Formation of C(sp2)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols

Guangwei Rong; Jincheng Mao; Defu Liu; Hong Yan; Yang Zheng; Jie Chen

doi:10.1039/C4RA15751F

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Formation of C(sp²)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols†

Guangwei Rong,^a Jincheng Mao,*^ab Defu Liu,^a Hong Yan,^a Yang Zheng^a and Jie Chen^a

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* Corresponding authors

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: jcmao@suda.edu.cn

^b State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, P. R. China

Abstract

Copper-catalyzed decarboxylative coupling between α-oxocarboxylic acids and diphenyl disulfides or thiophenols is presented, which provided an effective and direct approach for the preparation of useful thioesters through C(sp²)–S bond formation.

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Article information

DOI: https://doi.org/10.1039/C4RA15751F
Article type: Communication
Submitted: 03 pro 2014
Accepted: 10 bře 2015
First published: 10 bře 2015

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RSC Adv., 2015,5, 26461-26464

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Formation of C(sp²)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols

G. Rong, J. Mao, D. Liu, H. Yan, Y. Zheng and J. Chen, RSC Adv., 2015, 5, 26461 DOI: 10.1039/C4RA15751F

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