Hydroaminoalkylation: A Tool of Choice for the Catalytic Addition of Amines to Alkenes in Small Molecules and Materials

Saeed Ataie and Laurel L. Schafer

Acc. Chem. Res., 2025, 58, 2956
DOI: 10.1021/acs.accounts.5c00375

Toward a circular economy: Upcycling PET and fatty diamine derivatives into recyclable non–isocyanate poly(ester-urethane)s

Dominik Wołosz, Magdalena Mazurek-Budzyńska, Paulina Rajewska, Martyna Musiatowicz, Weronika Małgorzata Milanowska, Tomasz Gołofit, Marcin Jarosław Kędzierski, Subrajeet Deshmukh, Robert Brüll and Paweł Grzegorz Parzuchowski

European Polymer Journal, 2025, 239, 114330
DOI: 10.1016/j.eurpolymj.2025.114330

Sustainable polymers: Recycling and reprocessing mechanisms using reversible and dynamic covalent bonds

Mohammad Reza Gholizadeh, Hossein Roghani-Mamaqani and Vahid Haddadi-Asl

Materials Science and Engineering: R: Reports, 2026, 168, 101174
DOI: 10.1016/j.mser.2025.101174

Thermodynamic exclusion of alkaline ionic crystals from polymers and interfacial-controlled subcritical water degradation

Li Yan, Lin-Han Wang, Xiao-Sa Liu, Qi Zeng, Zi-Bin Huang, Jing-Yi Yang and Pei-Qing Yuan

Chemical Engineering Science, 2026, 330, 123853
DOI: 10.1016/j.ces.2026.123853

Identifying gaps in practical use of epoxy foam/aerogels: review - solutions and prospects

Tomy Muringayil Joseph, Seitkhan Azat, Ehsan Kianfar, Kunnelveli S. Joshy, Omid Moini Jazani, Amin Esmaeili, Zahed Ahmadi, Józef Haponiuk and Sabu Thomas

Reviews in Chemical Engineering, 2025, 41, 269
DOI: 10.1515/revce-2024-0044

Metathesis Depolymerization of a Fluorogenic Self-Immolative Polymer

Gavin J. Giardino and Jia Niu

ACS Macro Lett., 2025, 14, 558
DOI: 10.1021/acsmacrolett.5c00192

Toward Sustainable Polydienes

Pengfei Wu, Qixuan Hu, Lawal A. Ogunfowora, Zhixu Li, Andrew V. Marquardt, Brett M. Savoie and Letian Dou

J. Am. Chem. Soc., 2025, 147, 2960
DOI: 10.1021/jacs.4c12730

Recent Advances and Applications of Sustainable and Recyclable Polymers

Farimah Kamran, Hana Afshar and Farangis Shahi

Polymer Engineering & Sci, 2025, 65, 3845
DOI: 10.1002/pen.27257

Linear and Network-Forming Acetal Polymerization of Multifunctional Alcohols with Dichloromethane for Degradable and Recyclable Materials

Joshua T. Kamps, Bruce E. Kirkpatrick, Sean P. Keyser, Connor E. Miksch, Benjamin R. Nelson, John F. Rynk, Benjamin D. Fairbanks, Kristi S. Anseth and Christopher N. Bowman

Macromolecules, 2025, 58, 1578
DOI: 10.1021/acs.macromol.4c03078

Photo-Triggerable Polymerization and Depolymerization of Stiff-Stilbene Lactones

Yong-Liang Su, Wei Xiong, Timothy M. Hunter, Kaitlyn S. Engle and Will R. Gutekunst

J. Am. Chem. Soc., 2025, 147, 32054
DOI: 10.1021/jacs.5c10480

Selective Synthesis and Polymerization of Methyl-1,4-dioxan-2-one toward Closed-Loop Recyclable Poly(ether-alt-ester) from Methyl Glycolate and Propylene Oxide

Dongfang Zhao, Tianqi Li, Lihang Jiang, Zheng Li and Zhibo Li

Biomacromolecules, 2026, 27, 2125
DOI: 10.1021/acs.biomac.5c02468

Michael Addition–Elimination Ring-Opening Polymerization

Yong-Liang Su, Wei Xiong, Liang Yue, Mckinley K. Paul, Kaitlyn S. Otte, John Bacsa, H. Jerry Qi and Will R. Gutekunst

J. Am. Chem. Soc., 2024, 146, 18074
DOI: 10.1021/jacs.4c05054

Decarboxylation-Triggered Polymer Deconstruction

Sean R. Gitter, Cabell B. Eades, Megan E. Lott, Rhys W. Hughes, Austin M. Evans and Brent S. Sumerlin

