The title compound is the first carboxylate–phosphonate with an extended three-dimensional structure, a framework of trimers of edge-sharing CoO6-octahedra and organic species with two different functional groups, carboxylic and phosphonic, both coordinated to the metal atoms.
A. Distler and S. C. Sevov, Chem. Commun., 1998, 959 DOI: 10.1039/A801964I
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