The types of complexes mentioned in the title are prepared by sodium amalgam reduction of trans-[WCl4(PR3)2](PR3= tertiary phosphine) under dihydrogen, carbon monoxide, or dinitrogen, respectively.
B. Bell, J. Chatt and G. J. Leigh, J. Chem. Soc. D, 1970, 842a DOI: 10.1039/C2970000842A
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