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Facial Ru(II)- and Re(I)-complexes of a novel face-capping tris(pyridyl)truxene ligand were synthesised and characterised by various analytical techniques including single crystal XRD. The Ru(II) complex exhibits unusual green phosphorescence with a long excited-state lifetime.

Graphical abstract: Synthesis and photophysical properties of C3-symmetric tris(pyridyl)truxene scaffolds of Ru(ii) and Re(i)

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