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Abstract | Cited by

A flexible organic sheet spontaneously assembled under mild conditions from a tri-carbamate. By introducing cyclohexyl side chains as ‘pillars’ between the sheets, a hydrogen bonded organic framework was formed which displayed a capacity for accommodating and releasing guest molecules. The guest size/shape selectivity of the lamellar framework was demonstrated by testing with various guests.

Graphical abstract: A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate

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