An intramolecular H3O2 bridge as the resting form of an active metal-bound hydroxide in a dinuclear zinc(II) complex
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Franc Meyer and Peter Rutsch
Abstract
An intramolecular Zn–O2H3–Zn bridge as a complexed form of metal-bound hydroxide exhibits enhanced reactivity compared to the related Zn–OH–Zn unit, illustrated by the reaction with CO2.
References
N. Sträter, W. N. Lipscomb, T. Klabunde and B. Krebs, Angew. Chem., Int. Ed. Engl., 1996, 35, 2024 CrossRef.
(a) E. E. Kim and H. W. Wyckoff, J. Mol. Biol., 1991, 218, 449 CrossRefCAS;
(b) A. Volbeda, A. Lahm, F. Sakiyama and D. Suck, EMBO J., 1991, 10, 1607 CAS;
(c) E. Hough, L. K. Hansen, B. Birknes, K. Jynge, S. Hansen, A. Hordvik, C. Little, E. Dodson and Z. Derewenda, Nature, 1989, 338, 357 CrossRefCAS.
R. Alsfasser, S. Trofimenko, A. Looney, G. Parkin and H. Vahrenkamp, Inorg. Chem., 1991, 30, 4098 CrossRefCAS; S. Uhlenbrock and B. Krebs, Angew. Chem., Int. Ed. Engl., 1992, 31, 1647 CrossRef; M. Ruf, K. Weis and H. Vahrenkamp, J. Chem. Soc., Chem. Commun., 1994, 135 RSC.
C. Flassbeck, K. Wieghardt, E. Bill, C. Butzlaff, A. X. Trautwein, B. Nuber and J. Weiss, Inorg. Chem., 1992, 31, 21 CrossRefCAS; P. Chaudhuri, C. Stockheim, K. Wieghardt, W. Deck, R. Gregorzik, H. Vahrenkamp, B. Nuber and J. Weiss, Inorg. Chem., 1992, 31, 1451 CrossRefCAS; R. Alsfasser and H. Vahrenkamp, Chem. Ber., 1993, 126, 695 CAS; C. Bazzicalupi, A. Bencini, A. Bianchi, V. Fusi, L. Mazzanti, P. Paoletti and B. Valtancoli, Inorg. Chem., 1995, 34, 3003 CrossRefCAS.
H. Adams, N. A. Bailey, D. E. Fenton and Q.-Y. He, J. Chem. Soc., Dalton Trans., 1995, 697 RSC; W. H. Chapman, Jr. and R. Breslow, J. Am. Chem. Soc., 1995, 117, 5462 CrossRef; M. Yashiro, A. Ishikubo and M. Komiyama, J. Chem. Soc., Chem. Commun., 1995, 1793 RSC; C. Wendelsdorf, S. Warzeska, E. Kövári and R. Krämer, J. Chem. Soc., Dalton Trans., 1996, 3087 RSC; T. Koike, M. Inoue, E. Kimura and M. Shiro, J. Am. Chem. Soc., 1996, 118, 3091 CrossRefCAS; M. Yashiro, A. Ishikubo and M. Komiyama, Chem. Commun., 1997, 83 RSC.
M. Ruf, K. Weis and H. Vahrenkamp, J. Am. Chem. Soc., 1996, 118, 9288 CrossRefCAS.
M. Itoh, K. Motoda, K. Shindo, T. Kamiusuki, H. Sakiyama, N. Matsumoto and H. Okawa, J. Chem. Soc., Dalton Trans., 1995, 3635 RSC.
F. Meyer, S. Beyreuther, K. Heinze and L. Zsolnai, Chem. Ber./Recueil, 1997, 130, 605 CrossRefCAS; F. Meyer, A. Jacobi, B. Nuber, P. Rutsch and L. Zsolnai, Inorg. Chem., 1998, 37, 1213 CrossRefCAS.
F. Meyer, K. Heinze, B. Nuber and L. Zsolnai, J. Chem. Soc., Dalton Trans., 1998, 207 RSC.
M. Ardon and A. Bino, Structure Bonding (Berlin), 1987, 65, 1 CAS.
G. M. Sheldrick,
SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen,
1997; G. M. Sheldrick,
SHELXS-97, Program for Crystal Structure Solution, Universität Göttingen,
1997.
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