Enabling high-performance and high-rate-capability Na4MnV(PO4)3 sodium-ion battery cathodes through tuning the NASICON framework

Cheng-Yen Wu, Chen-En Huang, An-Chi Luo, Wen-Hsuan Lu, Shao-Chu Huang, Yu-Ming Huang, Vanessa K. Peterson, Hao-Yu Liu, Chi-Liang Chen, Ying-Rui Lu, Tsung-Yi Chen, Cheng-Zhang Lu, Wei Kong Pang and Han-Yi Chen

J. Mater. Chem. A, 2025, 13, 2716
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Recent advances in vanadium-based NASICON-structured cathode materials for sodium-ion batteries

Qianchen Wang, LiYao Lu, Zhonghao Lv, Yuhang Xin, Zimo Zhang, Yingshuai Wang and Hongcai Gao

Green Chem., 2025, 27, 12029
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Recent advances in rational design for high-performance potassium-ion batteries

Yifan Xu, Yichen Du, Han Chen, Jing Chen, Tangjing Ding, Dongmei Sun, Dong Ha Kim, Zhiqun Lin and Xiaosi Zhou

Chem. Soc. Rev., 2024, 53, 7202
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Constructing p-type substitution induced by Ca2+ in defective Na3V2−xCax(PO4)3/C wrapped with conductive CNTs for high-performance sodium-ion batteries

Xiaomei Jiang, Changcheng Liu, Zeyi Tian, Shiqi Sun, Jiahao Li, Que Huang, Weiguo Cao and Yanjun Chen

Dalton Trans., 2022, 51, 16145
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Coordination Chemistry Regulation Suppressing Voltage Hysteresis for Na3MnTi(PO4)3 in High-Rate Sodium-Ion Batteries

Shengping Deng, Chongran Song, Shuoshuo Cheng, Shiyu Li, Zhenxiang Cheng and Ying Bai

ACS Nano, 2025, 19, 10381
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Layered Structure Modification of Sodium Vanadate through Ca/F Co‐Doping for Enhanced Energy Storage Performance

Jiajia Han, Shuting Gao, Zhefei Sun, Zonghua Yang, Xingjun Liu and Cuiping Wang

Advanced Energy Materials, 2024, 14
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High-Rate-Capacity Cathode Based on Zn-Doped and Carbonized Polyacrylonitrile-Coated Na4MnV(PO4)3 for Sodium-Ion Batteries

Anping Yang, Xiaobing Huang, ChuCheng Luo, Haiyan Wang and Tao Zhou

ACS Appl. Mater. Interfaces, 2023, 15, 22132
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Nanosheet-Assembled Hierarchical Petal-like Na4MnV(PO4)3@Carbonized-Polyaniline Microspheres for Stable Sodium-Ion Batteries

Kun Wang, Xiaobing Huang, ChuCheng Luo, Zhi Zhang, Haiyan Wang and Tao Zhou

ACS Appl. Energy Mater., 2022, 5, 15701
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Manganese-based polyanionic cathode materials for sodium-ion batteries with high energy and long lifespan

Muhammad Munaim Khan, Yanshuo Zhao, Qi Liu, Wenxiu He, Daobin Mu, Li Li, Renjie Chen and Feng Wu

Journal of Energy Storage, 2025, 116, 116038
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W doping enhances rate and cycle performance of Na4VMn(PO4)3 in sodium-ion batteries

Xuan-Xi Liu, Zu-Tao Pan, Yao Xu, Hao-Peng Lu, Bo Li, Kun Yan, Fu-Ling Tang, Qi Zhou and Ling-Bin Kong

Journal of Energy Storage, 2025, 120, 116429
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Protein Cage Inspired Bridge‐Island Effect Enables Low‐Temperature Targeted Self‐Assembly of Hierarchical Hollow Polyanionic Cathodes for Sodium‐Ion Batteries

Shuqiang Li, Xueying Lu, Yu Li, Yuteng Gong, Qiannan Zhou, Huaizhi Wang, Feng Wu, Chuan Wu and Ying Bai

