Current understanding and insights towards protein stabilization and activation in deep eutectic solvents as sustainable solvent media

Niketa Yadav and Pannuru Venkatesu

Phys. Chem. Chem. Phys., 2022, 24, 13474
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Nanolubrication in deep eutectic solvents

James E. Hallett, Hannah J. Hayler and Susan Perkin

Phys. Chem. Chem. Phys., 2020, 22, 20253
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Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials

Oliver S. Hammond and Anja-Verena Mudring

Chem. Commun., 2022, 58, 3865
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Water distribution at the electrified interface of deep eutectic solvents

Mesfin Haile Mamme, Samuel L. C. Moors, El Amine Mernissi Cherigui, Herman Terryn, Johan Deconinck, Jon Ustarroz and Frank De Proft

Nanoscale Adv., 2019, 1, 2847
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Mechanism of selective gold extraction from multi-metal chloride solutions by electrodeposition-redox replacement

Ivan Korolev, Stylianos Spathariotis, Kirsi Yliniemi, Benjamin P. Wilson, Andrew P. Abbott and Mari Lundström

Green Chem., 2020, 22, 3615
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Insights into the role of molar ratio and added water in the properties of choline chloride and urea-based eutectic mixtures and their cellulose swelling capacity

Juho Antti Sirviö, Riikka Haataja, Anu M. Kantola, Terhi Suopajärvi and Henrikki Liimatainen

Phys. Chem. Chem. Phys., 2022, 24, 28609
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Revealing the interfacial nanostructure of a deep eutectic solvent at a solid electrode

Nebojša Zec, Gaetano Mangiapia, Mikhail L. Zheludkevich, Sebastian Busch and Jean-François Moulin

Phys. Chem. Chem. Phys., 2020, 22, 12104
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Structural evolution of iron forming iron oxide in a deep eutectic-solvothermal reaction

Oliver S. Hammond, Ria S. Atri, Daniel T. Bowron, Liliana de Campo, Sofia Diaz-Moreno, Luke L. Keenan, James Doutch, Salvador Eslava and Karen J. Edler

Nanoscale, 2021, 13, 1723
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Intermolecular interactions in clusters of ethylammonium nitrate and 1-amino-1,2,3-triazole

Shinae Kim, Justin A. Conrad, Garrett M. Tow, Edward J. Maginn, Jerry A. Boatz and Mark S. Gordon

Phys. Chem. Chem. Phys., 2023, 25, 30428
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The role of hydrogen bond donor and water content on the electrochemical reduction of Ni2+ from solvents – an experimental and modelling study

Monika Lukaczynska-Anderson, Mesfin Haile Mamme, Andrea Ceglia, Krista Van den Bergh, Joost De Strycker, Frank De Proft, Herman Terryn and Jon Ustarroz

Phys. Chem. Chem. Phys., 2020, 22, 16125
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Catalytic dissolution of metals from printed circuit boards using a calcium chloride–based deep eutectic solvent

Rodolfo Marin Rivera, Guillaume Zante, Jennifer M. Hartley, Karl S. Ryder and Andrew P. Abbott

Green Chem., 2022, 24, 3023
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Effect of Viscosity of a Deep Eutectic Solvent on CO2 Capture Performance in an Energy-Efficient Membrane Contactor-Based Process

Zachary Coin, Shailesh Dangwal, Mary Hannah Irwin, Thomas Knight, Ramesh Bhave, Gernot Rother, Robert Sacci, Md. Arifuzzaman, Vera Bocharova, Ilia Ivanov, David S. Sholl and Syed Z. Islam

ACS Omega, 2025, 10, 3407
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Are There Magic Compositions in Deep Eutectic Solvents? Effects of Composition and Water Content in Choline Chloride/Ethylene Glycol from Ab Initio Molecular Dynamics

Vahideh Alizadeh, Friedrich Malberg, Agílio A. H. Pádua and Barbara Kirchner

J. Phys. Chem. B, 2020, 124, 7433
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Electrified interfaces of deep eutectic solvents

