Shixiong
Zhai
abc,
Zhendong
Jin
ab,
Chengcheng
Li
ab,
JiaFeng
Sun
ab,
Hong
Zhao
ab,
Zhehai
Jin
ab,
Zaisheng
Cai
ab and
Yaping
Zhao
*ab
aKey Lab of Science & Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, P. R. China. E-mail: zhaoyping@dhu.edu.cn
bCollege of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, P. R. China
cDepartment of Chemistry, University of Calgary, Calgary, Alberta T2N 1N4, Canada
First published on 9th February 2023
A new strategy has been designed for enhancing the electrochemical performances of supercapacitor electrodes. In this work, flexible hetero-structure conductive cotton equipped with lamellar structure nickel/cobalt-based MOFs (NiCo-MOFs) is prepared through a self-sacrificial template method. The in situ conversion measure effectively strengthens the binding forces between the active materials and the current collector, which decreases the charge transfer resistance at the electrode–electrolyte interfaces. Morphological modulation of the NiCo-MOFs is carried out to construct fast transport channels for ions and charges during the charging–discharging process. The optimized NiC/NiCoMOF21 is composed of uniformly dispersed nanosheets with large gaps, which can provide more free space and active sites for electrode reactions. The energy density of the asymmetric supercapacitor (carbon cloth as the negative electrode) reaches 0.38 mW h cm−2 at 1.6 mW cm−2 (16.7% loss of the initial capacity after 2000 cycles), which overcomes the low energy storage performance of the existing textile-based electrodes.
Metal–organic frameworks (MOFs), as emerging crystalline materials coordinated with organic linkers, have been regarded as promising materials for supercapacitor electrodes.11–13 The structural properties of MOFs could optimize the molecular surface areas, which leads to the formation of a lot of chemical reaction sites.14 Besides, the good porosity and crystallinity of MOF-based materials could enable them to supply much more charge transfer channels at electrode–electrolyte interfaces than single-phase materials.15 Kishore et al.16 reported a zinc oxide-1,4-benzene dicarbox (MOF5)/NiCo2O4 composite for supercapacitor electrodes, which exhibits a specific capacitance of 557.50 F g−1 at 5 mV s−1 of the scan rate. However, a great challenge of MOF based materials at present is their poor conductivity which resulted from the introduction of organics.17 To solve this problem, many composite materials have been prepared. Mohanadas prepared copper-based metal–organic framework (Cu-MOF)/reduced graphene (RGO) using a hydrothermal method. Benefiting from the improved electrical conductivity, the hybrid material delivered a high specific energy of 31.2 W h kg−1 at 656.4 W kg−1. Li et al.18 fabricated a nickel gallium layered hydroxide nanosheet (NiGa-LDH)/carbon nanotube (CNT) composite for supercapacitor electrodes, which exhibits an improved specific capacitance of 2580 F g−1 at 1 A g−1. Although the conductivity of MOFs has been greatly increased by combining them with highly conductive materials, most of the materials reported in the past are powders which rely on non-conductive adhesives to combine with the current collector.19 This inevitably affects the holistic conductivity of the electrode. Therefore, directly growing MOF/highly conductive material composites on a current collector might be a feasible method to obtain high energy density electrodes with low electrical resistivity.20
Textiles with good flexibility and permeability could meet many practical applications.21 It is a considerable way to combine MOFs with textiles for expanding the application scenarios of MOFs.22 Fabric-based flexible composite materials could be used in many fields like sensors,23 removal of oil spills,24 ionic liquid welding,25 photocatalysts,26etc. Cotton, as one of the most important textiles, has excellent three-dimensional interlaced network structures which could provide a large active area for active materials.27 However, cellulose cannot be directly used for a current collector of the electrode due to its insulation properties. Many studies have been carried out to prepare a modified cotton fabric with good electrical conductivity. Ahirrao et al.28 prepared a highly conductive carbon cloth (CC) through carbonizing cotton. The synthesized CC was used for flexible current