We report the synthesis, isolation, and comprehensive characterization of N-heterocyclic carbene gold xanthate (NHC–Au–X, X – xanthate) complexes. These easily accessible complexes demonstrate significant versatility as photocatalysts, facilitating [2+2]-cycloadditions, and as π-catalysts in the intramolecular hydroxylation of allenes and hydrohydrazination of alkynes.
S. Chakraborty, A. Gorski, O. Danylyuk, K. Niemirowicz-Laskowska, H. Car and M. Michalak, Chem. Commun., 2025, 61, 1697 DOI: 10.1039/D4CC05193A
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