and Moritz Schmidt

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403081

Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions

Cory J. Windorff, Megan T. Dumas, Joseph W. Ziller, Andrew J. Gaunt, Stosh A. Kozimor and William J. Evans

Inorg. Chem., 2017, 56, 11981
DOI: 10.1021/acs.inorgchem.7b01968

Expanding the Nonaqueous Chemistry of Neptunium: Synthesis and Structural Characterization of [Np(NR2)3Cl], [Np(NR2)3Cl]−, and [Np{N(R)(SiMe2CH2)}2(NR2)]− (R = SiMe3)

Selena L. Staun, Lauren M. Stevens, Danil E. Smiles, Conrad A. P. Goodwin, Brennan S. Billow, Brian L. Scott, Guang Wu, Aaron M. Tondreau, Andrew J. Gaunt and Trevor W. Hayton

Inorg. Chem., 2021, 60, 2740
DOI: 10.1021/acs.inorgchem.0c03616

Transuranium organometallic chemistry

Benjamin L. L. Réant, Cameron N. Deakin, Ross E. MacKenzie and Conrad A. P. Goodwin

Nat Rev Chem, 2025, 9, 578
DOI: 10.1038/s41570-025-00732-4

Formation of Fully Stoichiometric, Oxidation-State Pure Neptunium and Plutonium Dioxides from Molecular Precursors

Appie Peterson, Sheridon N. Kelly, Trevor Arino, S. Olivia Gunther, Erik T. Ouellette, Jennifer N. Wacker, Joshua J. Woods, Simon J. Teat, Wayne W. Lukens, John Arnold, Rebecca J. Abergel and Stefan G. Minasian

Inorg. Chem., 2024, 63, 18417
DOI: 10.1021/acs.inorgchem.4c02099

Carbon oxygenate transformations by actinide compounds and catalysts

Polly L. Arnold and Zoë R. Turner

Nat Rev Chem, 2017, 1
DOI: 10.1038/s41570-016-0002

Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex

Alexander J. Myers, Michael L. Tarlton, Steven P. Kelley, Wayne W. Lukens and Justin R. Walensky

Angewandte Chemie, 2019, 131, 15033
DOI: 10.1002/ange.201906324

A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes

Cory J. Windorff, Joseph M. Sperling, Thomas E. Albrecht-Schönzart, Zhuanling Bai, William J. Evans, Alyssa N. Gaiser, Andrew J. Gaunt, Conrad A. P. Goodwin, David E. Hobart, Zachary K. Huffman, Daniel N. Huh, Bonnie E. Klamm, Todd N. Poe and Evan Warzecha

Inorg. Chem., 2020, 59, 13301
DOI: 10.1021/acs.inorgchem.0c01671

Coordination Chemistry and QTAIM Analysis of Homoleptic Dithiocarbamate Complexes, M(S2CNiPr2)4 (M = Ti, Zr, Hf, Th, U, Np)

Andrew C. Behrle, Alexander J. Myers, Andrew Kerridge and Justin R. Walensky

Inorg. Chem., 2018, 57, 10518
DOI: 10.1021/acs.inorgchem.8b00077

Synthesis of Non‐Aqueous Neptunium(III) Halide Solvates from NpO2

Megan A. Whitefoot, Diana Perales, Matthias Zeller and Suzanne C. Bart

Chemistry A European J, 2021, 27, 18054
DOI: 10.1002/chem.202103265

Bonding Trends in Tetravalent Th–Pu Monosalen Complexes

Thomas Radoske, Juliane März, Michael Patzschke, Peter Kaden, Olaf Walter, Moritz Schmidt and Thorsten Stumpf

Chemistry A European J, 2020, 26, 16853
DOI: 10.1002/chem.202003241

Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex

Alexander J. Myers, Michael L. Tarlton, Steven P. Kelley, Wayne W. Lukens and Justin R. Walensky

Angew Chem Int Ed, 2019, 58, 14891
DOI: 10.1002/anie.201906324

Using Redox-Active Ligands to Generate Actinide Ligand Radical Species

Shane S. Galley, Scott A. Pattenaude, Debmalya Ray, Carlo Alberto Gaggioli, Megan A. Whitefoot, Yusen Qiao, Robert F. Higgins, W. L. Nelson, Ryan Baumbach, Joseph M. Sperling, Matthias Zeller, Tyler S. Collins, Eric J. Schelter, Laura Gagliardi, Thomas E. Albrecht-Schönzart and Suzanne C. Bart

Inorg. Chem., 2021, 60, 15242
DOI: 10.1021/acs.inorgchem.1c01766

How 5 f Electron Polarisability Drives Covalency and Selectivity in Actinide N‐Donor Complexes

Luisa Köhler, Michael Patzschke, Moritz Schmidt, Thorsten Stumpf and Juliane März

