Synthesis of a phosphomolybdate with a tetranuclear vanadium core by installing vanadium atoms in a lacunary template using the protecting group strategy

Chifeng Li, Kazuya Yamaguchi and Kosuke Suzuki

Chem. Commun., 2021, 57, 7882
DOI: 10.1039/D1CC03099J

Molecular hybrids of trivacant lacunary polyoxomolybdate and multidentate organic ligands

Atsuhiro Jimbo, Chifeng Li, Kentaro Yonesato, Tomoki Ushiyama, Kazuya Yamaguchi and Kosuke Suzuki

Chem. Sci., 2023, 14, 10280
DOI: 10.1039/D3SC03713D

An inorganic Co-containing heteropolyoxoniobate: reversible chemochromism and H2O-dependent proton conductivity properties

Nian Shi, Yong-Jiang Wang, Xin-Xiong Li, Yan-Qiong Sun and Shou-Tian Zheng

Inorg. Chem. Front., 2021, 8, 5225
DOI: 10.1039/D1QI01065D

Ligand-directed top-down synthesis of trivacant lacunary polyoxomolybdates from plenary Keggin-type [α-XMo12O40]3− (X = P, As, V) in organic media

Atsuhiro Jimbo, Chifeng Li, Kentaro Yonesato, Kazuya Yamaguchi and Kosuke Suzuki

Dalton Trans., 2025, 54, 8234
DOI: 10.1039/D5DT00252D

Study on the incorporation of various elements into the Keggin lacunary-type phosphomolybdate [PMo9O34]9− and subsequent purification of the polyoxometalates by nanofiltration

Jan-Christian Raabe, Tobias Esser, Froze Jameel, Matthias Stein, Jakob Albert and Maximilian J. Poller

Inorg. Chem. Front., 2023, 10, 4854
DOI: 10.1039/D3QI00937H

A photo-switchable molecular capsule: sequential photoinduced processes

Manjiri Choudhari, Jingjing Xu, Alasdair I. McKay, Clément Guerrin, Craig Forsyth, Howard Z. Ma, Lars Goerigk, Richard A. J. O'Hair, Antoine Bonnefont, Laurent Ruhlmann, Stephane Aloise and Chris Ritchie

Chem. Sci., 2022, 13, 13732
DOI: 10.1039/D2SC04613J

Variable control of the electronic states of a silver nanocluster via protonation/deprotonation of polyoxometalate ligands

Kentaro Yonesato, Seiji Yamazoe, Soichi Kikkawa, Daisuke Yokogawa, Kazuya Yamaguchi and Kosuke Suzuki

Chem. Sci., 2022, 13, 5557
DOI: 10.1039/D2SC01156E

Synthesis of a Keggin-type polyoxoselenidotungstate via site-selective oxygen-to-selenium substitution

Kentaro Yonesato, Yota Watanabe, Magda Pascual-Borràs, R. John Errington, Kazuya Yamaguchi and Kosuke Suzuki

Chem. Sci., 2025, 16, 13183
DOI: 10.1039/D5SC03340C

Pd-incorporated polyoxometalate catalysts for electrochemical CO2 reduction

Kimitake Kawakami, Tomohiro Yabe, Fumiaki Amano, Kazuya Yamaguchi and Kosuke Suzuki

Chem. Sci., 2024, 15, 14829
DOI: 10.1039/D4SC04304A

Mixed addenda polyoxometalates by cooperative self-assembly and modulation of their optoelectronic properties

Ganga Singh, Ruchika Choudhary and Debaprasad Mandal

Inorg. Chem. Front., 2025
DOI: 10.1039/D5QI00961H

Isolation, Architecture of Ag8-Cluster Modified Polyoxometalate for Water Reduction into Hydrogen Driven by Visible Light

Ling-Tong Xu, Yan Zhao, Pin-Fang Yan, Hua Mei and Yan Xu

Inorg. Chem., 2025, 64, 11618
DOI: 10.1021/acs.inorgchem.5c01055

Two new inorganic-organic hybrid polyoxotantalates with proton conduction property

