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Encoded fluorescent particles are fabricated through the selective uptake of dyes in photopatterned metal–organic framework single crystals. The concept is based on spatially controlled photochemical cleavage of pore-blocking pendant groups. Because of the crystalline and porous nature of the host, this approach enables guest uptake that is tunable and can be triggered though controlled irradiation.

Graphical abstract: Photopatterning of fluorescent host–guest carriers through pore activation of metal–organic framework single crystals

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