Renata Costa, Ana T.S.C. Brandão, Carlos M. Pereira and A. Fernando Silva

Electrochimica Acta, 2023, 461, 142653
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Zinc Electrode Cycling in Deep Eutectic Solvent Electrolytes: An Electrochemical Study

Elisa Emanuele, Andrea Li Bassi, Andrea Macrelli, Claudio Mele, Jacopo Strada and Benedetto Bozzini

Molecules, 2023, 28, 957
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Self-assembled nanostructure induced in deep eutectic solvents via an amphiphilic hydrogen bond donor

Joshua J. Buzolic, Hua Li, Zachary M. Aman, Gregory G. Warr and Rob Atkin

Journal of Colloid and Interface Science, 2022, 616, 121
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Microstructure of Deep Eutectic Solvents: Current Understanding and Challenges

Supreet Kaur, Monika Kumari and Hemant K. Kashyap

J. Phys. Chem. B, 2020, 124, 10601
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Experimental study on the effect of water addition to ChCl-MEA DES towards its performance in CO2 removal from syngas

Haryo Wibowo, Li Zhong, Qun Huan, Qing Hu, Dicka Ar Rahim and Mi Yan

Biomass Conv. Bioref., 2022, 12, 61
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Effect of water or ethanol on the excess properties of deep eutectic solvents (tetrabutylammonium bromide + formic acid/propionic acid)

Yingying Zuo, Xiguang Chen, Ning Wei and Jing Tong

Journal of Molecular Liquids, 2023, 383, 122034
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Nanostructure of Locally Concentrated Ionic Liquids in the Bulk and at Graphite and Gold Electrodes

Jianan Wang, Joshua J. Buzolic, Jesse W. Mullen, Paul A. Fitzgerald, Zachary M. Aman, Maria Forsyth, Hua Li, Debbie S. Silvester, Gregory G. Warr and Rob Atkin

ACS Nano, 2023, 17, 21567
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Alginate hydrogel incorporating cellulose nanofiber from solid waste agar industry for hydrophobic antibiotic delivery: Synthesis and characterization

Budiono Ujaya Putra, Safrina Dyah Hardiningtyas, Novitri Hastuti, Wahyu Ramadhan, Uju, Muhamad Alif Razi and Luciasih Agustini

Materials Today Communications, 2024, 38, 108248
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Influence of cations size and charge on Zn electrodeposition from deep eutectic solvents

Andrea Volpe, Chiara Pelosi, Gianluca Ciancaleoni, Luca Bernazzani, Andrew P. Abbott and Jake M. Yang

Electrochimica Acta, 2026, 548, 148002
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A Comparative Study of Choline Chloride Deep Eutectic Electrolytes: Towards Sustainable Supercapacitors

Raquel San Emeterio, Antía Santiago-Alonso, Juan José Parajó, Ana T. S. C. Brandão, Carlos M. Pereira, Carlos Gracia, Pablo Vallet, Renata Costa and Josefa Salgado

Molecules, 2026, 31, 929
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Influence of Hydration on the Structure of Reline Deep Eutectic Solvent: A Molecular Dynamics Study

Pratibha Kumari, Shobhna, Supreet Kaur and Hemant K. Kashyap

ACS Omega, 2018, 3, 15246
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The Role of Water Content of Deep Eutectic Solvent Ethaline in the Anodic Process of Gold Electrode

Jie-Du Wu, Yu Ding, Feng Zhu, Yu Gu, Wei-Wei Wang, Lan Sun, Bing-Wei Mao and Jia-Wei Yan

Molecules, 2023, 28, 2300
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How Hydration Affects the Microscopic Structural Morphology in a Deep Eutectic Solvent

Supreet Kaur, Aditya Gupta and Hemant K. Kashyap

J. Phys. Chem. B, 2020, 124, 2230
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Corrosion behavior of AA2024-T6 and AA6065-T6 alloys in reline

Mihael Bucko, Alexandre C. Bastos, Kiryl A. Yasakau, Mario G.S. Ferreira and Jelena B. Bajat

