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The bimetallic chiral bipyridyl-type metalloligands based on aluminium derivatives of cinchonine, [R2Al(μ-CN)]2 (R = Me or Et), in combination with the corresponding ZnR2 compound as nodes were used for the generation of novel homochiral heterometallic coordination polymers of either zig-zag or helical topology, depending on the character of the R substituent.

Graphical abstract: Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers

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