Angew Chem Int Ed, 2025, 64
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Iron/manganese-based polyanionic cathode materials for sodium ion batteries

Zhongyi Cui, Lisi Liang, Jin Chen, Lixing Zhang, Zeming Wang, Zhuyue Zhang, Gexuan Ning, Jiajun Xi and Jiahui Chai

Journal of Energy Storage, 2025, 137, 118508
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Biphasic and Triphasic Oxide Cathode Materials for Advanced Na-Ion Batteries

Feng Li, Mohan Dong, Huijie Bian, Peiyu Hou, Zezhou Lin, Linhui Wang and Xijin Xu

ACS Energy Lett., 2026, 11, 2599
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Accelerating Electrochemical Responses of Na4VMn(PO4)3 via Bulk‐Defects and Architecture Engineering for High‐Performance Sodium‐Ion Batteries

Jingwen Zhao, Bo Zou, Weitao Yan, Shijia Li, Wentao Wu, Wei‐Hua Wang, Shiyu Li and Ying Bai

Advanced Science, 2025, 12
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Rapid and reversible sodium-ion cathode materials for NASICON Na3MnTiP3−xBxO12 achieved through Boron-substitution

Youli Chen, Jinze Wang, Jiahui Liu, Daiwen Tao, Hui Yang and Qilong Zhang

Journal of Colloid and Interface Science, 2025, 683, 632
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Electrochemical performance of Na4P2O7 decorated Na4MnV(PO4)3/C cathode material for sodium-ion batteries

Yiwen Guo, Jiaxin Ou, Ye Sun, Honghai Zhang, Yuchao He, Bin Huang and Quanqi Chen

Materials Letters, 2024, 370, 136785
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Na+-Activation Engineering in the Na3V2(PO4)3 Cathode with Boosting Kinetics for Fast-Charging Na-Ion Batteries

Xing Shen, Yuefeng Su, Ni Yang, Xiaoping Jiang, Xingxing Liu, Junlin Mo, Yan Ran and Feng Wu

ACS Appl. Mater. Interfaces, 2022, 14, 47685
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Novel NASICON‐Type Na‐V‐Mn‐Ni‐Containing Cathodes for High‐Rate and Long‐Life SIBs

Ruoyu Chen, Xinyu Zhang, Dongdong Li, Yilin Li, Shilin Li, Denys S. Butenko, Il'ya A. Gural'skiy, Guangshe Li, Igor V. Zatovsky and Wei Han

Small, 2024, 20
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Suppressing Anti‐Site Defects via Entropy Regulation Enables High‐Rate Sodium‐Ion Battery Cathodes

Shuoshuo Cheng, Yaping Qi, Miaorui Yang, Yibing Zhang, Shiyu Li, Peng Lv and Ying Bai

Advanced Energy Materials, 2025, 15
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Bimetal‐Substituted Polyanion Cathode for Sodium‐Ion Batteries: Less Vanadium and Boosted Low‐Temperature Kinetics

Shitan Xu, Wensun Zhu, Yang Yang, Yu Yao, Ghulam Ali, Xianghua Zhang, Xianhong Rui and Yan Yu

Small Structures, 2024, 5
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Recent advances of Na3V2(PO4)3 as cathode for rechargeable zinc-based batteries

Kunpeng Ding, Tian Jiang, Jian Peng, Peng Wang, Wenshan Gou, Qingyu Xu, Qi Fan, Wei Wang and Yueming Sun

Carbon Lett., 2023, 33, 989
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Protein Cage Inspired Bridge‐Island Effect Enables Low‐Temperature Targeted Self‐Assembly of Hierarchical Hollow Polyanionic Cathodes for Sodium‐Ion Batteries

Shuqiang Li, Xueying Lu, Yu Li, Yuteng Gong, Qiannan Zhou, Huaizhi Wang, Feng Wu, Chuan Wu and Ying Bai

Angewandte Chemie, 2025, 137
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Co-substitution of Mg2+ and Ti4+ in Na3V2(PO4)3 nanoparticles coated with highly conductive carbon nanotubes for superior sodium storage

