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The temporal control (ON/OFF/ON) of the fluorescence of a dichloromethane/acetonitrile 1 : 1 solution of calixarene 3 decorated with two pyrenyl moieties at the upper rim is attained by the addition of CCl3CO2H used as a convenient chemical fuel.

Graphical abstract: Dissipative control of the fluorescence of a 1,3-dipyrenyl calix[4]arene in the cone conformation

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