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DOI: 10.1039/A801262H (Paper) Reference Section for: Chem. Commun., 1998, 991-992

Arylsulfurdiimides: a new class of sulfur–nitrogen anion

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Andrey V. Zibarev, Andrey V. Zibarev, Enno Lork and Rüdiger Mews

Abstract

N-Aryl-N′-trimethylsulfurdiimides (aryl = 2,6-F2C6H3, 2-FC6H4) react with TASF to give quantitatively the corresponding TAS salts with the ArNSN– anions (2a, 2b), isoelectronic with arylthionylimides 3; because of the short terminal SN bond the anions should be regarded as thiazylamide rather than sulfurdiimide anions.

References

  1. D. Hänssgen and B. Ross, Z. Anorg. Allg. Chem., 1981, 473, 80 CrossRef.
  2. M. Herberhold, W. Ehrenreich, W. Bühlmeyer and K. Guldner, Chem. Ber., 1986, 119, 1424 CAS.
  3. H. W. Roesky, W. Schmieder and W. S. Sheldrick, Chem. Commun., 1981, 1013 RSC; H. W. Roesky, W. Schmieder, W. Isenberg, W. S. Sheldrick and G. M. Sheldrick, Chem. Ber., 1982, 115, 2714 CAS.
  4. D. Hänssgen and R. Steffens, J. Organomet. Chem., 1982, 236, 53 CrossRef.
  5. M. Herberhold and W. Ehrenreich, Angew. Chem., Int. Ed. Engl., 1986, 21, 633 CrossRef.
  6. Gmelin Handbook of Inorganic and Organometallic Chemistry, Sulfur Nitrogen Compounds, Part 7, Springer, Berlin, 1991, p. 10 ff Search PubMed.
  7. M. Herberhold, W. Jellen, W. Bühlmeyer, W. Ehrenreich and J. Reiner, Z. Naturforsch., Teil B, 1985, 40, 1229 Search PubMed.
  8. M. Herberhold, F. Neumann, G. Süss-Fink and U. Thewalt, Inorg. Chem., 1987, 26, 3612 CrossRef CAS.
  9. N. P. C. Walker, M. B. Hursthouse, C. P. Warrens and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1985, 227 RSC.
  10. R. Jones, D. J. Williams, P. T. Wood and J. D. Woollins, Polyhedron, 1989, 8, 91 CrossRef CAS.
  11. A. V. Zibarev and A. O. Miller, J. Fluorine Chem., 1990, 50, 359 CrossRef CAS.
  12. I. Yu. Bagryanskaya, Yu. V. Gatilov, A. O. Miller, M. M. Shakirov and A. V. Zibarev, Heteroatom Chem., 1994, 5, 561 CrossRef CAS.
  13. W. J. Middleton, Org. Synth., 1985, 64, 221.
  14. R. L. Cook and W. H. Kirchhoff, J. Chem. Phys., 1967, 47, 4521 CrossRef CAS.
  15. T. Beppo, E. Hirota and Y. Morino, J. Mol. Spectrosc., 1970, 36, 386 CrossRef; W. C. Emken and K. Hedberg, J. Chem. Phys., 1973, 58, 2195 CrossRef CAS.
  16. G. Hartmann, R. Mews, G. M. Sheldrick, R. Anderskewitz, M. Niemeyer and H. J. Emeleus, J. Fluorine Chem., 1986, 34, 46 CrossRef CAS.
  17. A. V. Zibarev and R. Mews, unpublished work.
  18. Structure solution and graphics, Siemens SHELXTL-Plus: G. M. Sheldrick, Release 4.0 for Siemens R3 Crystallographic Research Systems, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1989; Structure refinement, SHELXL-93, G. M. Sheldrick, University of Göttingen.
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