Issue 5, 2021

Ba3[Al(PO4)3]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO4)4]9− units

Abstract

A new SHG material, Ba3[Al(PO4)3], has been rationally designed by expanding the anionic condensation design strategy from atom-sharing to anionic-group-sharing. As the first Ba3[B(PO4)3]-type acentric phosphate, Ba3[Al(PO4)3] is characterized by moderate second-order optical nonlinearity, beneficial type I phase-matching behavior, deep-UV transparency and high thermal stability, favourable for practical applications.

Graphical abstract: Ba3[Al(PO4)3]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO4)4]9− units

Supplementary files

Article information

Article type
Communication
Submitted
07 pro 2020
Accepted
24 pro 2020
First published
24 pro 2020

J. Mater. Chem. C, 2021,9, 1550-1554

Ba3[Al(PO4)3]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO4)4]9− units

Z. Fang, C. Hu, B. Yang and J. Mao, J. Mater. Chem. C, 2021, 9, 1550 DOI: 10.1039/D0TC05743F

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