Ion transport and conduction in metal–organic framework glasses

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Metal–organic framework glass composites

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Functional metal–organic liquids

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Chem. Sci., 2024, 15, 7474
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Construction of unimpeded proton-conducting pathways in solution-processed nanoporous polymer membranes

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Mater. Horiz., 2021, 8, 3088
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Morphological control for high proton conduction in robust Co3O4-diethylmethylamine (metal–organic framework) membrane

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Melt-quenched synthesis of a manganese ZIF glass

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Chem. Commun., 2025, 61, 11641
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Membrane-shaped MOF proton conductors

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Photoluminescent coordination polymer bulk glasses and laser-induced crystallization

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Chem. Sci., 2022, 13, 3281
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Structural features of proton-conducting metal organic and covalent organic frameworks

Pampa Jhariat, Priyanka Kumari and Tamas Panda

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Metal–organic frameworks as proton conductors: strategies for improved proton conductivity

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Fast proton conductors for low humidity: hydrophilic sulfonated and phosphonated polysilsesquioxanes with Al–O–P crosslinks

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Chem. Commun., 2024, 60, 5683
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Proton-conductive coordination polymer glass for solid-state anhydrous proton batteries

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Chem. Sci., 2021, 12, 5818
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Post-synthetic modification of ionic liquids using ligand-exchange and redox coordination chemistry

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J. Mater. Chem. A, 2020, 8, 22674
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Aggregation suppression and enhanced blue emission of perylene in zinc-based coordination polymer glass

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Functions and applications of emerging metal–organic-framework liquids and glasses

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State- and water repellency-controllable molecular glass of pillar[5]arenes with fluoroalkyl groups by guest vapors

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Chem. Sci., 2022, 13, 4082
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Modulation of proton conductivity in coordination polymer mixed glasses

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Chem. Commun., 2022, 58, 6064
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Tunnel-Structured Phosphate Exhibiting High Proton Conductivity and Thermal Stability over a Wide Intermediate Temperature Range

Yasuaki Matsuda, Jun Nakajima, Yuta Inoue, Akihisa Ishikawa, Naoya Ueta, Daisuke Mori, Sou Taminato, Nobuyuki Imanishi, Takashi Fukushima and Shinya Higashimoto

Inorg. Chem., 2024, 63, 8018
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Molten Zinc Coordination Polymer Glass as a Host for Stable and Processable Optical Dye Composites

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Soft Mode Metal-Linker Dynamics in Carboxylate MOFs Evidenced by Variable-Temperature Infrared Spectroscopy

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J. Am. Chem. Soc., 2020, 142, 19291
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MOF Ceramic‐Like Membrane With High Proton Conduction and Tunable Transparency

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Angewandte Chemie, 2026
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Hierarchical Metal‐Organic Network‐Forming Glasses toward Applications

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Adv Funct Materials, 2024, 34
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Glassy Metal–Organic Framework‐Based Solid‐State Electrolytes: Advance, Challenge, and Emerging Opportunities

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Small Methods, 2025, 9
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Coordination polymer design for fast proton conduction: Hybrid atomistic approach based on kinetic Monte Carlo and molecular dynamics methods

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Materials & Design, 2022, 222, 111094
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Metal–Organic Network-Forming Glasses

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Chem. Rev., 2022, 122, 4163
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Size-dependent vitrification in hybrid glasses at micro-meter scale

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Water-Stable Al(III) Coordination Polymer Glass with High Proton Conductivity toward Stable Electrolytes in a Fuel Cell

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Luminescent metal-organic framework glasses: Challenges in quantum dot integration and rare earth doping

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Li(C2N3) as eutectic forming modifier in the melting process of the molecular perovskite [(C3H7)3N(C4H9)]Mn(C2N3)3±

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APL Materials, 2023, 11
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Enhanced Proton Conductivity of (3-mercaptopropyl)trimethoxysilane—Grafted Graphene Oxide Membranes for Hydrogen Fuel Cells

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J. Electrochem. Soc., 2021, 168, 124502
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Coordination Polymer Glasses with Lava and Healing Ability for High‐Performance Gas Sieving

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Angew Chem Int Ed, 2021, 60, 21304
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Mechanics, Ionics, and Optics of Metal–Organic Framework and Coordination Polymer Glasses

Satoshi Horike, Nattapol Ma, Zeyu Fan, Soracha Kosasang and Morten M. Smedskjaer

Nano Lett., 2021, 21, 6382
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High‐Level Disordered Metal–Organic Frameworks Synthesized by Interference‐Oriented Attachment for Electrochemical Anion Sieve

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Glass and Liquid States of Coordination Polymer Crystals

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Bull. Jpn. Soc. Coord. Chem., 2023, 81, 74
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Ammonia Capture via an Unconventional Reversible Guest-Induced Metal-Linker Bond Dynamics in a Highly Stable Metal–Organic Framework

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Chem. Mater., 2021, 33, 6186
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Structural Design of Phosphates for the Development of Proton Solid Electrolytes Operating at the Intermediate Temperature

