Meghan Betourney, Hannah Ashton, Gabrielle Costello, Jordan Hunter, Sang H. Park, Benjamin Shepler, Joseph C. Sloop, Matthew Stancea and Karla Wilmott

Journal of Fluorine Chemistry, 2025, 285-286, 110455
DOI: 10.1016/j.jfluchem.2025.110455

Chiral Bis‐phosphate Macrocycles for Catalytic, Efficient, and Enantioselective Electrophilic Fluorination

Lie‐Wei Zhang, Xu‐Dong Wang, Yu‐Fei Ao, De‐Xian Wang and Qi‐Qiang Wang

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400498

Synthetic Advantages of Defluorinative C−F Bond Functionalization

Leidy V. Hooker and Jeffrey S. Bandar

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202308880

Strategies for the Synthesis of Fluorinated Nucleosides, Nucleotides and Oligonucleotides

Harshita Shet, Rajesh Sahu, Yogesh S. Sanghvi and Anant R. Kapdi

The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202200066

Three-component aminofluorination of alkenes with electronically rich amino sources

Yang Li, Jiamin Bao, Yu Zhang, Xue Peng, Weijie Yu, Tao Wang, Dengtao Yang, Qun Liu, Qian Zhang and Junkai Fu

Chem, 2022, 8, 1147
DOI: 10.1016/j.chempr.2022.02.014

Synthesis of Diastereomeric 8‐Fluoro‐ABC‐Steroid Building Blocks

Michael Essers and Günter Haufe

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300206

Ligandless Iron‐Catalyzed C(sp3)─H Bond Fluorination

A. Dina Dilinaer, Alexis Mateo and Marcus W. Drover

ChemCatChem, 2026, 18
DOI: 10.1002/cctc.202501660

Organocatalytic Halogenation of Aromatic and Heteroaromatic Compounds

Paola Acosta‐Guzmán, Alexander Garay‐Talero and Diego Gamba‐Sánchez

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500125

Development of N-F fluorinating agents and their fluorinations: Historical perspective

Teruo Umemoto, Yuhao Yang and Gerald B Hammond

Beilstein J. Org. Chem., 2021, 17, 1752
DOI: 10.3762/bjoc.17.123

Fluorination of heterocyclic compounds accompanied by molecular rearrangements

Gennady I. Borodkin

Chem Heterocycl Comp, 2024, 60, 323
DOI: 10.1007/s10593-024-03340-0

Recent Developments of Monofluorination via Three-Component Reactions

Fumin Shen, Jingjing Yao, Siying Xu, Ran Xia and Zhan-Yong Wang

Synthesis, 2025, 57, 2753
DOI: 10.1055/a-2616-5364

Late‐Stage Fluorination of Tyrosine Residues in Antiviral Protein Cyanovirin‐N

Lívia C. R. M. da Frota, Ariana A. Vasconcelos, Fábio C. L. Almeida and Fernanda G. Finelli

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400850

Ring‐Opening Fluorination of Carbo/Heterocycles and Aromatics: Construction of Complex and Diverse Fluorine‐Containing Molecules

Masaaki Komatsuda and Junichiro Yamaguchi

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202200281

Synthetic Advantages of Defluorinative C−F Bond Functionalization

Leidy V. Hooker and Jeffrey S. Bandar

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202308880

Electrophilic and Oxidative Fluorination of Heterocyclic Compounds in Aqueous Medium

G. I. Borodkin

Russ J Org Chem, 2026, 62
DOI: 10.1134/S1070428025604418

Multicomponent Synthesis of β-Boryl Ketones Triggered by Ketene-Induced Metallate Rearrangement of Alkenylboronic Esters

Haruki Mizoguchi, Atsuro Tanakura, Honoka Kokado, Yoko Misaki, Masaki Bando, Yuya Kobashi and Akira Sakakura

Org. Lett., 2026
DOI: 10.1021/acs.orglett.6c00987

Asymmetric Bio- and Organocatalysis: Historical Aspects and Concepts

Pierre Vogel

Catalysts, 2026, 16, 131
DOI: 10.3390/catal16020131

Synthesis of gem‐Difluorinated Keto‐Sulfoxides from Sulfoxonium Ylides

Marcio Hayashi and Antonio C. B. Burtoloso

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400108

Copper‐Catalyzed Stereoselective Direct Olefinic β‐C(sp2)−H Imidation of Acyclic Enamides with NFSI

Guisheng Chen, Xiaolan Li, Jie Liu, Haidong Liu and Haiqing Luo

Chin. J. Chem., 2025, 43, 2347
DOI: 10.1002/cjoc.70118

Ring-Opening Fluorination of Isoxazoles

Masaaki Komatsuda, Hugo Ohki, Hiroki Kondo, Ayane Suto and Junichiro Yamaguchi

Org. Lett., 2022, 24, 3270
DOI: 10.1021/acs.orglett.2c01149

Oxidative Three-Component Selenofunctionalization of Alkenes: Convenient Access to Vicinally Functionalized Selenides

