A triple quadrupole mass spectrometer has been used to study the reactions of simple even-electron ions (e.g. CH3+, CH2F+, etc.) with acetylene and substituted acetylenes; CH3+ reacts with C2H2 to give C3H3+ in very high yield.
A. Mitchell, J. K. Conner, K. Stanney and J. M. Tedder, J. Chem. Soc., Chem. Commun., 1984, 1529 DOI: 10.1039/C39840001529
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