Issue 1, 1998

Synthesis and structure of a novel binuclear rhenium(I) complex containing an unusual bridging ligand derived from coordinated acetonitrile. Unusual reactivity of [Re(CO)3(bpy)(MeCN)]+

Abstract

[Re(CO)3(bpy)(MeCN)]+ forms a novel binuclear rhenium(I) complex containing a N[triple bond, length half m-dash]CCH[double bond, length half m-dash]C(CH3)NH bridge derived from the reaction of the coordinated acetonitrile with NaH; the crystal structure of which has been determined.

Article information

Article type
Paper

Chem. Commun., 1998, 135-136

Synthesis and structure of a novel binuclear rhenium(I) complex containing an unusual bridging ligand derived from coordinated acetonitrile. Unusual reactivity of [Re(CO)3(bpy)(MeCN)]+

V. Wing-Wah Yam and K. Man-Chung Wong, Chem. Commun., 1998, 135 DOI: 10.1039/A707514F

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