Yun-Qian Zhang, You-Qin Jiang, Yong-Hao Wang, Cong Qi, Yong Ling, Yanan Zhang and Gong-Qing Liu

J. Org. Chem., 2023, 88, 7431
DOI: 10.1021/acs.joc.3c00788

Regioselective Transfer Hydrogenative Defluorination of Polyfluoroarenes Catalyzed by Bifunctional Azairidacycle

Asuka Matsunami, Shigeki Kuwata and Yoshihito Kayaki

Organics, 2022, 3, 150
DOI: 10.3390/org3030012

Pyridinium-Masked Enol as a Precursor for Constructing Alpha-Fluoromethyl Ketones

Jijun Xu, Yi Li, Xuanyu Zhu, Shisong Lv, Yiming Xu, Tanyu Cheng, Guohua Liu and Rui Liu

Org. Lett., 2023, 25, 6211
DOI: 10.1021/acs.orglett.3c02419

Applications of Nucleophilic Fluorine Sources in the Selective Fluorofunctionalization of Unsaturated Carbon-Carbon Bonds

Cheng-Qiang Wang and Chao Feng

Acta Chimica Sinica, 2024, 82, 160
DOI: 10.6023/A23080373

An N-Fluorinated Imide for Practical Catalytic Imidations

Yuno Oe, Ryuhei Yoshida, Airi Tanaka, Akiya Adachi, Yuichiro Ishibashi, Takashi Okazoe, Kohsuke Aikawa and Takuya Hashimoto

J. Am. Chem. Soc., 2022, 144, 2107
DOI: 10.1021/jacs.1c13569

Electrophilic Fluorination of Imidazoheterocycles by Selectfluor

Feng Wu, Tong Liu, Wanpeng Liao, Zhixu Zhou and Hongyu Dai

Russ J Gen Chem, 2022, 92, 1333
DOI: 10.1134/S1070363222070234

Copper Nitrate Mediated Regioselective Difunctionalization of Alkenes with N-Fluorobenzenesulfonimide: A Direct Approach to β-Aminonitrates

Kaijing Zhou, Li Yin, Ying Guo, Chang-Hua Ding and Bin Xu

Synthesis, 2023, 55, 744
DOI: 10.1055/a-1942-7033

Electrochemical Fluorination Functionalization of gem-Difluoroalkenes with CsF as a Fluorine Source: Access to Fluoroalkyl Building Blocks

Linzi Wen, Ziyan Zou, Naifu Zhou, Chengbo Sun, Peixu Xie and Pengju Feng

Org. Lett., 2024, 26, 241
DOI: 10.1021/acs.orglett.3c03901

Electrochemically Direct Fluorination Functionalization of Styrenes with Different Fluorine Source: Access to Fluoroalkyl Derivatives

Boao Li, Xiaojian Liao, Linzi Wen, Mengyao Mi, Xiwen Xing, Pengju Feng and Shihai Xu

J. Org. Chem., 2024, 89, 9440
DOI: 10.1021/acs.joc.4c00722

Multi-faceted reactivity of N-fluorobenzenesulfonimide (NFSI) under mechanochemical conditions: fluorination, fluorodemethylation, sulfonylation, and amidation reactions

José G Hernández, Karen J Ardila-Fierro, Dajana Barišić and Hervé Geneste

Beilstein J. Org. Chem., 2022, 18, 182
DOI: 10.3762/bjoc.18.20

Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N‐Heterocyclic Olefins

Andreas Eitzinger, Justus Reitz, Patrick W. Antoni, Herbert Mayr, Armin R. Ofial and Max M. Hansmann

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202309790

Carbofluorination of π‐Bonds and Related Reactions Involving Tandem C−C/C−F Bond Formation

E. Ali McKnight, Dusty Cadwallader and Christine M. Le

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202300017

Fluorine-Based Oxidant Enables Room-Temperature Pd-Catalyzed C–H Arylation with Boronic Acids

Delphine S. Pichon-Barré, Nicholas R. McDonald and Erik A. Romero

J. Org. Chem., 2025, 90, 3989
DOI: 10.1021/acs.joc.4c03106

Strategies for Nucleophilic C(sp3)–(Radio)Fluorination

Isabelle Nathalie-Marie Leibler, Shivaani S. Gandhi, Makeda A. Tekle-Smith and Abigail G. Doyle

J. Am. Chem. Soc., 2023, 145, 9928
DOI: 10.1021/jacs.3c01824

Cobalt-Catalyzed Divergent Aminofluorination and Diamination of Styrenes with N-Fluorosulfonamides