Yi-Lun Wang, Yan-Lan Wu, Qing-Xin Zeng, Xin-Xiong Li and Shou-Tian Zheng

Journal of Solid State Chemistry, 2023, 322, 123943
DOI: 10.1016/j.jssc.2023.123943

Roles of Organic Fragments in Redirecting Crystal/Molecular Structures of Inorganic–Organic Hybrids Based on Lacunary Keggin-Type Polyoxometalates

Ruhollah Khajavian, Vida Jodaian, Fatemeh Taghipour, Joel T. Mague and Masoud Mirzaei

Molecules, 2021, 26, 5994
DOI: 10.3390/molecules26195994

Structural overview and evolution paths of lacunary polyoxometalates

Lu-Lu Liu, Lan Wang, Xin-Yu Xiao, Peng Yang, Junwei Zhao and Ulrich Kortz

Coordination Chemistry Reviews, 2024, 506, 215687
DOI: 10.1016/j.ccr.2024.215687

Reusable and Highly Active Copper-Based Lacunary-type Polyoxometalate (LPMo-Cu) as an Effective Catalyst for Nitroarene Reduction in Aqueous Solution

Shima Aghajani, Maryam Mohammadikish and Maryam Khalaji-Verjani

Langmuir, 2023, 39, 8484
DOI: 10.1021/acs.langmuir.3c00766

“Template synthesis” of discrete metal clusters with two- or three-dimensional architectures

Yusuke Sunada, Kazuya Yamaguchi and Kosuke Suzuki

Coordination Chemistry Reviews, 2022, 469, 214673
DOI: 10.1016/j.ccr.2022.214673

Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

Zhihui Ni, Hongjin Lv and Guoyu Yang

Molecules, 2022, 27, 8799
DOI: 10.3390/molecules27248799

Creation of Highly Dispersed Supported Polyoxometalate Cesium Salts via Cation Exchange from Alkylammonium Salts on Supports

Takaaki Suzuki, Tomohiro Yabe, Keiju Wachi, Kentaro Yonesato, Kosuke Suzuki and Kazuya Yamaguchi

ChemNanoMat, 2023, 9
DOI: 10.1002/cnma.202200428

Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides

Stefan Repp, Moritz Remmers, Alexandra Stefanie Jessica Rein, Dieter Sorsche, Dandan Gao, Montaha Anjass, Mihail Mondeshki, Luca M. Carrella, Eva Rentschler and Carsten Streb

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-41257-y

Recent Advances in Polyoxometalate‒Metal Nanocluster Hybrids

Kentaro Yonesato, Daiki Yanai, Kazuya Yamaguchi and Kosuke Suzuki

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202500877

Gold Nanoparticles Capped with a Novel Titanium(IV)‐Containing Polyoxomolybdate Cluster: Selective and Enhanced Bactericidal Effect Against Escherichia coli

Mónica Paesa, Fernando Almazán, Cristina Yus, Víctor Sebastián, Manuel Arruebo, Luis M. Gandía, Santiago Reinoso, Ismael Pellejero and Gracia Mendoza

Small, 2024, 20
DOI: 10.1002/smll.202305169

Pyridine-functionalized chiral polyoxometalates via in situ degradation

Yu Xia, Tao Zhang, Luyu Tian, Yadian Xie, Xin Zhuo, Zhi-Qiang Shi, Hailiang Hu and Gang Li

Journal of Molecular Structure, 2025, 1338, 142292
DOI: 10.1016/j.molstruc.2025.142292

Precise Design of Polyoxometalates and their Application to Photocatalyst

Kosuke Suzuki and Kazuya Yamaguchi

J. Synth. Org. Chem. Jpn., 2022, 80, 149
DOI: 10.5059/yukigoseikyokaishi.80.149

Development of Environmentally Friendly Dehydrogenative Oxidation Reactions Using Multifunctional Heterogeneous Catalysts

Kazuya Yamaguchi, Xiongjie Jin, Takafumi Yatabe and Kosuke Suzuki

Bulletin of the Chemical Society of Japan, 2022, 95, 1332
DOI: 10.1246/bcsj.20220181

A Molecular Hybrid of an Atomically Precise Silver Nanocluster and Polyoxometalates for H2 Cleavage into Protons and Electrons