Xiaomei Jiang, Changcheng Liu, Que Huang, Weiguo Cao, Yanjun Chen and Li Guo

Journal of Alloys and Compounds, 2022, 928, 167119
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Enabling One‐Step De‐Sodiation of Na4MnV(PO4)3 Cathode via Regulating Coordination Environment for High‐Power and Long‐Lasting Sodium‐Ion Batteries

Can Chen, Liqun Wang, Zhihao Deng, Xueling Kong, Tianyi Zhang, Qinqin Yu, Zuyong Wang, Peining Zhu and Yuan‐Li Ding

Adv Funct Materials, 2025, 35
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Synergistically Achieving Superior Sodium Storage of Metal Selenides by Constructing N‐Doped Carbon Foams and Utilizing Cu‐Driven Replacement Reaction

Chao Zhu, Tao Long, Bin Feng, Chunyang Wu, Qinqin Yu and Yuan‐Li Ding

Small, 2023, 19
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Boosting cycling stability through Al(PO3)3 loading in a Na4MnV(PO4)3/C cathode for high-performance sodium-ion batteries

Kun Wang, Xiaobing Huang, ChuCheng Luo, YouMing Shen, Haiyan Wang and Tao Zhou

Journal of Colloid and Interface Science, 2023, 642, 705
DOI: 10.1016/j.jcis.2023.04.006

Optimizing the crystal structure and electrochemical properties of Na4MnCr(PO4)3 by trace La doping

Keyi Sun, Yuxuan Liu, Wenbin Fei, Yian Wang, Huazhang Guo, Kexin Rao, Mengting Deng, Yulei Sui and Ling Wu

Applied Surface Science, 2025, 681, 161505
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Activating Reversible V4+/V5+ Redox Couple in NASICON‐Type Phosphate Cathodes by High Entropy Substitution for Sodium‐Ion Batteries

Siya Wang, Jin Bai, Peiyao Wang, Yunjie Mao, Ke Xiao, Yuanyuan Liu, Shiyu Qiu, Xuebin Zhu, Bangchuan Zhao and Yuping Sun

Small, 2025, 21
DOI: 10.1002/smll.202500566

Investigating the effect of calcination temperature on the electrochemical properties of Na4MnV(PO4)3/NC@CNTs cathode materials for sodium ion batteries

Yuanqiang Zhu, Hui Xu, Yuanhai Bao, Siyao Li and Yong Chen

Journal of Energy Storage, 2024, 90, 111910
DOI: 10.1016/j.est.2024.111910

Refining the electrochemical performance of Na4MnAl(PO4)3 cathode material by magnesium doping for sodium ion batteries

Qing Zhu, Xiuli Hu, Rui Tong, Ningchen Tian, Wenhao Li, Jinxin Wu and Yanwei Li

Journal of Energy Storage, 2024, 92, 112258
DOI: 10.1016/j.est.2024.112258

Thermal Stability of NASICON-Type Na3V2(PO4)3 and Na4VMn(PO4)3 as Cathode Materials for Sodium-ion Batteries

Ruslan Samigullin, Maxim Zakharkin, Oleg Drozhzhin and Evgeny Antipov

Energies, 2023, 16, 3051
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A Medium‐Entropy Phosphate Cathode with Multielectron Redox Reaction for Advanced Sodium‐Ion Batteries

Lin Zhu, Miaomiao Wang, Shuang Xiang, Dan Sun, Yougen Tang and Haiyan Wang

Advanced Energy Materials, 2023, 13
DOI: 10.1002/aenm.202302046

Recent Progress of Promising Cathode Candidates for Sodium‐Ion Batteries: Current Issues, Strategy, Challenge, and Prospects

Chenxi Peng, Xijun Xu, Fangkun Li, Lei Xi, Jun Zeng, Xin Song, Xuanhong Wan, Jingwei Zhao and Jun Liu

Small Structures, 2023, 4
DOI: 10.1002/sstr.202300150

Next-generation cathodes for calcium-ion batteries: Leveraging NASICON structures for enhanced stability and energy density