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Meltable, Glass-Forming, Iron Zeolitic Imidazolate Frameworks

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J. Am. Chem. Soc., 2023, 145, 11258
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Network Size Control in Coordination Polymer Glasses and Its Impact on Viscosity and H+ Conductivity

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Chem. Mater., 2022, 34, 5832
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Coordination polymers for emerging molecular devices

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Chemical Physics Reviews, 2022, 3
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Recent progress of amorphous and glassy coordination polymers

Zhichong Yu, Liang Tang, Nattapol Ma, Satoshi Horike and Wenqian Chen

Coordination Chemistry Reviews, 2022, 469, 214646
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A Second Glass Transition Observed in Single-Component Homogeneous Liquids Due to Intramolecular Vitrification

Ben A. Russell, Mario González-Jiménez, Nikita V. Tukachev, Laure-Anne Hayes, Tajrian Chowdhury, Uroš Javornik, Gregor Mali, Manlio Tassieri, Joy H. Farnaby, Hans M. Senn and Klaas Wynne

J. Am. Chem. Soc., 2023, 145, 26061
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Engineering Proton Conductive Metal–Organic Glasses Through Secondary Network Formers

Nattapol Ma, Hideka Ando, Renzhi Ma and Takashi Nakanishi

Small, 2026
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Coordination polymer glass based mixed matrix membrane containing hydroxylated multi walled carbon nanotubes for enhanced CO2/N2 separation

Shuang Wang, Dudu Li, Zelong Xu, Fan Zhou, Zhihua Qiao, Zibo Yang and Zhi Wang

Polymer, 2025, 338, 129085
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Liquid Coordination Polymers with Anhydrous Proton Conductivity

Nattapol Ma, Soracha Kosasang, Satoshi Horike and Hiroki Yamada

Angewandte Chemie, 2025, 137
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Zwitterionic ionic liquids modulating two-dimensional hierarchically porous zeolitic imidazolate framework composites

Yuanyuan Duan, Mingyue Qiu, Shaobo Xu, Dongna Li, Haonan Wu, Liping Chang, Qun Yi, Lijuan Shi and Hongbo Zeng

Journal of Colloid and Interface Science, 2022, 620, 365
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Development of Proton Conductors in Mixed Cation Phosphates

Yasuaki MATSUDA

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Artificial 2d Van Der Waals Inorganic Oxychloride Anhydrous Proton Conductor

Shingo Ohta, Hiroshi Nozaki, Liang Wang, Hongfei Jia, Nikhilendra Singh, Timothy Arthur, Daniel Hashemi and Hideo Iizuka

SSRN Journal, 2022
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Glass and Liquid Chemistry of Coordination Polymers and MOFs

Satoshi Horike

Bulletin of the Chemical Society of Japan, 2023, 96, 887
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Host–Guest Assembly of H-Bonding Networks in Covalent Organic Frameworks for Ultrafast and Anhydrous Proton Transfer

Xiaowei Wu, Ziya Liu, Hu Guo, You-lee Hong, Bingqing Xu, Kun Zhang, Yusuke Nishiyama, Wei Jiang, Satoshi Horike, Susumu Kitagawa and Gen Zhang

ACS Appl. Mater. Interfaces, 2021, 13, 37172
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Development of Molecular Frameworks for Intermediate Temperature Proton Conductivity

Satoshi HORIKE, Masane KIN and Takashi SATO

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Coordination Polymer Glasses with Lava and Healing Ability for High‐Performance Gas Sieving

Jie Li, Jiaming Wang, Qingqing Li, Mengxi Zhang, Jiani Li, Chao Sun, Shuai Yuan, Xiao Feng and Bo Wang

Angewandte Chemie, 2021, 133, 21474
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MOF‐Based Solid‐State Proton Conductors Obtained by Intertwining Protic Ionic Liquid Polymers with MIL‐101

Shunlin Zhang, Yuxin Xie, Rosie J. Somerville, Farzaneh Fadaei Tirani, Rosario Scopelliti, Zhaofu Fei, Dunru Zhu and Paul J. Dyson

Small, 2023, 19
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Glass transition of amorphous materials composed of organically modified metal oxo-oligomers

Ryo Tsutsui, Shinya Oda, Kota Suzuki, Haruka Nakano, Yutaka Emi, Shinnosuke Yamazaki and Hirmotsu Kozuka

Materials Chemistry and Physics, 2024, 314, 128845
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Synthesis of Calcium Phosphates with Various Ca/P Ratios Using Phytic Acid as a Green Phosphorus Source

Kazuki Maeda, Yoshiki Aoto and Satoru Dohshi

ACS Agric. Sci. Technol., 2023, 3, 1148
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ZnO incorporated hybrid catalytic proton exchange membrane for H2 generation

Jay N. Mishra, Priyanka A. Jha, Pardeep K. Jha, Parvin K. Singh, Suman Roy Choudhary and Prabhakar Singh

APL Energy, 2023, 1
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Looking into the future of hybrid glasses