collectors. The polyaniline (PANI)/CC flexible electrode showed a specific capacitance of 691 F g−1 at 1 A g−1. Karami et al.29 used RGO and silver (Ag) nanoparticles to enhance the conductivity of cotton. The symmetric supercapacitor based on Ag/RGO/cotton composite electrodes showed a large energy density of 43.2 W h Kg−1 at 123 W Kg−1. Besides precious metals and carbon materials, Ni-based materials are also famous for preparing a cotton fabric with high electrical conductivity. Ding et al.30 reported a highly conductive cotton fabric by Ni-tungsten (W)–phosphorus electroless plating for electromagnetic shielding textile. The electrical conductivity of the Ni-W-P/cotton composite was only 0.08 Ω sq−1. Wang et al.31 prepared NiCoS nanoflakes/cotton for a self-supporting electrode, which shows an energy density of 48.9 W h kg−1 at 390 W kg−1. Nevertheless, conductive cotton electrodes prepared using physical or chemical methods are good candidate materials for supercapacitor electrodes. However, the low capacitive performance of the existing textile-based electrodes (TBEs) severely limited their practical application.32 How to improve the electrochemical reactivity on TBE surfaces becomes an urgent problem.33
Taking into account all of the above, we attempt to equip NiCo-based MOFs on conductive cotton for preparing high-performance flexible supercapacitor electrodes (Fig. 1). In this work, conductive cotton was prepared by a electroless nickel plating method, considering that directly sacrificing a metal to provide ion sources is not conducive to the structural orientation of the products. Electrochemical oxidation was performed to enhance the interfacial properties of the Ni-plated cotton electrode. The strategy of in situ conversion strengthens the binding forces between the depositions and the substrate in comparison with many loose structures of Ni deposited with Ni(OH)2 as previously reported.32 Nickel nitrate (Ni(NO3)2) and cobalt nitrate (Co(NO3)2) were used as Ni and Co sources. Terephthalic acid (PTA) was used as the organic ligand. NiCo-based bimetallic MOFs were in situ grown on the NiC surfaces through a solvothermal method. Electron exchanges occurred between metal ions and PTA ligands under solvothermal conditions, which led to the formation of oriented MOF materials on the NiC substrate. To our knowledge, sacrificing specially structured precursor templates on a flexible substrate for synthesizing regular MOF materials has been rarely reported. The sacrifice of the template could effectively improve the actual orientation of the synthesized MOFs. We prepared NiCo-based bimetallic MOFs constructed on NiC with various compositions and morphologies by adjusting the ratio of Ni to Co. Besides, we explored the relationship between energy storage performances and physicochemical structures of the samples. The lamellar structure MOFs in situ grown on the NiC were combined with the Ni-microspheres firmly. These fancy three-dimensional composite structures not only reduce the electrochemical resistance of the pristine MOFs but expose numerous redox sites at the electrode–electrolyte interfaces. As we expected, the assembled supercapacitor based on the optimized NiCo-based MOF composite electrode shows a satisfactory energy density with good cycling stability. It is no doubt that exploring the construction mechanism and the structure–function relationship of NiC/NiCo-based MOFs will have a great significance for preparing high-performance supercapacitor electrodes.
Fig. 1 Schematic diagram of the preparation process of NiC/NiCo-MOFs (a and b) and the modification process of cotton. (c) Preparation of NiC/NiCo-MOFs by a hydrothermal method. |
Fig. 2c shows the Fourier-transform infrared (FTIR) spectra of the samples. The predominant peaks detected at about 1580 cm−1 and 1374 cm−1 could be ascribed to the –COOH groups in PTA ligands.38 The peaks at 1501 cm−1 and 751 cm−1 are assigned to the stretching vibrations of CC and C–H of the benzene ring.39 Other peaks lower than 1000 cm−1 are attributed to Ni–OH or Co–OH groups.40 Moreover, a distinct peak located at about 3606 cm−1 corresponding to benzene dicarboxylic acid coordinated with metal ions could be identified, which further confirms the structures of Co–COO–Co and Ni–COO–Ni.41 The molecular model of NiCo-MOF is shown in Fig. 2d. Ni