Electrochimica Acta, 2020, 357, 136861
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Water-Induced Restructuring of the Surface of a Deep Eutectic Solvent

Rahul Gera, Carolyn J. Moll, Aditi Bhattacherjee and Huib J. Bakker

J. Phys. Chem. Lett., 2022, 13, 634
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Deep eutectic electrodeposition for energy storage and conversion systems. A comprehensive review

M. Fouji, M.R. Khalili, M. Askarzadeh Torghabeh and Ghasem Barati Darband

International Journal of Hydrogen Energy, 2024, 69, 1511
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Electrodeposition of iron and neodymium from calcium chloride hexahydrate eutectic solvents

Muwafaq A. Rabeea, Molly E. Keal, Christopher E. Elgar, Jake M. Yang, Andrew P. Abbott and Jennifer M. Hartley

Electrochimica Acta, 2025, 533, 146517
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Molecular insight into wetting behavior of deep eutectic solvent droplets on ionic substrates: A molecular dynamics study

Qingwei Gao, Nanhua Wu, Yao Qin, Aatto Laaksonen, Yudan Zhu, Xiaoyan Ji and Xiaohua Lu

Journal of Molecular Liquids, 2020, 319, 114298
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Electrochemical interfaces between Au(100) and deep eutectic solvents: An in situ scanning tunneling microscopy study

Zhuo Tan, Kaixuan Li, Yuanhui Xiao, Yu Gu, Ziang Nan, Weiwei Wang, Lan Sun, Deyin Wu, Bingwei Mao and Jiawei Yan

Electrochimica Acta, 2023, 461, 142686
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Moisture-activated deep eutectic electrolyte enabling stable metal Zn anode

Yihua Xie, Jianhang Huang, Taoyi Kong, Xing Zhou, Kai Wu, Xiaoyu Liu, Jin Yi, Lidan Xing and Yongyao Xia

Energy Storage Materials, 2023, 56, 218
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Tuning the nanostructure and tribological properties of a non-ionic deep eutectic solvent with water addition

Joshua J. Buzolic, Matteo Tiecco, Rob Atkin and Hua Li

Journal of Colloid and Interface Science, 2025, 683, 722
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23Na NMR T1 relaxation measurements as a probe for diffusion and dynamics of sodium ions in salt–glycerol mixtures

Carmine D’Agostino, Stefan J. Davis and Andrew P. Abbott

The Journal of Chemical Physics, 2021, 154
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Calcium chloride-based systems for metal electrodeposition

Jennifer M. Hartley, Jack Allen, Julia Meierl, Alexei Schmidt, Ingo Krossing and Andrew P. Abbott

Electrochimica Acta, 2022, 402, 139560
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Surface-active ionic liquids as lubricant additives to hexadecane and diethyl succinate

Joshua J. Buzolic, Hua Li, Zachary M. Aman, Debbie S. Silvester and Rob Atkin

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 699, 134669
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Mass transport and heterogeneous electron transfer in high-concentration electrolytes: From conventional to two-dimensional material electrodes

Shuai Liu, Guilhem Pignol, Corinne Lagrost, Bingwei Mao, Philippe Hapiot and Jiawei Yan

Current Opinion in Electrochemistry, 2025, 51, 101667
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Molecular dynamics-to-machine learning for deep eutectics in energy storages

Rituraj Dubey, Anees A. Ansari, Youngil Lee, Shili Gai, Ruichan Lv, Ziyue Ju, Shafiya Mohammad, Piaoping Yang and Laxman Singh

Renewable and Sustainable Energy Reviews, 2025, 212, 115358
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Confining deep eutectic solvents in nanopores: Insight into thermodynamics and chemical activity

Benjamin Malfait, Aicha Jani and Denis Morineau

Journal of Molecular Liquids, 2022, 349, 118488
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Molecular Resolution Nanostructure and Dynamics of the Deep Eutectic Solvent—Graphite Interface as a Function of Potential