Minseon Kim, Jaejung Park, Heekyu Kim, Jaejun Lee, Inhyo Lee, Juo Kim, Seungchul Lee and Kyoungmin Min

Energy Storage Materials, 2024, 73, 103827
DOI: 10.1016/j.ensm.2024.103827

Synergetic effects of Mo doping and Mn site vacancies on electrochemical performance of Na4MnV(PO4)3/C cathode material for sodium-ion batteries

Ye Sun, Jiaxin Ou, Yiwen Guo, Honghai Zhang, Yuchao He, Yachun Lu and Quanqi Chen

Electrochimica Acta, 2025, 538, 146985
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Improvement in potassium storage performance of magnesium-doped K3V3(PO4)4/C cathode materials

Jiaxin Ou, Wenqing Xu, Ye Sun, Honghai Zhang, Yuchao He, Zongyi Wen, Yachun Lu, Jianwen Yang and Quanqi Chen

Journal of Energy Storage, 2026, 141, 119319
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Boosting the cyclability and electrochemical kinetics of Na4MnV(PO4)3/C cathode material through Zr doping for sodium-ion batteries

Jiaxin Ou, Ye Sun, Yiwen Guo, Honghai Zhang, Yuchao He, Bin Huang and Quanqi Chen

Journal of Energy Storage, 2025, 112, 115568
DOI: 10.1016/j.est.2025.115568

Low‐Cost Polyanion‐Type Cathode Materials for Sodium‐Ion Battery

Zijing Song, Rui Liu, Wei-Di Liu, Yanan Chen and Wenbin Hu

Adv Energy and Sustain Res, 2023, 4
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Spatially engineered Y2O3/rGO dual-modification empowers ultra-stable and high-rate Na3V2(PO4)3 cathodes

Houlin Cheng, Jingxuan Li, Pengcheng Wang, Youzu Xu, Zhiyang Zhang, Qian Feng, Hurong Yao, Zhigao Huang and Jiaxin Li

Chemical Engineering Journal, 2025, 524, 168998
DOI: 10.1016/j.cej.2025.168998

Metal-organic-framework-derived porous core/shell CoP polyhedrons intertwined with 2D MXene as anode for Na-ion storage

Yanyan Ma, Hongwei Zhang, Haofei Cong, Yuxiao Wang, Shuwen Xin, Peilong Xu, Yuanbin Qin, Guangxu Xu, Xiaochan Kang and Fengyun Wang

Journal of Alloys and Compounds, 2023, 968, 171985
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The recent advances of NASICON-Na3V2(PO4)3 cathode materials for sodium-ion batteries

Yuanqiang Zhu, Hui Xu, Ji Ma, Pengdong Chen and Yong Chen

Journal of Solid State Chemistry, 2023, 317, 123669
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Synergistic Strain Suppressing and Interface Engineering in Na4MnV(PO4)3/C for Wide-Temperature and Long-Calendar-Life Sodium-Ion Storage

Lei Wang, Jiaqing Wang, Leilei Wang, Hanghang Dong, Chao Yang, Hao Yan, Yao Xiao, Yong Wang, Shulei Chou and Shuangqiang Chen

ACS Nano, 2024, 18, 10863
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Stabilized Multi‐Electron Reactions in a High‐Energy Na4Mn0.9CrMg0.1(PO4)3 Sodium‐Storage Cathode Enabled by the Pinning Effect

Jie Li, Xudong Zhao, Pingge He, Yukun Liu, Junteng Jin, Qiuyu Shen, Yao Wang, Shengwei Li, Xuanhui Qu, Yongchang Liu and Lifang Jiao

Small, 2022, 18
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Engineering mesoporous Na4Mn0.9Ni0.1V(PO4)3@NC microspheres cathode towards advanced sodium ion batteries

Lin Gao, Haobo Zhan, Guangsheng Feng, Yanan Ma, Chuankun Zhang, Yuxuan Zhang and Minglei Cao

