Issue 1, 1989

Macrocyclic dimanganese complexes with 1,1 bridging ligands; X-ray crystallographic structure determination of an N-only bridged thiocyanato derivative

Abstract

X-Ray crystallographic structure determination confirms the inference from i.r. spectra that the µ 1,1 NCS bridge is present in dimanganese(II) complexes of a 22-membered N6 macrocycle: these complexes show no appreciable magetic interaction above 93 K, unlike the µ-methoxo-dimanganese(III) complex of the same ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 5-7

Macrocyclic dimanganese complexes with 1,1 bridging ligands; X-ray crystallographic structure determination of an N-only bridged thiocyanato derivative

S. Raghunathan, C. Stevenson, J. Nelson and V. Mckee, J. Chem. Soc., Chem. Commun., 1989, 5 DOI: 10.1039/C39890000005

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