Justin S. Freeman, Mesfin Haile Mamme, Jon Ustarroz, Gregory G. Warr, Hua Li and Rob Atkin

Small, 2023, 19
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Adsorption phenomena at the interface between mercury and solutions containing choline chloride, ethylene glycol and water

F.I. Danilov, Y.D. Rublova and V.S. Protsenko

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Corrosion of iron, nickel and aluminium in deep eutectic solvents

Essa I. Ahmed, Karl S. Ryder and Andrew P. Abbott

Electrochimica Acta, 2021, 397, 139284
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Study on the effect of operating parameters towards CO2 absorption behavior of choline chloride – Monoethanolamine deep eutectic solvent and its aqueous solutions

Haryo Wibowo, Wenjuan Liao, Xuanyou Zhou, Caimeng Yu, Dicka Ar Rahim, Dwi Hantoko, Huan Qun and Mi Yan

Chemical Engineering and Processing - Process Intensification, 2020, 157, 108142
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Sustainable Synthesis of Cellulose Nanofibers from Industrial Agar Seaweed Waste Biomass Using Hydrated Deep Eutectic Solvents

Safrina Dyah Hardiningtyas, Budiono Ujaya Putra, Krisna Bayu Anggara, Indah Yuniasani, Wahyu Ramadhan, Rizfi Fariz Pari, Uju, Novitri Hastuti, Dian Anggraini Indrawan, Rie Wakabayashi, Masahiro Goto and Noriho Kamiya

Waste Biomass Valor, 2024, 15, 4899
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Probing the interface of choline chloride-based deep eutectic solvent ethaline with gold surfaces: A molecular dynamics simulation study

Elisabete S.C. Ferreira, Iuliia V. Voroshylova and M.Natália D.S. Cordeiro

Surfaces and Interfaces, 2024, 46, 104051
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An In Situ Scanning Tunneling Microscopy Study on the Electrochemical Interface between Au(111) and Ethaline Deep Eutectic Solvent

Zhuo Tan, Yu Peng, Jingli Liu, Yun Yang, Zhisen Zhang, Zhaobin Chen, Bingwei Mao and Jiawei Yan

ChemElectroChem, 2020, 7, 4601
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Electrochemical interfaces in ionic liquids/deep eutectic solvents incorporated with water: A review

Shuai Liu, Zhuo Tan, Jiedu Wu, Bingwei Mao and Jiawei Yan

Electrochemical Science Adv, 2023, 3
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Advanced chiral molecular media for enantioselective electrochemistry and electroanalysis

Sara Grecchi, Serena Arnaboldi, Simona Rizzo and Patrizia Romana Mussini

Current Opinion in Electrochemistry, 2021, 30, 100810
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Deep Eutectic Solvents: A Review of Fundamentals and Applications

Benworth B. Hansen, Stephanie Spittle, Brian Chen, Derrick Poe, Yong Zhang, Jeffrey M. Klein, Alexandre Horton, Laxmi Adhikari, Tamar Zelovich, Brian W. Doherty, Burcu Gurkan, Edward J. Maginn, Arthur Ragauskas, Mark Dadmun, Thomas A. Zawodzinski, Gary A. Baker, Mark E. Tuckerman, Robert F. Savinell and Joshua R. Sangoro

Chem. Rev., 2021, 121, 1232
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The Impact of Water on the Lateral Nanostructure of a Deep Eutectic Solvent–Solid Interface

Aaron Elbourne, Quinn A. Besford, Nastaran Meftahi, Russell J. Crawford, Torben Daeneke, Tamar L. Greaves, Christopher F. McConville, Gary Bryant, Saffron J. Bryant and Andrew J. Christofferson

Australian Journal of Chemistry, 2022, 75, 111
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Deep Eutectic Solvent Reline at 2D Nanomaterial Interfaces

Sara Rozas, Mert Atilhan and Santiago Aparicio

J. Phys. Chem. B, 2020, 124, 1197
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Nanostructure of a deep eutectic solvent at solid interfaces