ACS Polym. Au, 2025, 5, 669
DOI: 10.1021/acspolymersau.5c00146

Thermochemical upcycling of plastic waste: A comprehensive view from technology to commercialization

Jechan Lee, Seonguk Heo, Doeun Choi and Ki-Hyun Kim

Materials Science and Engineering: R: Reports, 2026, 168, 101170
DOI: 10.1016/j.mser.2025.101170

Stimuli-Responsive Main-Chain Degradable Polymers: Synthesis, Applications, and Future Perspectives

Sagar Bag, Desoshree Ghosh, Supratim Banerjee and Priyadarsi De

ACS Appl. Polym. Mater., 2025, 7, 14033
DOI: 10.1021/acsapm.5c03009

Reprocessable and Recyclable Materials for 3D Printing via Reversible Thia‐Michael Reactions

Yong‐Liang Su, Liang Yue, McKinley K. Paul, Joseph Kern, Kaitlyn S. Otte, Rampi Ramprasad, H. Jerry Qi and Will R. Gutekunst

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202423522

Orthogonal and Multiresponsive Quinolinone Systems for Reversible and Recyclable Polymer Networks

Claas-Hendrik Stamp, Annalena Groß, Aitana Beato Irulegui, Bizan N. Balzer and Céline Calvino

J. Am. Chem. Soc., 2025, 147, 32830
DOI: 10.1021/jacs.5c08976

Chemically recyclable rosin-based polymers

Ye Sha, Xiaofan Chen, Wei Sun, Yuan Hu, Chengcheng Wang, Enhua Xu, Zhenyang Luo and Puyou Jia

European Polymer Journal, 2024, 213, 113141
DOI: 10.1016/j.eurpolymj.2024.113141

Ultrafast Thermal RAFT Depolymerization at Higher Solid Contents

Dimitra Mantzara, Richard Whitfield, Hyun Suk Wang, Nghia P. Truong and Athina Anastasaki

ACS Macro Lett., 2025, 14, 235
DOI: 10.1021/acsmacrolett.5c00009

Polyheptenamer: A chemically recyclable polyolefin enabled by the low strain of seven‐membered cycloheptene

Tarek Ibrahim, Jordan Martindale, Angelo Ritacco, Mia Rodriguez and Hao Sun

Journal of Polymer Science, 2024, 62, 4921
DOI: 10.1002/pol.20240196

Preparation of Degradable Polymers Containing Tunable Ratios of Dithioacetals and Disulfides via Mixed Mode Polymerization

Sean P. Keyser, Benjamin D. Fairbanks, Joshua T. Kamps and Christopher N. Bowman

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202515269

Enabling a Diversity‐Oriented Catalytic Atom Looping of a Biobased Polycarbonate

Enrico Lanaro, Thirusangumurugan Senthamarai, Stephen K. Hashmi and Arjan W. Kleij

ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202501905

AI-Assisted Design of Chemically Recyclable Polymers for Food Packaging

Brandon K. Phan, Chiho Kim, Janhavi Nistane, Wei Xiong, Haoyu Chen, Woo Jin Jang, Farzad Gholami, Yongliang Su, Jerry Qi, Ryan Lively, Will Gutekunst and Rampi Ramprasad

Polymers, 2026, 18, 730
DOI: 10.3390/polym18060730

Functional Group Transformation Approach to Chemically Recyclable Polymers from Ultra-Low to Moderate Strain Monomers

Tarek Ibrahim, Kaia Kendzulak, Angelo Ritacco, Melanie Monetti and Hao Sun

Macromolecules, 2025, 58, 3898
DOI: 10.1021/acs.macromol.4c03248

Entropy-Driven Design of Depolymerizable Polyolefins from Strained Bridged Bicyclic Monomers

Tarek Ibrahim, Desmond Brown and Hao Sun

J. Am. Chem. Soc., 2026
DOI: 10.1021/jacs.6c02456

Thermal Solution Depolymerization of RAFT Telechelic Polymers

Nethmi De Alwis Watuthanthrige, Richard Whitfield, Simon Harrisson, Nghia P. Truong and Athina Anastasaki

ACS Macro Lett., 2024, 13, 806
DOI: 10.1021/acsmacrolett.4c00286

Development and application of a method to assess the resource attributes of different types of waste plastics: From an exergy perspective