or Co atoms, as inorganic metal centers, bind with PTA ligands to form a crystal–organic hybrid composite with a periodic network structure. The distance between the Ni/Co atoms are significantly enlarged because of the introduction of the PTA ligand. Therefore, the difference in the charge density of Ni-MOF and Co-MOF leads to a large gap between inorganic metal atoms (Fig. 2e).42 The total density of states (TDOS) of NiCo-MOF is calculated taking into account the DOS of both Ni-MOF and Co-MOF (Fig. 2g). The main peaks of NiCo-MOF could be well recognized as the combination of the peaks of single Ni-MOF and single Co-MOF, which demonstrates the binding stability of NiCo-MOF.43
The bonding states of NiC/NiCoMOF12, NiC/NiCoMOF11 and NiC/NiCo21 MOF were investigated by XPS (Fig. 3). C, O, Ni and Co elements coexist in all samples, proving the chemical composition of NiC/NiCo-MOFs (Fig. 3a). C, O and partial Ni elements are derived from the NiC substrate. The other Ni and Co elements originate from NiCo-MOFs anchored on NiC. The high-resolution spectra of C 1s, O 1s, Ni 2p and Co 2p are displayed in Fig. 3b–e. The deconvoluted peaks of C 1s at 284.6 eV, 285.2 eV and 288.7 eV correspond to CC, CO and OC–O bonds (Fig. 3b).44 Three peaks in O 1s spectra located at 531.4 eV, 532.1 eV and 532.6 eV could be observed, which are attributed to the metal–oxygen (O–Ni/Co), O–C and OC–O bonds (Fig. 3c).45 In Fig. 3d, the peaks at 856.1 eV and 874.7 eV are corresponding to the Ni 2p3/2 and Ni 2p1/2 in Ni2+. The spin-energy separation of 17.6 eV demonstrates the existence of Ni2+.32 For Co 2p, two prominent peaks at 797.6 eV and 781.3 eV with a spin-energy separation of 16.1 eV could be assigned to Co 2p1/2 and Co 2p3/2 of Co2+ in NiCo-MOFs.46 The characteristic peaks of Ni in all Ni–Co ratio samples were much more intense than those of Co. This might be due to the competitive effect of Ni2+ and Co2+ to combine with organic ligands.47 Ni2+ was more likely to win the Co2+ in the combination process between metal ions and PTA ligands.48
Fig. 3 XPS spectra: (a) Full survey; (b) C 1s of NiC/NiCoMOF12, NiC/NiCoMOF11, NiC/NiCoMOF21; (c) O 1s; (d and e) Ni 2p and Co 2p. |
The micro-morphologies of the samples were investigated by SEM (Fig. 4). The proportion of reactants has a huge influence on the morphology of the products. NiC/NiCo-MOFs are constructed using secondary structures with different thickness nanosheets. The distance between atoms in Fig. 4a–d was obtained from materials studio software. The distance between Co atoms (2.52 Å) is larger than that of Ni (2.48 Å), which might make Co tend to form a more stacked structure during the crystal growth process (Fig. 4a and b). Therefore, the cluster degree of the nanosheets is enhanced with the increased ratio of Co to Ni. The lattice distance of the Co-MOF (2.81 Å) and Ni-MOF (3.22 Å) is bigger than that of Co and Ni. The introduction of organic PTA could effectively separate the monatomic metals, which results in the generation of voids and a large specific surface area. The TEM and HRTEM images of NiC/NiCoMOF01 and NiC/NiCoMOF10 are shown in Fig. S5 (ESI†). The lattice distances of the two samples are 0.27 nm and 0.33 nm, which are close to the theoretical calculation values. NiC and NiC/NiCoMOF10 are micro-spheres stacked with nano-Ni flakes (Fig. 4e–l). NiC/NiCoMOF01 is composed of nano-flowers with thick nano-Co sheets. The morphologies of NiC/NiCoMOF12, NiC/NiCoMOF11 and NiC/NiCoMOF21 are accordion-like structures composed of nanosheets with different stacking degrees, which proves the occurrence of phase transformation between Ni-MOFs and Co-MOFs.49 The distributions of NiC/NiCoMOF12 nanosheets (Fig. 4m and n) and NiC/NiCoMOF11 (Fig. 4i–g) are more disperse than NiC/NiCoMOF01, which could provide more active sites in electrochemical reactions.27 Compared to other samples, NiC/NiCoMOF21 has no uniformly dispersed nanosheets but large gaps between the interlaced independent units. This structure has more free space and a favorable ion transport pathway, which is beneficial to improve the reactivity of the active material in the electrode process. Fig. 4q–t display the element mappings of the NiC/NiCoMOF21 with different magnifications compared to SEM images, which further confirms the successful coordination between Ni, Co species and organic PTA ligands.