Peng Guo, Jun-Fa Han, Guo-Cai Yuan, Lin Chen, Jia-Bin Liao and Ke-Yin Ye

Org. Lett., 2021, 23, 4067
DOI: 10.1021/acs.orglett.1c01308

Practical Synthesis of NFSI Derivatives through ArSO2NHF without F2

Yu‐Yang Zhang, Xiu‐Hua Xu and Feng‐Ling Qing

Chin. J. Chem., 2022, 40, 2956
DOI: 10.1002/cjoc.202200537

A Catalytic Three‐Component Aminofluorination of Unactivated Alkenes with Electron‐Rich Amino Sources

Junchao Dong, Yujie Liang, Yang Li, Wei Guan, Qian Zhang and Junkai Fu

Advanced Science, 2024, 11
DOI: 10.1002/advs.202305006

Recent Advances in Bioconjugation of Aromatic Amino Acid Residues by a Reactivity‐Guided Approach

Bruno M. da S. Santos, Lívia C. R. M. da Frota, Thais G. Silva and Fernanda G. Finelli

The Chemical Record, 2026, 26
DOI: 10.1002/tcr.202500215

Oxidations of Alcohols, Aldehydes, and Diols Using NaBr and Selectfluor

Harshit Joshi, Debobrata Paul and Shyam Sathyamoorthi

J. Org. Chem., 2023, 88, 11240
DOI: 10.1021/acs.joc.3c01307

Electrochemical Construction of C−F Bonds: Recent Advances and Future Perspectives

Boao Li, Muwu Xu, Pengju Feng and Shihai Xu

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400605

Recent Advancement on Selectfluor Mediated Synthesis of Heterocyclic Molecules

Sukanya Das, Risika Das, Tapas Ghosh and Raj Kumar Nandi

The Chemical Record, 2025, 25
DOI: 10.1002/tcr.202400216

Metal-Catalyzed Fluoroacetyl Carbene Transfer from Sulfonium Salts

Arturs Sperga, Artis Kinens and Janis Veliks

Org. Lett., 2025, 27, 5446
DOI: 10.1021/acs.orglett.5c01416

Advances in Continuous Flow Fluorination Reactions

Tsz Chun Lee, Yi Tong and Wai Chung Fu

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202300723

Diastereoselective Synthesis of Less Accessible Fluorine-Containing Acyclic Tetrasubstituted Stereocenters via Electrophilic Fluorination of β,β-Disubstituted Metalloenamines

Tao Liu, Nuermaimaiti Yisimayili, Li-Feng Chu and Chong-Dao Lu

J. Org. Chem., 2024, 89, 5726
DOI: 10.1021/acs.joc.4c00306

anti‐Markovnikov Iodofluorination of Alkenes

Bai‐Yu Qian, Wei Zhang, Jin‐Hong Lin, Weiguo Cao and Ji‐Chang Xiao

Chemistry An Asian Journal, 2022, 17
DOI: 10.1002/asia.202200184

Photocatalytic Decarboxylative Fluorination by Quinone-Based Isoreticular Covalent Organic Frameworks

Ayan Jati, Ashok Kumar Mahato, Durba Chanda, Pramod Kumar, Rahul Banerjee and Biplab Maji

J. Am. Chem. Soc., 2024, 146, 23923
DOI: 10.1021/jacs.4c06510

Elucidating Fluorine Steering Effects in Diels‐Alder Reactions Interfaced with Charge‐Enhanced Reactivity

Sabrina Hoford, Julius Jan, Jeffrey N. Johnston and Travis Dudding

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401203

Catalytic Fluorination of α-Branched Ketones with Nucleophilic Fluorine

Shengyu Zhong, Zhiyou Yu, Yuze Zhu and Lei Shi

Org. Lett., 2025, 27, 3452
DOI: 10.1021/acs.orglett.5c00972

Mesoionische N‐Heterocyclische Olefine verschieben die obere Grenze der Nucleophilie‐Skala

Andreas Eitzinger, Justus Reitz, Patrick W. Antoni, Herbert Mayr, Armin R. Ofial and Max M. Hansmann

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202309790

Copper-Catalyzed Three-Component Aminofluorination of Alkenes and 1,3-Dienes: Direct Entry to Diverse β-Fluoroalkylamines

Guangshou Feng, Colton K. Ku, Jiaqi Zhao and Qiu Wang

J. Am. Chem. Soc., 2022, 144, 20463
DOI: 10.1021/jacs.2c09118

Conversion of a AuI Fluorido Complex into an N‐Fluoroamido Derivative: N−F versus Au−N Reactivity

Simon G. Rachor, Mike Ahrens and Thomas Braun

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202212858