Chemistry A European J, 2021, 27, 18058
DOI: 10.1002/chem.202102849

Advances in containment methods and plutonium recovery strategies that led to the structural characterization of plutonium(IV) tetrachloride tris-diphenylsulfoxide, PuCl4(OSPh2)3

Samantha K. Cary, Kevin S. Boland, Justin N. Cross, Stosh A. Kozimor and Brian L. Scott

Polyhedron, 2017, 126, 220
DOI: 10.1016/j.poly.2017.01.013

A Linear trans-Bis(imido) Neptunium(V) Actinyl Analog: NpV(NDipp)2(tBu2bipy)2Cl (Dipp = 2,6-iPr2C6H3)

Jessie L. Brown, Enrique R. Batista, James M. Boncella, Andrew J. Gaunt, Sean D. Reilly, Brian L. Scott and Neil C. Tomson

J. Am. Chem. Soc., 2015, 137, 9583
DOI: 10.1021/jacs.5b06667

Probing the Framework Metal Dependent Properties of Actinide-Centered Polyoxoalkoxide Sandwich-Type Complexes

Dominic Shiels, Adriana C. Berlfein, Barbara M. T. C. Peluzo, Lauren M. Lopez, Andrew W. Mitchell, William W. Brennessel, Matthias Zeller, Matthew R. Crawley, Suzanne C. Bart, Michael T. Ruggiero and Ellen M. Matson

Inorg. Chem., 2025, 64, 9180
DOI: 10.1021/acs.inorgchem.5c00780

Uranium(IV) Chloride Complexes: UCl62– and an Unprecedented U(H2O)4Cl4 Structural Unit

Jennifer N. Wacker, Monica Vasiliu, Kevin Huang, Ryan E. Baumbach, Jeffery A. Bertke, David A. Dixon and Karah E. Knope

Inorg. Chem., 2017, 56, 9772
DOI: 10.1021/acs.inorgchem.7b01293

From Thorium to Plutonium: Trends in Actinide(IV) Chloride Structural Chemistry

Jennifer N. Wacker, Sae Young Han, Aphra V. Murray, Nicole A. Vanagas, Jeffery A. Bertke, Joseph M. Sperling, Robert G. Surbella and Karah E. Knope

Inorg. Chem., 2019, 58, 10578
DOI: 10.1021/acs.inorgchem.9b01279

[AnI3(THF)4] (An = Np, Pu) Preparation Bypassing An0 Metal Precursors: Access to Np3+/Pu3+ Nonaqueous and Organometallic Complexes

Conrad A. P. Goodwin, Michael T. Janicke, Brian L. Scott and Andrew J. Gaunt

J. Am. Chem. Soc., 2021, 143, 20680
DOI: 10.1021/jacs.1c07967

Chlorination of Pu and U Metal Using GaCl3

Stephanie H. Carpenter, Bonnie E. Klamm, Taylor V. Fetrow, Brian L. Scott, Andrew J. Gaunt, Nickolas H. Anderson and Aaron M. Tondreau

Inorg. Chem., 2023, 62, 8462
DOI: 10.1021/acs.inorgchem.3c00522

Fate of Oxidation States at Actinide Centers in Redox‐Active Ligand Systems Governed by Energy Levels of 5 f Orbitals

Tomoyuki Takeyama, Satoru Tsushima, Robert Gericke, Peter Kaden, Juliane März and Koichiro Takao

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302702

Structure, Covalency, and Paramagnetism of Homoleptic Actinide and Lanthanide Amidinate Complexes

Boseok Hong, Adrian Näder, Till Sawallisch, Tobias Bode, Sebastian Fichter, Robert Gericke, Peter Kaden, Michael Patzschke, Thorsten Stumpf, Moritz Schmidt and Juliane März

Inorg. Chem., 2024, 63, 17488
DOI: 10.1021/acs.inorgchem.4c01901

Ligand Control of Oxidation and Crystallographic Disorder in the Isolation of Hexavalent Uranium Mono-Oxo Complexes

Julie E. Niklas, Chad M. Studvick, John Bacsa, Ivan A. Popov and Henry S. La Pierre

Inorg. Chem., 2023, 62, 2304
DOI: 10.1021/acs.inorgchem.2c04056

The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds

Sara E. Gilson and Peter C. Burns

Coordination Chemistry Reviews, 2021, 445, 213994
DOI: 10.1016/j.ccr.2021.213994

Conversion of Americia to Anhydrous Trivalent Americium Halides

Shane S. Galley, Joseph M. Sperling, Cory J. Windorff, Matthias Zeller, Thomas E. Albrecht-Schmitt and Suzanne C. Bart

Organometallics, 2019, 38, 606
DOI: 10.1021/acs.organomet.8b00840

Aqueous Speciation of Tetravalent Actinides in the Presence of Chloride and Nitrate Ligands

Rameswar Bhattacharjee and Pere Miró

Inorg. Chem., 2022, 61, 14718
DOI: 10.1021/acs.inorgchem.2c02064