Metal-organic Frameworks Derived Micro-/Nano-materials: Precise Synthesis and Clean Energy Applications

Abstract

Metal-organic frameworks (MOFs) and their derived materials have emerged as forefront contenders in the realm of advanced materials science, heralded for their versatility, high surface areas, and tunable properties. These materials distinguish themselves through their exceptional ability to be tailored during synthesis, offering precise control over their morphology and functionalities. The derivation process from MOFs not only preserves their inherent large surface areas but also enhances their electrical conductivity and stability. Herein, we summarized the different synthetic strategies of MOF derived micro-/nano-materials up to date, including but not limited to calcining, phosphating, sulfurization, selenylation method, ion exchange, and etching strategies. Recent progress of MOFs derived micro-/nano-nanomaterials for various applications including supercapacitors, metal-ion batteries, Li-S batteries, metal-air batteries, hydrogen evolution reaction, oxygen evolution reaction and o reduction reaction were reviewed. Through detailed summary of these applications and the innovative approaches to their synthesis, this work highlights the utility and potential that MOF-derived materials hold. Concluding with a discussion on the challenges and future prospects of these materials, we underscore their transformative potential in advancing materials science and technology.