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Abstract | Cited by

Excess electron transfer dynamics in DNA hairpins was investigated by femtosecond laser flash photolysis of a donor–DNA–acceptor system using N,N-dimethylaminopyrene and diphenylacetylene as an electron donor and acceptor, respectively. It was revealed that the excess electron hopping rate between T's is faster than that of the hole.

Graphical abstract: Excess electron transfer dynamics in DNA hairpins conjugated with N,N-dimethylaminopyrene as a photosensitizing electron donor

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