The electrochemical performances of NiC-based NiCo-MOFs were measured using a three-electrode system. 2 M KOH aqueous solution was used as the electrolyte. Fig. 5a shows the CV curves of the five samples at 2 mV s−1 (−0.2 to 0.6 V of the potential window). All the samples showed similar redox peaks, which corresponds to the reversible faradaic pseudo-capacitive reactions between Ni2+/Co2+and Ni3+/Co3+.50 OH− ions were intercalated and de-intercalated at the NiC/NiCoMOF-electrolyte interfaces during the electrode reaction, which results in the phase transition from Ni–O/Co–O to Ni–O–OH/Co–O–OH. NiC/NiCoMOF21 possesses the biggest CV curve area, demonstrating the optimum stoichiometric ratio of Co-MOF to Ni-MOF in NiC/NiCoMOFs. Based on Formula (S1) (ESI†), the specific capacities of the NiC/NiCoMOFs could be obtained from GCD curves (Fig. 5b and d). NiC/NiCoMOF21 shows higher specific capacity (24.4 C cm−2 at 10 mA cm−2) than that of NiC/NiCoMOF01 (3.6 C cm−2 at 10 mA cm−2), NiC/NiCoMOF10 (12.6 C cm−2 at 10 mA cm−2), NiC/NiCoMOF12 (13.2 C cm−2 at 10 mA cm−2) and NiC/NiCoMOF11 (14.6 C cm−2 at 10 mA cm−2). The GCD curves of NiC are shown in Fig. S8 (ESI†). All the NiC/NiCoMOFs show better specific capacities than the NiC substrate (2.1 C cm−2), proving the improvement in electrochemical performance by introducing the Ni-MOF and Co-MOF. Particularly, the specific capacities of all bimetallic MoFs are much higher than those of single metal-based MOFs. This suggests that synergistic effects between Ni-MOF and Co-MOF existed in the composite.39 Interfacial reactions occurred between the two different metal-based MOFs during the hydrothermal reaction, which improves the redox reactivity of each component.51 NiC/NiCoMOF21 has the best specific capacity among other samples, which could be ascribed to its optimized structure. N2 adsorption–desorption isotherms of the samples are displayed in Fig. S6 (ESI†), from which it can be observed that NiC/NiCoMOF21 shows the highest specific surface (50.3 m2 g−1) area among NiC/NiCoMOF01 (27.9 m2 g−1), NiC/NiCoMOF10 (39.1 m2 g−1), NiC/NiCoMOF12 (33.4 m2 g−1) and NiC/NiCoMOF11 (43.5 m2 g−1). Two-dimensional ordered nanosheets could not only expose more available redox active sites but also shorten the ion diffusion distances, which significantly promote the reaction kinetics of the electrode. Besides, the thinner nanosheets structure of NiC/NiCoMOF21 could further improve the ion transport efficiency between the interfaces of the electrode and electrolyte.52
The sheet resistance of the samples was measured using a four-probe resistance tester (Table S2, ESI†). The cotton fabrics with insulating properties were changed to conductive materials after the deposition of Ni. The conductivity of the NiC/NiCoMOFs was lower than that of NiC, which might be due to the introduction of the organic PTA ligand. Furthermore, electrochemical impedance spectroscopy (EIS) was performed to study the charge transfer resistance of the samples (Fig. 5d). The intersection with real axis (Z′-axis) corresponds to the intrinsic ohmic resistance of the electrodes (Rs), and the diffusion resistance of ions is related to the diameter of the semicircle (Rct). NiC/NiCoMOF01 has the lowest Rs (1.3 Ω) among NiC/NiCoMOF11 (1.98 Ω), NiC/NiCoMOF21 (2.21 Ω), NiC/NiCoMOF12 (1.69 Ω) and NiC/NiCoMOF10 (2.34 Ω). This could be boiled down to the lower electrical resistivity of Co metals in comparison with the Ni metal.53 However, NiC/NiCoMOF10 and NiC/NiCoMOF21 have lower Rct values (0.7 Ω and 0.9 Ω) than NiC/NiCoMOF11 (1.0 Ω), NiC/NiCoMOF12 (1.29 Ω) and NiC/NiCoMOF01. This is because that the more dispersed nanostructures could provide numerous charge transfer channels, which accelerates the ion exchange at electrode–electrolyte interfaces.52