Zheng-Jie Qian, Bo-Xue Sun, Zuo-Ren Nie, Shi-Wei Du and Xian-Zheng Gong

Journal of Environmental Chemical Engineering, 2025, 13, 116599
DOI: 10.1016/j.jece.2025.116599

Dynamic Bond Chemistry in Soft Materials: Bridging Adaptability and Mechanical Robustness

Haeseung Lee, Jiyun Kim, Minwoo Lee and Jiheong Kang

Chem. Rev., 2025, 125, 11379
DOI: 10.1021/acs.chemrev.5c00566

Recent polymer modification strategies for reducing plastic waste and enhancing recyclability

Hridoy Dey, Md. Rezaul Karim Sheikh and Asnaf Nihan Shuvo

Polymers and Polymer Composites, 2026, 34
DOI: 10.1177/09673911261441896

Reprocessable and Recyclable Materials for 3D Printing via Reversible Thia‐Michael Reactions

Yong‐Liang Su, Liang Yue, McKinley K. Paul, Joseph Kern, Kaitlyn S. Otte, Rampi Ramprasad, H. Jerry Qi and Will R. Gutekunst

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202423522

Benzo-Fused Monomer Design toward Semiaromatic Polymers for a Circular Plastic Economy

Zhongzheng Cai, Yi-Min Tu, Hua-Zhong Fan and Jian-Bo Zhu

Acc. Chem. Res., 2026, 59, 311
DOI: 10.1021/acs.accounts.5c00743

Poly(vinyl chloride) (PVC): an updated review of its properties, polymerization, modification, recycling, and applications

Great Iruoghene Edo, Winifred Ndudi, Ali B. M. Ali, Emad Yousif, Khalid Zainulabdeen, Priscillia Nkem Onyibe, Helen Avuokerie Ekokotu, Endurance Fegor Isoje, Ufuoma Augustina Igbuku, Arthur Efeoghene Athan Essaghah, Dina S. Ahmed, Huzaifa Umar and Dilber Uzun Ozsahin

J Mater Sci, 2024, 59, 21605
DOI: 10.1007/s10853-024-10471-4

Living Anionic Polymerization of 2-Isopropenylthiophene Derivatives

Yuki Kurishiba, Daisuke Yamamoto, Chihiro Homma, Raita Goseki and Takashi Ishizone

Macromolecules, 2025, 58, 4726
DOI: 10.1021/acs.macromol.4c02845

Kinetic modeling for radical polymerization and depolymerization

Yue Fang and Hanyu Gao

Current Opinion in Chemical Engineering, 2025, 49, 101152
DOI: 10.1016/j.coche.2025.101152

Degradable Polydithioacetals with Adjustable Mechanical Properties and Insights into Entropy-Driven Ring-Opening Polymerization

Abdulwarith O. Kassim, Lasith S. Kariyawasam and Ying Yang

Macromolecules, 2025, 58, 3395
DOI: 10.1021/acs.macromol.4c03237

Preparation of Degradable Polymers Containing Tunable Ratios of Dithioacetals and Disulfides via Mixed Mode Polymerization

Sean P. Keyser, Benjamin D. Fairbanks, Joshua T. Kamps and Christopher N. Bowman

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202515269

Modulating Poly(oligocyclobutane) Properties Through Backbone Modifications

Shawn M. Maguire, Cherish Nie, Sahana V. Sundar, Stavros X. Drakopoulos, Paul J. Chirik, Rodney D. Priestley and Emily C. Davidson

Macromolecules, 2025, 58, 9469
DOI: 10.1021/acs.macromol.5c01592

High Molecular Weight Biobased Long-Chain Aliphatic Polyesters with Degradability: Insights into Mimicking Polyethylene

Nagarjuna A. Mahadas, Amir Suhail, Martin Taylor Sobczak, Xiaomeng Li, Kezhi Chen, Kenan Song, Guangbin Dong, Olga Kuksenok and Chuanbing Tang

Macromolecules, 2025, 58, 4070
DOI: 10.1021/acs.macromol.5c00176

Depolymerization of Vinyl Polymers

Tanmoy Maity, Don X. Bones, Rhys W. Hughes, Kaden C. Stevens, William M. Gramlich and Brent S. Sumerlin

ACS Macro Lett., 2026, 15, 17
DOI: 10.1021/acsmacrolett.5c00740

Polymer Deconstruction and Redesign Strategies for Plastics Recycling

Anjani K. Maurya, Arun S. Asundi, Ozge D. Bozkurt, Katrina M. Knauer, Simon R. Bare and Christopher J. Tassone

Adv Materials Technologies, 2026
DOI: 10.1002/admt.202502008