Aaron Elbourne, Nastaran Meftahi, Tamar L. Greaves, Christopher F. McConville, Gary Bryant, Saffron J. Bryant and Andrew J. Christofferson

Journal of Colloid and Interface Science, 2021, 591, 38
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Electrodeposition of Ni–Fe alloy from a choline chloride-containing ionic liquid

Felix I. Danilov, Dmytro A. Bogdanov, Olena V. Smyrnova, Sergiy A. Korniy and Vyacheslav S. Protsenko

J Solid State Electrochem, 2022, 26, 939
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Effect of water on the electrodeposition of copper from a deep eutectic solvent

P. E. Valverde, T. A. Green and S. Roy

J Appl Electrochem, 2020, 50, 699
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Trace Water Changes Metal Ion Speciation in Deep Eutectic Solvents: Ce3+ Solvation and Nanoscale Water Clustering in Choline Chloride–Urea–Water Mixtures

Oliver S. Hammond, Elly K. Bathke, Daniel T. Bowron and Karen J. Edler

Inorg. Chem., 2023, 62, 18069
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Molecular dynamics investigation of wetting–dewetting behavior of reline DES nanodroplet at model carbon material

Akshay Malik, Harender S. Dhattarwal and Hemant K. Kashyap

The Journal of Chemical Physics, 2020, 153
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Recent developments of deep eutectic solvent as absorbent for CO2 removal from syngas produced from gasification: Current status, challenges, and further research

Haryo Wibowo, Herri Susanto, Nurak Grisdanurak, Dwi Hantoko, Kunio Yoshikawa, Huan Qun and Mi Yan

Journal of Environmental Chemical Engineering, 2021, 9, 105439
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Potential Dependence of Surfactant Adsorption at the Graphite Electrode/Deep Eutectic Solvent Interface

Katharina Häckl, Hua Li, Iain M. Aldous, Terrence Tsui, Werner Kunz, Andrew P. Abbott, Gregory G. Warr and Rob Atkin

J. Phys. Chem. Lett., 2019, 10, 5331
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The Anodic Behaviour of Bulk Copper in Ethaline and 1-Butyl-3-Methylimidazolium Chloride

Wrya O. Karim, Shujahadeen B. Aziz, Mohamed. A. Brza, Ranjdar M. Abdullah and Mohd. F. Z. Kadir

Applied Sciences, 2019, 9, 4401
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Influence of water content and applied potential on the electrodeposition of Ni coatings from deep eutectic solvents

Monika Lukaczynska, El Amine Mernissi Cherigui, Andrea Ceglia, Krista Van Den Bergh, Joost De Strycker, Herman Terryn and Jon Ustarroz

Electrochimica Acta, 2019, 319, 690
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Deep eutectics and analogues as electrolytes in batteries

Maria Enrica Di Pietro and Andrea Mele

Journal of Molecular Liquids, 2021, 338, 116597
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Natural-based chiral task-specific deep eutectic solvents: A novel, effective tool for enantiodiscrimination in electroanalysis

Serena Arnaboldi, Andrea Mezzetta, Sara Grecchi, Mariangela Longhi, Elisa Emanuele, Simona Rizzo, Fabiana Arduini, Laura Micheli, Lorenzo Guazzelli and Patrizia Romana Mussini

Electrochimica Acta, 2021, 380, 138189
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Application of deep eutectic solvents for dissolution of sulphide ores: Review

Rudzani Nepfumbada, Endazenaw Bizuneh Chemere and Mapula Lucey Mavhungu

Mineral Processing and Extractive Metallurgy: Transactions of the Institutions of Mining and Metallurgy, 2026, 135, 14
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Design of alumina-supported solid base catalysts via deep eutectic solvents: Leveraging solvent and template effects

Peng Wang, Chengchao Lv, Xiaoling Zhang, Jiajun Yin, Jiayue Kang, Xinxin Zhu and Yupei Zhao

Chemical Engineering Journal: Green and Sustainable, 2026, 2, 100030
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Manipulating meso-scale solvent structure from Pd nanoparticle deposits in deep eutectic solvents