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Nat. Chem., 2024, 16, 1755
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Vitrification-enabled enhancement of proton conductivity in hydrogen-bonded organic frameworks

Feng-Fan Yang, Xiao-Lu Wang, Jiayue Tian, Yang Yin and Linfeng Liang

Nat Commun, 2024, 15
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High Proton Conductivity over a Wide Intermediate-Temperature Range in Benitoite-Type KMg1–xLixHx(PO3)3·yH2O with a Three-Dimensional Water Network within a Rigid Open Framework

Kazuhiko Hirose and Yasuaki Matsuda

ACS Appl. Energy Mater., 2025, 8, 17688
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Quantification of gas-accessible microporosity in metal-organic framework glasses

Louis Frentzel-Beyme, Pascal Kolodzeiski, Jan-Benedikt Weiß, Andreas Schneemann and Sebastian Henke

Nat Commun, 2022, 13
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(RPh3P)[Mn(dca)3]: A Family of Glass-Forming Hybrid Organic–Inorganic Materials

Bikash Kumar Shaw, Lucia Corti, Joshua M. Tuffnell, Celia Castillo-Blas, Patrick Schlachta, Georgina P. Robertson, Lauren McHugh, Adam F. Sapnik, Sebastian A. Hallweger, Philip A. Chater, Gregor Kieslich, David A. Keen, Sian E. Dutton, Frédéric Blanc and Thomas D. Bennett

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Plasticity of Metal–Organic Framework Glasses

Remo N. Widmer, Alice M. Bumstead, Manish Jain, Thomas D. Bennett and Johann Michler

J. Am. Chem. Soc., 2021, 143, 20717
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MOF Ceramic‐Like Membrane With High Proton Conduction and Tunable Transparency

Manni Li, Kaixi Lan, Yanting Zhang, Lei Wu, Dongshuang Wu, Yaotian Yan, Wenxin Zhang, Weidong Shi and Kun Zhang

Angew Chem Int Ed, 2026
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Eutectic CsHSO4-Coordination Polymer Glasses with Superprotonic Conductivity

Nattapol Ma, Nao Horike, Loris Lombardo, Soracha Kosasang, Kotoha Kageyama, Chonwarin Thanaphatkosol, Kanokwan Kongpatpanich, Ken-ichi Otake and Satoshi Horike

J. Am. Chem. Soc., 2022, 144, 18619
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Crystallization Kinetics of a Liquid-Forming 2D Coordination Polymer

Chinmoy Das, Taichi Nishiguchi, Zeyu Fan and Satoshi Horike

Nano Lett., 2022, 22, 9372
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Formation of Porosity toward Acetylene upon Vitrification of Non-porous Photochromic Coordination Polymer Crystals

Zeyu Fan, Yong-Sheng Wei, Hiroyasu Tabe, Tomotaka Nakatani, Chinmoy Das, Hiroki Yamada and Satoshi Horike

Chem. Mater., 2023, 35, 3859
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Liquid Coordination Polymers with Anhydrous Proton Conductivity

Nattapol Ma, Soracha Kosasang, Satoshi Horike and Hiroki Yamada

Angew Chem Int Ed, 2025, 64
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Three-Dimensional Metal–Organic Network Glasses from Bridging MF62– Anions and Their Dynamic Insights by Solid-State NMR

Takuya Kurihara, Kotaro Ohara, Kentaro Kadota, Hitoshi Izu, Yusuke Nishiyama, Motohiro Mizuno and Satoshi Horike

Inorg. Chem., 2022, 61, 16103
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Glass formation, structure, relaxation, and property of metal-organic framework (MOF) glasses: A review

Di Xu and Chuanqi Pan

Progress in Natural Science: Materials International, 2025, 35, 98
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Pore-filling membrane containing solely zirconium phosphonates with high content through in-situ conversion

T. Taniuchi, T. Ogawa, M. Yoshida, T. Nakazono and K.N. Ishihara

International Journal of Hydrogen Energy, 2023, 48, 31337
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Tin-based hybrid: from crystal engineering to sensitive Cd2+ detection in real water samples

Najeh Abbassi, Naoufel Ben Hamadi, Jassem Wannassi, Noureddine Mhadhbi, Ali Ben Ahmed, Ahlem Guesmi, Fehmi Boufahja, Jeanneau Erwann, Houcine Barhoumi and Houcine Naïli

Inorganic Chemistry Communications, 2026, 183, 115886
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High proton conductivity and thermal stability in Benitoite-type KCa1-H2(PO3)3·yH2O with a crystal-water diffusion network

Kazuhiko Hirose, Yuuka Kou and Yasuaki Matsuda

Solid State Ionics, 2026, 440, 117179
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Practical Considerations in the Design and Use of Non‐Crystalline Metal–Organic Frameworks

Hamidreza Mahdavi, Farnaz Zadehahmadi, Mehran Arzani, Leena Melag, Ashley L. Sutton, Muhammad M. Sadiq, Zongli Xie, Matthew R. Hill and Benny D. Freeman

Advanced Materials, 2025, 37
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