Alkali metal cation cooperative iodide anion recognition by new heteroditopic bis(calix[4]arene) rhenium(I) bipyridyl receptor molecules
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Paul D. Beer and James B. Cooper
Abstract
New heteroditopic bis(calix[4]arene) rhenium(I) bipyridyl receptors are synthesised and shown to simultaneously bind alkali metal cations and iodide anion with positive cooperativity.
M. T. Reetz, C. M. Niemeyer and K. Harris, Angew. Chem., Int. Ed. Engl., 1991, 30, 1472 CrossRef.
D. M. Rudkevich, Z. Brzozka, M. Palys, H. C. Visser, W. Verboom and D. N. Reinhoudt, Angew. Chem., Int. Ed. Engl., 1994, 33, 467 CrossRef.
K. I. Kinnear, D. P. Mousley, E. Arafar and J. C. Lockhart, J. Chem. Soc., Dalton Trans., 1994, 3637 RSC.
P. D. Beer, M. G. B. Drew, R. J. Knubley and M. I. Ogden, J. Chem. Soc., Dalton Trans., 1995, 3117 RSC.
J. Scheerder, J. P. M. van Duynhoven, J. F. J. Engbersen and D. N. Reinhoudt, Angew. Chem., Int. Ed. Engl., 1996, 35, 1090 CrossRef.
P. D. Beer, Chem. Commun., 1996, 689 RSC and references therein.
F. Arnaud-Neu, E. M. Collins, M. Deasy, G. Ferguson, S. J. Harris, B. Kaitner, A. J. Lough, M. A. McKervey, E. Marques, B. L. Ruhl, M. J. Schwing-Weill and E. M. Seward, J. Am. Chem. Soc., 1989, 111, 8681 CrossRefCAS.
C. P. Whittle, J. Heterocycl. Chem., 1977, 14, 191 CAS.
M. J. Hynes, J. Chem. Soc., Dalton Trans., 1993, 311 RSC.
In ref. 6, lower rim complexation of alkali metal cations is essential for
upper rim halide anion complexation.
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