Kentaro Yonesato, Seiji Yamazoe, Daisuke Yokogawa, Kazuya Yamaguchi and Kosuke Suzuki

Angewandte Chemie, 2021, 133, 17131
DOI: 10.1002/ange.202106786

Ligand-Protecting Strategy for the Controlled Construction of Multinuclear Copper Cores within a Ring-Shaped Polyoxometalate

Yoshihiro Koizumi, Kentaro Yonesato, Kazuya Yamaguchi and Kosuke Suzuki

Inorg. Chem., 2022, 61, 9841
DOI: 10.1021/acs.inorgchem.2c01029

Nanostructured Manganese Oxides within a Ring‐Shaped Polyoxometalate Exhibiting Unusual Oxidation Catalysis

Kai Sato, Kentaro Yonesato, Takafumi Yatabe, Kazuya Yamaguchi and Kosuke Suzuki

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202104051

Imidazole-Dependent Assembly of Copper Polymolybdate Frameworks for One-Pot Sulfide Oxidation and C–H Activation

Xianqiang Huang, Yanan Cui, Gang Liu, Haitao Wang, Junyu Ren, Yalin Zhang, Guodong Shen, Lingling Lv, Huai-Wei Wang and Yi-Fa Chen

Energy Fuels, 2022, 36, 1665
DOI: 10.1021/acs.energyfuels.1c03886

Interplay between protonation and Jahn–Teller effects in a manganese vanadium cubane water oxidation catalyst

Simon Tippner, Patrick Lechner, Leticia González and Sebastian Mai

The Journal of Chemical Physics, 2024, 160
DOI: 10.1063/5.0189673

Ligand‐Directed Approach in Polyoxometalate Synthesis: Formation of a New Divacant Lacunary Polyoxomolybdate [γ‐PMo10O36]7−

Chifeng Li, Kazuya Yamaguchi and Kosuke Suzuki

Angewandte Chemie, 2021, 133, 7036
DOI: 10.1002/ange.202016642

Modulation of the Band Gap and Redox Properties by Mixed Addenda in Sandwich Polyoxometalates

Ganga Singh and Debaprasad Mandal

Inorg. Chem., 2023, 62, 19648
DOI: 10.1021/acs.inorgchem.3c03020

A Molecular Hybrid of an Atomically Precise Silver Nanocluster and Polyoxometalates for H2 Cleavage into Protons and Electrons

Kentaro Yonesato, Seiji Yamazoe, Daisuke Yokogawa, Kazuya Yamaguchi and Kosuke Suzuki

Angew Chem Int Ed, 2021, 60, 16994
DOI: 10.1002/anie.202106786

Aminobenzoic Acid Covalently Modified Polyoxotungstates Based on {XW6} Clusters with Proton Conductivity Property

Yunfan Zhang, Yizhen Song, Lihua Liu, Chenyang Song, Peipei Tian, Miao Zhang, Bingxue Niu, Zong-Jie Guan, Lin Sun and Pengtao Ma

Inorg. Chem., 2025, 64, 1488
DOI: 10.1021/acs.inorgchem.4c04719

Polyoxometalate-based all-inorganic open frameworks

Xi-Kai Lian, Huai-Bin Chen, Yu-Diao Lin, Xin-Xiong Li and Shou-Tian Zheng

Coordination Chemistry Reviews, 2023, 497, 215440
DOI: 10.1016/j.ccr.2023.215440

Ligand-directed bottom-up synthesis of trivacant lacunary polyoxomolybdates in organic media

Atsuhiro Jimbo, Chifeng Li, Kentaro Yonesato, Kazuya Yamaguchi and Kosuke Suzuki

Chemistry Letters, 2025, 54
DOI: 10.1093/chemle/upaf072

Ligand‐Directed Approach in Polyoxometalate Synthesis: Formation of a New Divacant Lacunary Polyoxomolybdate [γ‐PMo10O36]7−

Chifeng Li, Kazuya Yamaguchi and Kosuke Suzuki

Angew Chem Int Ed, 2021, 60, 6960
DOI: 10.1002/anie.202016642