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A scalable solid-state reaction is presented to synthesize an FeF3 cathode material by using PTFE as a source of both fluorine and carbon. The method yields nanocrystalline FeF3/C showing excellent electrochemical performance even without any conducting additive. This method can be utilized for engineering MFs’ properties and developing other fluorine compounds.

Graphical abstract: Novel and scalable solid-state synthesis of a nanocrystalline FeF3/C composite and its excellent electrochemical performance

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