Journal of Energy Storage, 2024, 97, 112890
DOI: 10.1016/j.est.2024.112890

Linking Local Atomic Structure and Carbon Network Architecture to Electrochemical Performance and Na+ Diffusivity in Na4VMn(PO4)3/C Cathodes

Songyoot Kaewmala, Natthapong Kamma, Sujeera Pleuksachat, Pornjira Phuenhinlad, Wanwisa Limphirat, Natthawan Prasongthum, Jeffrey Nash and Nonglak Meethong

ACS Omega, 2025, 10, 49845
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V Doping in NASICON‐Structured Na3MnTi(PO4)3 Enables High‐Energy and Stable Sodium Storage

Ping Hu, Congcong Cai, Xinyuan Li, Zihe Wei, Mengyao Wang, Changliang Chen, Ting Zhu, Liqiang Mai and Liang Zhou

Adv Funct Materials, 2024, 34
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Elevating electrochemical performance of Na4MnCr(PO4)3 cathode material for sodium ion batteries through the synergistic effect of Sc doping and RuO2/C coating

Qing Zhu, Jinxin Wu, Rui Tong, Xiuli Hu, Ningchen Tian, Botian Liu, Jiqiong Jiang, Yanwei Li, Jianwen Yang and Jianwei Zhao

Chemical Engineering Journal, 2024, 499, 156289
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Boosting sodium-ion battery performance by anion doping in NASICON Na4MnCr(PO4)3 cathode

Qing Zhu, Jinxin Wu, Wenhao Li, Xiuli Hu, Ningchen Tian, Liqing He and Yanwei Li

Journal of Colloid and Interface Science, 2024, 663, 191
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Recent progress and prospects of manganese-based NASICON-type cathodes for Na-ion batteries

Yuanqiang Zhu, Wenxia Li, Yong Chen and Hui Xu

Chemical Engineering Journal, 2026, 528, 172272
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Chlorine-regulated Na-O coordination environment of sodium iron sulfate for boosting sodium storage

Can Chen, Ruotong Li, Bingcheng Li, Xi Guo, Yuan Wang, Gang Wang, Qinqin Yu, Shuigen Li, Bowen Huang and Yuan-Li Ding

Chemical Engineering Journal, 2026, 530, 173412
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Achieving high capacity and ultra-stable sodium storage of Na2TiV(PO4)3 cathode by integrated lattice regulation and surface modification

Lin Zhu, Miaomiao Wang, Kang Liang, Shuang Xiang, Dan Sun, Xiaobing Huang, Qi Zhang, Haiyan Wang and Yougen Tang

Journal of Energy Chemistry, 2025, 103, 793
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Tailoring Cathode Interfaces in Sodium‐Ion Batteries: Advanced Coating Strategies and Electrochemical Interface Regulation

Hongwei Bi, Xia Sun, Boyang Zhao, Ruiyi Li, Yongguang Zhang, Xiaoen Wang, Meng Zhang, Dan Luo and Zhongwei Chen

Adv Funct Materials, 2025, 35
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Ultrafast Charge‐Discharge Capable and Long‐Life Na3.9Mn0.95Zr0.05V(PO4)3/C Cathode Material for Advanced Sodium‐Ion Batteries

Zhuangzhou Wang, Guijia Cui, Qinfeng Zheng, Xiangyu Ren, Qingheng Yang, Siqi Yuan, Xu Bao, Chaojiu Shu, Yixiao Zhang, Linsen Li, Yu‐Shi He, Liwei Chen, Zi‐Feng Ma and Xiao‐Zhen Liao

Small, 2023, 19
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Manganese‐based polyanionic cathodes for sodium‐ion batteries

Yubin Niu, Yanan Zhao and Maowen Xu

Carbon Neutralization, 2023, 2, 150
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Medium- and high-entropy materials as positive electrodes for sodium-ion batteries: Quo Vadis?

N.G. Garcia, Josué M. Gonçalves, Carla Real, Bruno Freitas, José G. Ruiz-Montoya and Hudson Zanin

Energy Storage Materials, 2024, 67, 103213
DOI: 10.1016/j.ensm.2024.103213