Synthesis of spherical particulate polysiloxane resins as catalyst supports

Abstract

Spherical particulate polysiloxanes are synthesised for the first time, chemically derivatised and employed as a support in molybdenum(VI) catalysed alkene epoxidation.

References

1. Syntheses and Separations Using Functional Polymers, ed. D. C. Sherrington and P. Hodge, Wiley, Chichester, UK, 1988.
2. Combinatorial Peptide and Non-peptide Libraries, ed. G. Jung, VCH, Weinheim, Germany, 1996.
3. F. R. Hartley, Supported Metal Complexes, Reidel, Dordrecht, Germany, 1985.
4. D. Pini, A. Petri, A. Mastantuono and P. Salvadori, in Chiral Reactions in Heterogeneous Catalysis, ed. G. Jannes and V. Dubois, Plenum, New York, 1995, p. 155.
5. T. Brock and D. C. Sherrington, Polymer, 1992, 33, 1773.
6. M. M. Miller and D. C. Sherrington, J. Chem. Soc., Perkin Trans. 2, 1994, 2091.
7. T. Brock, D. C. Sherrington and J. Swindell, J. Mater. Chem., 1994, 4, 229.
8. J. H. Ahn and D. C. Sherrington, Chem. Commun., 1996, 643.
9. E. N. Eijke, R. V. Parish and A. Jideonwo, J. Appl. Polym. Sci., 1989, 38, 171.
10. E. Lindner, R. Schreiber, T. Schneller, P. Wegner and H. A. Mayer, Inorg. Chem., 1996, 35, 514.
11. K. Soga, T. Arai, B. T. Hoang and T. Uozumi, Macromol. Rapid Commun., 1995, 16, 905.
12. I. F. J. Vankelecom, D. Tas, R. F. Parton, V. Vande Vyver and P. A. Jacobs, Angew. Chem., Int. Ed. Engl., 1996, 35, 1346.
13. Dr. B. J. Brisdon, Department of Chemistry, University of Bath, UK, personal communication.
14. Z. C. Brezezinska, W. R. Cullen and G. Strukul, Can. J. Chem., 1980, 58, 750.
15. G. Yacoub-George, E. Bratz and H. Tiltscher, J. Non-Cryst. Solids, 1994, 167, 9.
16. M. Miller and D. C. Sherrington, J. Catal., 1995, 152, 377.