DOI: 10.1039/A800930I
(Paper)
Reference Section for: Chem. Commun., 1998, 989-990
Manganese(IV) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde
(Note: The full text of this document is currently only available in the PDF Version )
Rafael Ruiz, Ally Aukauloo, Yves Journaux, Rafael Ruiz, Ally Aukauloo, Isabel Fernández, José R. Pedro, Antonio L. Roselló, Beatriz Cervera, Isabel Castro and M. Carmen Muñoz
Abstract
A new manganese(IV) oxamato complex possessing a bis(µ-oxo)dimanganese core has been synthesized, magnetically and structurally characterized, and found to catalyze the aerobic oxidation of secondary alcohols to ketones with co-oxidation of pivalaldehyde to pivalic acid with good yields and high selectivities.
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