Joshua A. Hammons, Quinn A. Besford, Jan Ilavsky and Andrew J. Christofferson

The Journal of Chemical Physics, 2021, 155
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Structure of Deep Eutectic Solvents (DESs): What We Know, What We Want to Know, and Why We Need to Know It

Nicole M. Stephens and Emily A. Smith

Langmuir, 2022, 38, 14017
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Interfacial Nanostructure and Hydrogen Bond Networks of Choline Chloride and Glycerol Mixtures Probed with X-ray and Vibrational Spectroscopies

Pyeongeun Kim, Chaya Weeraratna, Slavomír Nemšák, Nureshan Dias, Alexander K. Lemmens, Kevin R. Wilson and Musahid Ahmed

J. Phys. Chem. Lett., 2024, 15, 3002
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Hydrogen Bond Donors Dictate the Frictional Response in Deep Eutectic Solvents

Hannah J. Hayler, James E. Hallett and Susan Perkin

Langmuir, 2024, 40, 5695
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Transition of a Deep Eutectic Solution to Aqueous Solution: A Dynamical Perspective of the Dissolved Solute

Sushil S. Sakpal, Samadhan H. Deshmukh, Srijan Chatterjee, Deborin Ghosh and Sayan Bagchi

J. Phys. Chem. Lett., 2021, 12, 8784
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Bulk and interfacial nanostructure and properties in deep eutectic solvents: Current perspectives and future directions

Saffron J. Bryant, Andrew J. Christofferson, Tamar L. Greaves, Christopher F. McConville, Gary Bryant and Aaron Elbourne

Journal of Colloid and Interface Science, 2022, 608, 2430
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Restructuring a Deep Eutectic Solvent by Water: The Nanostructure of Hydrated Choline Chloride/Urea

Liel Sapir and Daniel Harries

J. Chem. Theory Comput., 2020, 16, 3335
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EXAFS and Rotating Disc Electrode Study into the Thermochromic Behavior of Nickel Salts in Deep Eutectic Solvents

Jennifer M. Hartley, George Tebbutt, Andrew Ballantyne, Charlotte Ashworth-Güth, Gero Frisch and Karl S. Ryder

J. Phys. Chem. C, 2025, 129, 20758
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Electrochemical Potential–Driven Ion Migration and Interfacial Adsorption in Ionic Liquids

Qilong Zhou, Tao Jin, Huaze Sun, Aatto Laaksonen, Jiahua Zhu, Xiaohua Lu and Liwen Mu

Green Chemical Engineering, 2026
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Recent Advances in the Synthesis of Inorganic Materials Using Environmentally Friendly Media

Lorenzo Gontrani, Pietro Tagliatesta, Domenica Tommasa Donia, Elvira Maria Bauer, Matteo Bonomo and Marilena Carbone

Molecules, 2022, 27, 2045
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Long-Range Electrostatic Colloidal Interactions and Specific Ion Effects in Deep Eutectic Solvents

Adrian Sanchez-Fernandez, Andrew J. Jackson, Sylvain F. Prévost, James J. Doutch and Karen J. Edler

J. Am. Chem. Soc., 2021, 143, 14158
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Effects of Water on Electrochemical Behavior of ZnCl2 and FeCl3 in Deep Eutectic Solvent Composed of Choline Chloride and Urea

F. Zhu, R. X. Deng and Q. H. Jiang

Russ J Electrochem, 2022, 58, 617
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An Alternative Route to Prepare Polymelamine by Electropolymerization in Deep Eutectic Solvents Containing Water

Xi Xiao, Jin Ma, Yujie Tan, Canjun Liu, Yuanqiang Hao, Peisheng Zhang, Rongjin Zeng and Shu Chen

Electrocatalysis, 2024, 15, 394
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Deep eutectic solvents and their application in electrochemistry

Andrew P. Abbott

Current Opinion in Green and Sustainable Chemistry, 2022, 36, 100649
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