An intramolecular H3O2 bridge as the resting form of an active metal-bound hydroxide in a dinuclear zinc(II) complex

(Note: The full text of this document is currently only available in the PDF Version )

Franc Meyer and Peter Rutsch


Abstract

An intramolecular Zn–O2H3–Zn bridge as a complexed form of metal-bound hydroxide exhibits enhanced reactivity compared to the related Zn–OH–Zn unit, illustrated by the reaction with CO2.


References

  1. N. Sträter, W. N. Lipscomb, T. Klabunde and B. Krebs, Angew. Chem., Int. Ed. Engl., 1996, 35, 2024 CrossRef.
  2. (a) E. E. Kim and H. W. Wyckoff, J. Mol. Biol., 1991, 218, 449 CrossRef CAS; (b) A. Volbeda, A. Lahm, F. Sakiyama and D. Suck, EMBO J., 1991, 10, 1607 CAS; (c) E. Hough, L. K. Hansen, B. Birknes, K. Jynge, S. Hansen, A. Hordvik, C. Little, E. Dodson and Z. Derewenda, Nature, 1989, 338, 357 CrossRef CAS.
  3. R. Alsfasser, S. Trofimenko, A. Looney, G. Parkin and H. Vahrenkamp, Inorg. Chem., 1991, 30, 4098 CrossRef CAS; S. Uhlenbrock and B. Krebs, Angew. Chem., Int. Ed. Engl., 1992, 31, 1647 CrossRef; M. Ruf, K. Weis and H. Vahrenkamp, J. Chem. Soc., Chem. Commun., 1994, 135 RSC.
  4. C. Flassbeck, K. Wieghardt, E. Bill, C. Butzlaff, A. X. Trautwein, B. Nuber and J. Weiss, Inorg. Chem., 1992, 31, 21 CrossRef CAS; P. Chaudhuri, C. Stockheim, K. Wieghardt, W. Deck, R. Gregorzik, H. Vahrenkamp, B. Nuber and J. Weiss, Inorg. Chem., 1992, 31, 1451 CrossRef CAS; R. Alsfasser and H. Vahrenkamp, Chem. Ber., 1993, 126, 695 CAS; C. Bazzicalupi, A. Bencini, A. Bianchi, V. Fusi, L. Mazzanti, P. Paoletti and B. Valtancoli, Inorg. Chem., 1995, 34, 3003 CrossRef CAS.
  5. H. Adams, N. A. Bailey, D. E. Fenton and Q.-Y. He, J. Chem. Soc., Dalton Trans., 1995, 697 RSC; W. H. Chapman, Jr. and R. Breslow, J. Am. Chem. Soc., 1995, 117, 5462 CrossRef; M. Yashiro, A. Ishikubo and M. Komiyama, J. Chem. Soc., Chem. Commun., 1995, 1793 RSC; C. Wendelsdorf, S. Warzeska, E. Kövári and R. Krämer, J. Chem. Soc., Dalton Trans., 1996, 3087 RSC; T. Koike, M. Inoue, E. Kimura and M. Shiro, J. Am. Chem. Soc., 1996, 118, 3091 CrossRef CAS; M. Yashiro, A. Ishikubo and M. Komiyama, Chem. Commun., 1997, 83 RSC.
  6. M. Ruf, K. Weis and H. Vahrenkamp, J. Am. Chem. Soc., 1996, 118, 9288 CrossRef CAS.
  7. M. Itoh, K. Motoda, K. Shindo, T. Kamiusuki, H. Sakiyama, N. Matsumoto and H. Okawa, J. Chem. Soc., Dalton Trans., 1995, 3635 RSC.
  8. F. Meyer, S. Beyreuther, K. Heinze and L. Zsolnai, Chem. Ber./Recueil, 1997, 130, 605 CrossRef CAS; F. Meyer, A. Jacobi, B. Nuber, P. Rutsch and L. Zsolnai, Inorg. Chem., 1998, 37, 1213 CrossRef CAS.
  9. F. Meyer, K. Heinze, B. Nuber and L. Zsolnai, J. Chem. Soc., Dalton Trans., 1998, 207 RSC.
  10. M. Ardon and A. Bino, Structure Bonding (Berlin), 1987, 65, 1 CAS.
  11. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, 1997; G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, Universität Göttingen, 1997.
Click here to see how this site uses Cookies. View our privacy policy here.