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Well-defined Zn-complexes in homogeneous catalysis: recent advances and future scope

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Ligand-centered redox-driven Zn(ii)-catalyzed anti-Markovnikov hydroamination of activated alkenes with primary aromatic amines via aminium radical cations

Subhasree Pal, Santana Chakraborty, Afsana Pervin and Nanda D. Paul

Org. Chem. Front., 2026, 13, 216
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Recent progress in transition-metal-catalysed intermolecular saturated C(sp3)–N(sp3) bond formation reactions

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Green chemistry spotlight: metal-free organic transformations mediated by potassium persulfate

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Accelerating cross-modality reaction optimization via robotically automated vacuum enabled direct-inject mass spectrometry (RAVE MS)

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Ruthenium-catalyzed late-stage C–H alkenylation of N-arylpyridazino[4,5-b]quinolin-1(2H)-ones

Chinnagounder Kameshwaran and Fazlur Rahman Nawaz Khan

Org. Biomol. Chem., 2026, 24, 411
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Nickel-catalysed regio- and stereoselective hydrocyanation of alkynoates and its mechanistic insights proposed by DFT calculations

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Triflic acid catalyzed intermolecular hydroamination of alkenes with Fmoc-NH2 as the amine source

Aswathi C. S., Chinraj Sivarajan and Raja Mitra

Org. Biomol. Chem., 2025, 23, 5352
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Silanes as a versatile hydride source for Ni–H catalysis: a promising tool for π-hydro functionalization

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NiH‐Catalyzed Enantio‐ and Regioselective Hydroarylation of Unactivated Alkenes Enabled by Outer‐Sphere Electron Transfer with Diaryliodonium Salts

Hyung‐Joon Kang, Leejae Kim, Juyeon Lee and Sungwoo Hong

Angew Chem Int Ed, 2025, 64
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Transition-Metal Hydride Catalysis Meets Nitrenoid Transfer: Design Principles for Precision C–N Bond Formation

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Halogen Promoted Desulfurative Cleavage of Cyclopropylmethyl Thioethers and Amination of the Formed Cyclopropylcarbinyl Cations

Pablo Marín‐Díaz, Clara Martínez‐Núñez, Roberto Sanz and Samuel Suárez‐Pantiga

Eur J Org Chem, 2024, 27
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Synthesis of Acyclic α-Quaternary Chiral Nitriles via Ni-Catalyzed Asymmetric Markovnikov Hydrocyanation of 1,1-Disubstituted and Trisubstituted Alkenes

Mingdong Jiao, Zhaohang Jiang, Riyong Ye, Ting Wang and Xianjie Fang

J. Am. Chem. Soc., 2026, 148, 3872
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Modular Access to Quaternary α-Cyano Carbonyl Compounds via NiH Catalysis

Yoonho Lee, Yujin Jung, Seonhwa Choo and Kwangmin Shin

JACS Au, 2025, 5, 4506
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Recent Advances in Catalytic Hydroamidation Reactions of Unsaturated Substrates with Dioxazolones

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Nickel Catalyzed Enantioselective 1,4-Hydroamination of 1,3-Dienes

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J. Am. Chem. Soc., 2024, 146, 18440
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NiH-Catalyzed Regioselective Hydroamidation of Unactivated Alkenes with Dioxazolones

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J. Org. Chem., 2025, 90, 12385
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Iron-catalysed radical Markovnikov hydroamidation of complex alkenes

Mengjun Huang, Constantin Gabriel Daniliuc and Armido Studer

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Regio- and Enantioselective Nickel-Catalyzed Hydroamination of Unactivated Alkenes with Anthranils

Jia-Yi Li, Zhe-Xuan Li, Yue Liu, Yue Qiao and Yan-Long Zheng

ACS Catal., 2025, 15, 16622
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Recent Developments in Titanium, Nickel, and Other First-Row Transition Metal-Catalyzed Hydro(amination/aminoalkylation), Oxidative Amination, and Carboamination Reactions

Britney Baez and Adam R. Johnson

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Potassium Carbonate Catalyzed Intramolecular Post-Ugi Hydroamination Reaction Leading to N-Aryl Piperazine Derivatives

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Synlett, 2025, 36, 1219
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Designing a Potential Pathway for the Catalytic Synthesis of 1,3-Cyclohexanediamine

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Catalytic Hydroamination as a Solvent-Free Method for Silicone Materials Obtaining

Konstantin V. Deriabin, Vadim P. Boyarskiy and Regina M. Islamova

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Tunable Preparation of β‐Substituted Alkenoate Esters via Radical Alkenylation of C(sp3)–H Bonds with Allenoates

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Ligand-controlled NiH-catalyzed regiodivergent hydroalkylation of 2-alkenylazaarenes

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Acid-Catalyzed Solvent-Switchable Chemoselective N-Alkylation and para C-Alkylation of Unprotected Arylamines Utilizing ortho-Quinone Methides

Rina Mahato, Rima Samanta, Dulal Musib and Chinmoy K. Hazra

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NiH‐Catalyzed Enantio‐ and Regioselective Hydroarylation of Unactivated Alkenes Enabled by Outer‐Sphere Electron Transfer with Diaryliodonium Salts

Hyung‐Joon Kang, Leejae Kim, Juyeon Lee and Sungwoo Hong

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Hydrogen atom transfer-enabled hydroacylation of alkenes with acyl chlorides

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Regioselective Hydroamidation of α,β-Unsaturated Esters Enabled by Lewis Acid/Iron Relay Catalysis

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J. Am. Chem. Soc., 2025, 147, 33615
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Ni‐Catalyzed Stereodivergent Synthesis of N‐Glycosides

Jinhong Chen and Ruben Martin

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Nickel-Catalyzed Hydroalkynylation of Unactivated Alkenes: Synthesis of Substituted Alkynes

Ankita Kar and Masilamani Jeganmohan

J. Org. Chem., 2026, 91, 4388
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Palladium(II)-Catalyzed Regioselective Hydroamination of Allylamines to N-Alkyl Sulfoximines

Shib Nath Saha, Nityananda Ballav and Mahiuddin Baidya

Org. Lett., 2025, 27, 1999
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Synthesis and Antimicrobial Activity of Novel Sulfonyl Piperidine Carboxamide Derivatives Prepared from N-Boc-Piperidine-3-carboxylic Acid via Amide Coupling

Shital Jagtap and Poonam Kaswan

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Nickel-Catalyzed Regio- and Enantioselective Hydrofluorination in Unactivated Alkenes

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Efficient amidation of aldehydes and amine hydrochloride salts by magnetic Cu-MOF nanocatalyst

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Enantioselective Access to β-Amino Carbonyls via Ni-Catalyzed Formal Olefin Hydroamidation

Xiang Lyu, Hoimin Jung, Dongwook Kim and Sukbok Chang

J. Am. Chem. Soc., 2024, 146, 14745
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Nickel-Catalyzed Hydrofluorination in Unactivated Alkenes: Regio- and Enantioselective C–F Bond Formation

Changseok Lee, Minseok Kim, Seunghoon Han, Dongwook Kim and Sungwoo Hong

J. Am. Chem. Soc., 2024, 146, 9375
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Nickel-Catalyzed Regio- and Stereoselective Hydroalkylation of Allenes: Exploiting the Unique Reactivity of Diazo Compounds as an Alkylating Source

Ujjwal Karmakar, Jaehan Bae, Jin A Kim, Seoyeon Kim, Won-Geun Yang and Eun Jin Cho

ACS Catal., 2024, 14, 16570
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