The theory of voltammetric-response (TVR) is applied to study the charge storage kinetics of NiC/NiCoMOF21 electrodes (Formula (S4)–(S6), ESI†). The value of the electric current will be changed with the changed scan rate. In general, the logarithm of the current and the logarithm of the scan rate are linearly dependent in a surface-limited process (i = av1 in Formula (S4), ESI†). If b = 0.5, it is a diffusion-limited reaction. The b-value could be obtained from CV curves. The b values of the NiC/NiCoMOF21 electrode are 0.52 (cathode current) and 0.53 (anode current) respectively, suggesting that the charge storage reaction of the NiC/NiCoMOF21 electrode was dominated by a diffusion-controlled process (Fig. 6a and c). The b values of NiC/NiCoMOF11 (0.53 of the cathode and anode current) and NiC/NiCoMOF12 (0.53 of the cathode current and 0.55 of the anode current) were slightly higher than those of NiC/NiCoMOF21 (Fig. 6c). This might be due to the more plentiful secondary structure supported by the stacked nanosheets of NiC/NiCoMOF21, which increase the active sites at the electrode–electrolyte interfaces. Therefore, the redox reactions of NiC/NiCoMOF21 were more sufficient, resulting in the high proportion of battery-type response in the electrode process. Based on Formula (S5) and (S6) (ESI†), the proportion of capacitive behavior (k1·v) and the Faraday process (k2·v0.5) could be calculated. The fitting results are displayed in Fig. 6d and e. 16–51% of the total current was occupied by the surface-limited process at 1–10 mV s−1 of the scan rates. Diffusion-controlled contribution of the entire current became smaller at higher scan rates. This is because the redox reactions between the electrode active materials and electrolyte became insufficient at large scan rates, which makes the intercalation of OH− ions into the electrode become more difficult. According to the Formula (S1) (ESI†), the specific capacities of NiC/NiCoMOF21 could be calculated from the GCD curves (Fig. 6b). The NiC/NiCoMOF21 electrode achieved high specific capacities of 24.8 C cm−2, 24.4 C cm−2, 21.7 C cm−2, 18.8 C cm−2 and 14.6 C cm−2 at the current densities of 5 mA cm−2, 10 mA cm−2, 15 mA cm−2, 20 mA cm−2 and 25 mA cm−2. The capacity retention reached 59% with the current densities increasing from 5 to 25 mA cm−2, which further indicates the excellent electrochemical energy storage performances of the NiC/NiCoMOF21.
To measure the practical performances of the NiC/NiCoMOF21 electrode, a hybrid supercapacitor (NCMC-Sp) based on NiC/NiCoMOF21 (positive electrode) and activated carbon cloth (CC, negative electrode) was assembled (Fig. 7g). The activated carbon cloth was obtained by the carbonization and KOH activation of the cotton at 800 °C under N2 atmosphere. The suitable potential windows of Cc and NiC/NiCoMOF21 are −1 to 0 V and −0.2 to 0.6 V, demonstrating that the NCMC-Sp device is hopeful to achieve a stable voltage potential of 1.6 V (Fig. 7a). Fig. 7b shows the CV profiles of the NCA-Sp at different potential windows at 100 mV s−1. The undistorted CV curves could be maintained until the voltage window was extended to 0 to 1.6 V, which confirms the matched voltage window of NCMC-Sp and Cc. Accordingly, the charges could be swimmingly stored in the electrode with a wide potential window of 1.6 V (Fig. 7c), while the polarization reaction occurred on the electrode surface made the charging process become difficult.54 Therefore, the optimized working potential of the NCMC-Sp device is 0 to 1.6 V. The CV curves of NCMC-Sp have no obvious change at various scan rates (5–100 mV s−1), suggesting the good rate performance of the device (Fig. 7d). According to Formula (S2) and S3 (ESI†) and GCD curves (Fig. 7e), the energy densities of NCMC-Sp are calculated to be 0.38, 0.36, 0.33, 0.30 and 0.29 mW h cm−2 at 1.6, 2.4, 4.0, 6.4, 8.0 and 12.0 mW cm−2, which are comparable to those of other electrodes reported recently (Fig. 7h).55–61 The CV curves of NCMC-Sp under different bending angles are shown in Fig. 7i and j. No obvious changes in current response curves prove the good flexibility of the NCMC-Sp. Fig. 7f shows the cycling stability of the NCMC-Sp. The capacity of the device is increased during the first 100 cycles, which could be attributed to the electrode activation process. At the beginning of the reaction, the activation of ions and the electrode active materials led to the enhancement of the electrochemical performances. As the charging and discharging process involves some irreversible redox reactions, the energy storage performance of the electrode decreased with the number of charging and discharging cycles. The performance of the supercapacitor was not changed obviously after about 1000 cycles. And 83.3% of the initial capacity with 98.4% of the coulombic efficiency could be retained after 2000 cycles, which proves the electrochemical stability of the NCMC-Sp.
Footnote |
† Electronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d2qm00126h |
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